Journal of Materials Science

, Volume 50, Issue 19, pp 6518–6525 | Cite as

Graphene as a lubricant on Ag for electrical contact applications

  • Fang MaoEmail author
  • Urban Wiklund
  • Anna M. Andersson
  • Ulf Jansson
Open Access
Original Paper


The potential of graphene as a solid lubricant in sliding Ag-based electrical contacts has been investigated. Graphene was easily and quickly deposited by evaporating a few droplets of a commercial graphene solution in air. The addition of graphene reduced the friction coefficient in an Ag/Ag contact with a factor of ~10. The lubricating effect was maintained for more than 150,000 cycles in a pin-on-disk test at 1 N. A reduction in friction coefficient was also observed with other counter surfaces such as steel and W but the life time was strongly dependent on the materials combination. Ag/Ag contacts exhibited a significantly longer life time than steel/Ag and W/Ag contacts. The trend was explained by an increased affinity for metal–carbon bond formation.


Friction Coefficient Contact Resistance Graphene Layer Tribological Behavior Lubricate Effect 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.


Electrical contacts are important in modern technology. From a materials science point of view, the design of such contacts is a complex problem, in particular for a sliding contact. In general, a contact material must have a low resistivity, a low contact resistance, a high corrosion resistance, and also be reasonable inexpensive. For a sliding contact, additional materials properties are required. The material cannot be too soft and must exhibit a low wear rate. In addition, a low friction coefficient between the sliding surfaces is required. All these properties are difficult to combine in one single material and the development of new, more reliable contact materials is therefore a true challenge.

One of the most widely used contact materials is Ag. This noble metal exhibits a low resistivity and low contact resistance. The disadvantages of Ag, are the rather high materials costs and the fact that it form surface compounds such as sulfides which may be detrimental for the performance. Most important of all, in a sliding contact application, it is too soft and the friction coefficient between two sliding Ag surfaces is far too high (>1). Consequently, there is a need to modify the Ag surfaces to reduce the friction coefficient by e.g., adding a surface coating on the Ag contact. One example for such coating is AgI which can be deposited by electrochemical techniques or by exposure to an I 2 solution [1, 2, 3]. Ag versus AgI-coated Ag contacts typically exhibit a friction coefficient of 0.3 but have a limited life time as the AgI coatings have a rather high wear rate [3]. Hence, other methods to produce low friction surfaces on Ag contacts with long lifetimes are needed.

One of the emerging lubricating materials is graphene, which has been widely studied for its remarkable mechanical, electrical, optical, and thermal properties [4, 5, 6, 7]. The tribological properties, especially as a lubricating additive, have attracted intense research attention as well [8, 9, 10, 11, 12, 13]. Recently, however, Berman et al. demonstrated that the addition of few-layer graphene flakes to a steel surface can significantly reduce the friction coefficient from ~1 to about 0.15 against steel in a pin-on-disk test [14, 15]. It is conceivable that graphene layers (GL) also could drastically reduce the friction coefficient for a sliding Ag/Ag contacts but this has yet not been demonstrated. Ag interacts weakly with graphene and forms weak Ag–C bonds. It is therefore possible that the tribological behavior for a graphene-coated Ag surface can be quite different compared to a graphene-coated steel surface where stronger interactions with graphene and also stronger Fe–C bonds are expected. Furthermore, it is possible to design a contact where a Ag surface is sliding against a counter surface of another metal or alloy. In this case, the graphene can be expected to exhibit different effects on the tribological properties depending on the metal–graphene interactions.

The aim of this study is to investigate the potential use of graphene in sliding Ag-based contacts. Also, trends of metal-graphene interactions are studied by using Ag/Ag, Ag/steel, and Ag/W contacts. Me–C bond strength is known to vary among the transition metals where W shows the strongest bonds and Ag the weakest. Fe-based alloys such as steel are therefore expected to exhibit intermediate bond strength to carbon. We have investigated the tribological behavior of these materials combinations with added graphene and characterized the contacts with Raman spectroscopy and X-ray photoelectron spectroscopy (XPS).

Materials and methods

Tribological studies of flat Ag samples with and without added graphene were performed using a ball-on-disk tribometer (from VIT) with rotation geometry at room temperature. The flat Ag samples from Alfa Aesar (99.95 % purity) were polished and its roughness was measured using an optical profiler WYKO NT1100 (from Veeco/WYKO) to R q = ~18 nm. The counter materials were a silver-coated cylindrical Cu rod with a hemispherical tip of 9 mm diameter with R q = ~60 nm, bearing steel balls of 6 mm diameter with R q = ~10 nm, and tungsten balls of 8 mm diameter with R q = ~50 nm. All the specimens were cleaned by sonication in acetone, and then in isopropanol and followed by flushing in dry N2 to clean up any contaminants left from the sample preparation and polishing steps. All of the tribological tests were carried out at a sliding speed of 0.02 m/s with contact track of 2.5 mm radius. The friction coefficient was continually recorded during each test. Two different normal loads were applied for the tribological tests; 2 N normal load was used for lifetime testing of lubricating GL, while more detailed comparisons between different balls against Ag with added graphene were performed using a normal load of 1 N. A graphene-containing ethanol solution (1 mg/L) from Graphene Supermarket Inc. was used a graphene source. The solution contained monolayer graphene with an average flake size of 550 nm. Before the tribological tests, three droplets of the graphene solution were added on the highly polished silver plate surface and allowed to evaporate in ambient atmosphere (humidity 30 %).

The surface morphology was studied using a scanning electron microscopy (SEM; Merlin, Zeiss) with a field emission gun as the electron source and an acceleration voltage of 5 kV. After the tribological tests, the contact tracks were examined using Raman spectroscopy, using a red laser light (λ = 633 nm) in a Renishaw Invia-Raman spectroscope. The chemical bonds in the contact tracks were studied with XPS using a Physical Systems Quantum 2000 spectrometer with monochromated Al Kα radiation. The analysis was performed with an analysis spot of 50 μm without any pre-sputtering. The instrument was calibrated against Au, Ag, and Cu references. The composition ratio of Ag/C on the surface of the contact tracks was estimated using XPS areas and sensitivity factors given by the Physical Electronics Software MultiPak V6.1A. The imaging of the contact tracks was performed with an Olympus optical microscope (from Leitz). The roughness and height profile of the sample surface of the contact tracks were determined with an optical profiler WYKO NT1100 (from Veeco/WYKO).

The contact resistances of the Ag surface and the graphene-coated Ag were measured using a custom-made set-up, based on a four-point resistance method, measuring the voltage drop as a current flows from the probe tip to the test surface. The terminal on the probe is placed as close to the contact point as possible to ensure the distance for shared path of current and voltage is as short as possible to reduce the resistance contribution from probe. The path of the current and voltage divides immediately after the contact point to ensure the contact resistance measurement is not affected by the sheet resistance of the measured film or the internal resistance of the wires. The normal load during contact resistance measurements was varied from 1 to 5 N. All measurements were carried out against a commercial Au-coated probe K60.05.33 (from Fixtest, Germany) with a hemispherical tip with Φ 3.3 mm.


The lubricating effect of graphene was evaluated by measurements of friction coefficients of a clean Ag surface and a graphene-modified Ag surface using three different counter materials Ag, steel, and W. In the following the graphene-free systems are denoted Ag/Ag, steel/Ag, and W/Ag while the graphene-modified systems are denoted Ag/GL/Ag, steel/GL/Ag, and W/GL/Ag, respectively. During the initial experiments, we observed a variation in results also for the same set of counter materials. A general observation was that the graphene solution was susceptible to aging and that the lubricating effect of the applied graphene solution decreased by time. Furthermore, some variation in e.g., friction coefficient was also observed between different experiments. Thus the results presented below shows a representative set of observations where the general trends between materials will be demonstrated.

A typical set of friction curves for the different materials pairs with and without added graphene are shown in Fig. 1. The optical micrographs and profiles of the tracks for each tribotest are also included as insets. As can be seen, a dramatic reduction of the friction coefficient is observed after addition of graphene, in particular for the Ag/GL/Ag system. In addition, the roughness of tracks is also affected by the addition of graphene.
Fig. 1

Friction coefficients (μ), optical micrographs (scale bar 200 μm) and height profiles of the tracks from the pin-on-disk tests (load: 1 N) for a Ag, b steel, and c W against Ag plate with and without graphene deposition. All tribological tests were manually stopped after 1500 cycles

As shown in Fig. 1a, Ag/Ag performed poorly with a high and fluctuating friction coefficient (~1.15). The optical micrograph shows that the Ag/Ag pair suffered severe adhesive material transfer between the surfaces, which is also illustrated by the profile of the track surface. With addition of graphene, however, the friction coefficient was reduced remarkably to around 0.2–0.25 initially. Typically, the friction was reduced with time and reached a value of 0.1–0.15 after 1000 laps. However, a friction coefficient as low as 0.05 was observed in some experiments. In the Ag/Ag pair, the high tendency for adhesion gives a strong interface, similar in strength to the two mating materials, and promotes material transfer and a large area of contact. All of these effects result in a high roughness of the contact track and a high friction coefficient for the Ag/Ag pair. However, GL weaken the ‘interface’, where it is deposited, and thus provide a preferred shear plane, resulting in less adhesion, less material transfer, a smoother track, and a lower friction coefficient in the Ag/GL/Ag pair.

The steel/Ag pair initially shows a very low friction coefficient (0.15), due to the low roughness of steel ball, resulting in a delayed onset of adhesion. After 50 cycles, the friction coefficient gradually starts to increase to ~0.85. With addition of graphene, the friction coefficient was reduced from about 0.85 (steel/Ag) to 0.15 (steel/GL/Ag) after 1500 cycles. The example in Fig. 1b shows an experiment where the friction in the steel/GL/Ag pair initially was below 0.1 and increased to about 0.15. The optical micrographs and height profiles of the tracks illustrates a rough track surface and ridges piling up to a similar volume as the groove in the steel/Ag track, indicating a combination of adhesive material transfer and plastic deformation of the Ag surface in the steel/Ag pair. With addition of graphene, however, almost no adhesive material transfer is visible in the steel/GL/Ag track, instead plastic deformation dominates completely.

As shown in Fig. 1c, graphene also improves the tribological behavior of the W/Ag pair. The addition of graphene decreased the friction coefficient from 0.75 (W/Ag) to 0.45 (W/GL/Ag). The height profile of W/Ag track shows a combination of adhesive transfer and plastic deformation, similar as steel/Ag track. However, with addition of graphene, unlike the steel/GL/Ag pair, some adhesive material transfer is evident in the W/GL/Ag track. The results in Fig. 1 show that graphene was a less effective lubricant with W as a counter surface than with Ag and steel as counter surfaces.

The results in Fig. 1, from tests carried out at a 1 N load, clearly show a lubricating effect with graphene strongly influenced by the metal in the counter surface. To further study this effect, a lifetime study was performed. In a first experiment, a Ag/GL/Ag pair was tested at 1 N (black curve in Fig. 2). This system showed a friction coefficient about 0.06. The test was terminated after about 150,000 laps without loss of lubricating effect. Berman et al. have observed that the lubricating effect of graphene is load dependent [15]. A second set of experiments were therefore carried out at 2 N. In this case, the Ag/GL/Ag pair showed a slightly higher friction coefficient for more than 40,000 laps, followed by a rapid increase in friction probably due to a loss of lubrication. In contrast, both the steel/GL/Ag and W/GL/Ag pairs showed a considerably lower lifetime in our experimental set-up. The lifetime of the steel/GL/Ag pair was determined to about 2700 cycles (not even discernible in Fig. 2) when the friction coefficient starts to fluctuate and increase gradually to high values. The corresponding life time for the W/GL/Ag pair was determined to be only about 500 cycles.
Fig. 2

Lifetime testings of lubricating graphene in the tribological pairs of different metal counter surfaces (Ag, Steel, and W) against the graphene-coated Ag plate

SEM and Raman spectroscopy were used to characterize the surfaces after addition of graphene on Ag. As shown in Fig. 3a, after evaporation of the ethanol, grayish flakes on the surface can be seen in the SEM images. It is clear that the size of the deposited flakes varies with massive amount of flakes less than 1 μm in diameter. It also shows that the silver surface is not fully covered by the deposited flakes. Raman spectroscopy confirms that the flakes indeed are graphene (see Fig. 3b). The characteristic peaks of graphene were observed at ~1330 cm−1 (D peak), ~1600 cm−1 (G peak) and ~2650 cm−1 (2D peak). The D peak is due to a breathing mode of sp2 atoms in rings, which is activated by disordered structures, e.g., edges or defects from partial oxidation of graphene [16, 17, 18, 19]. The D peak is quite strong, indicating a large amount of disordered structures, e.g., edges or partial oxidation in graphene flakes. The Raman results suggest that the flakes consist of few-layer graphene, very similar to those observed by Berman et al. on steel surfaces [15].
Fig. 3

a SEM image and b Raman spectrum of as-deposited graphene flakes on Ag plate surface before pin-on-disk test. Scale bar for SEM image is 2 μm

To further study the lubricating effect of the GL, Raman spectroscopy was also carried out inside the track after the completion of the dry sliding tribological tests. The Raman spectra and the SEM images of the tracks are shown in Fig. 4. The track of the Ag/Ag pair clearly suggests an adhesive material transfer as observed in Fig. 1. In contrast, the SEM image of the Ag/GL/Ag pair shows a microscopic plowing pattern with plenty of grayish flakes remaining in the track. The existence of GL in the tracks after 1500 cycles was also confirmed by the characteristic Raman spectrum, which is almost identical to that from as-deposited flakes in Fig. 3. The SEM images from the steel/Ag and steel/GL/Ag pairs also confirm that graphene has a strong impact of the tribological behavior. The track in the steel/Ag pair shows adhesive material transfer mixed with plowing while the steel/GL/Ag pair only exhibits minute plowing with remains of grayish flakes. The Raman spectrum from the steel/Ag track shows a number of peaks e.g., at ~560, 650, and 1320 cm−1. These peaks can be attributed to metal oxides such as Fe2O3 which has been transferred from the steel ball to the Ag surface during the tribological test [20]. In contrast, the Raman spectrum from the steel/GL/Ag track shows clear peaks from graphene, similar to the Ag/GL/Ag case, but no metal oxide peaks. This shows that the presence of graphene has a strong influence on the tribological behavior also with steel as a counter surface. A completely different behavior was observed with W as a counter material. The Raman spectrum from the W/Ag track shows a strong peak W–O at ~900 cm−1 suggesting an extensive formation of tungsten oxides in the track [21]. Upon addition of graphene, the W/GL/Ag track shows very few graphene flakes in SEM. Furthermore, the W–O peak is still clearly seen in the Raman spectrum but only very weak and broad D and G peaks are observed. Such peaks are typical for amorphous carbon and suggest that the graphene has been highly damaged or completely destroyed during the sliding test.
Fig. 4

Raman spectra and SEM images for the tracks on the Ag plate with and without graphene deposition after pin-on-disk tests using different counters: a Ag ball; b steel ball; and c W ball. Scale bar for SEM images are 100 μm

XPS analysis can give supplementary information about graphene coverage inside the tracks through the C/Ag composition ratio. As shown in Fig. 5, the composition ratio of C/Ag inside the tracks of the three bare metals/Ag was almost similar to 1, which means that there were some carbon contaminations on the bare track surface after the tribological tests. This originates from the carbon-containing contaminants adsorbed on the surfaces. In contrast, the three metals/GL/Ag pairs, exhibit significantly higher C/Ag ratios in the tracks. The Ag/GL/Ag track exhibits a higher ratio than steel/GL/Ag and considerably larger than that for the W/GK/Ag track. This result is consistent with the Raman and SEM results that plenty of graphene remains in Ag/GL/Ag track and less graphene left in the W/GL/Ag track.
Fig. 5

Composition ratio of C/Ag inside the tracks on the Ag plate after pin-on-disk tests using different counter surfaces

To understand the reasons for different tribological behaviors in different metal-graphene interfaces, XPS was used to analyze the chemical bonding in the tracks of different metals/GL/Ag pairs. As shown in Fig. 6a, Ag, C, and O signals were detected in all tracks. The C1s peak could originate from a mixture of remaining graphene flakes and other carbon contaminations. The O can be attributed to partially oxidized graphene or oxidized metal particles formed during the sliding tests. Some organic contaminants can also contribute. It is interesting to notice that W peaks were also observed in the XPS spectrum from the track of the W/GL/Ag pair, while no Fe peaks were seen in the spectrum from the steel/GL/Ag track. This indicates that W has been transferred to the Ag surface from the W ball during sliding while no such transfer occurs from the steel ball. High resolution spectra from the W4f peak indicate that the W is oxidized (not shown here).
Fig. 6

a Survey XPS spectra and b high resolution XPS spectra of C1s peaks for the track surface on the graphene-coated Ag plate after pin-on-disk tests using different metal counters

High resolution spectra of the C1s peak obtained after 1500 cycles are shown in Fig. 6b. In the track of Ag/GL/Ag, a C1s peak is observed at 284.8 eV, which can be attributed to mainly C–C bonds in graphene [22]. Also, the C1s peaks show weak contribution around 289 eV which can be attributed to a type of C–O bonds. The relative intensity of the C–O contribution is slightly higher for the steel/GL/Ag par and significantly higher for the W/GL/Ag pair. This suggests a somewhat stronger oxidation of the GL with a steel counter surface. Furthermore, for the W/GL/Ag pair, the C1s peak is shifted with 0.2 eV to a lower binding energy together with an increase in the intensity of C–O feature. This shift suggests a strong interaction of carbon with a metal such as W. The peak shift is not an indication of the formation of a hexagonal WC phase since the C1s peak in this compound is observed at 283.5 eV. However, the C-W binding energy is strongly dependent on the type of W–C coordination and, for example, a binding energy of 284.1 eV has been observed in W2C [23]. It can be concluded, however, that the peak shift and increased C–O intensity is in good agreement with a decomposition of the graphene flakes in the W/GL/Ag track and the formation of amorphous carbon and some type of W–C compound.

The contact resistance of graphene-coated Ag surfaces was also evaluated using a four-point resistance method. A general observation was that the addition of graphene slightly reduced the contact resistance compared to the pure Ag surface, but at a similar level, as shown in Fig. 7. The graphene-coated Ag surface exhibited a contact resistance of 0.8 mΩ, compared to 1.18 mΩ for pure Ag at a normal load of 1 N. The deviations decrease with increasing load, e.g., 0.41 mΩ for graphene/Ag and 0.59 mΩ for Ag using 5 N. Graphene as a zero-overlap semimetal (with both holes and electrons as charge carriers) with very high electrical conductivity could be the main contribution for the good contact property of graphene-coated Ag surface [24].
Fig. 7

Contact resistance of Ag and graphene-coated Ag (graphene/Ag) surface for different loads


Our results clearly show that graphene is an excellent lubricant in Ag/GL/Ag contacts. In contrast, graphene showed a lubricating effect with tungsten as a counter surface but the friction coefficient was higher and the lifetime of the graphene was much shorter. The steel/GL/Ag pair showed an intermediate behavior. There are two main mechanisms which may contribute to these results: (i) the general trend in the Me–C bond strength and the Me–graphene interactions and (ii) the mechanical deformation mechanisms in the metal/GL/Ag contacts.

Our XPS and Raman results clearly suggest that graphene on W in the track is highly damaged and probably partly decomposed. The shift of the XPS C1s peak suggests a strong C-W interaction between the metal and damaged graphene and/or partial formation of a C–W compound. No direct indications of such decomposition were observed on Ag or steel. It is clear that chemical interactions between metals and carbon are strongly dependent on the position of the metal in the periodic table. In general, the Me–C bond strength decreases with increasing number of d-electrons in the metal. In our study, the W–C bond strength is rather high and several tungsten carbide phases are known with the hexagonal WC phase an illustrative example. The Fe–C bonds are weaker and only metastable iron carbides are known. Finally, the Ag–C interactions are very weak and no stable or metastable silver carbides are known. Consequently, from a thermodynamic point of view, a driving force exists to form carbides by a chemical reaction between W and graphene while no such driving force exists for Fe and Ag. Secondly, the kinetics of decomposition of graphene can be strongly affected by Me–C interactions. A change of charge transfer can dramatically change the stability of a molecule due to changes in the bonding/antibonding states. Theoretical calculations on adsorption of graphene have shown mainly weak adsorption (physisorption) on late transition metals such as Cu, Ag, and Au while a much stronger interactions including chemisorptions can be observed on Co and Ni [25, 26, 27]. Hence, from a pure chemical point of we should expect strong interactions between graphene and W and to some extent also Fe. This can explain the general trends observed in the tribological properties described above.

An alternative explanation to the observed trends in friction could possibly be variations in the mechanical deformation mechanisms in the metal/GL/Ag contacts. The tracks after tribological tests indeed look very different; some shallow and some extending to large depths. But when comparing the different tribological behaviors, it is important to keep the vast differences in mechanical strength in mind and to separate the mechanical plastic deformation from the more interesting tribological mechanisms behind the friction coefficients. Ag is a very soft metal known for very limited strain hardening. In any contact with considerably harder materials, like steel or W, only the Ag will deform plastically. This means that the steel balls, the W balls and even the Ag tips used in this work will all be pressed into the silver counter material until the contact area has grown sufficiently large to make the contact pressure match the hardness of Ag. In other words, the contact pressure will be very similar for all three (or six) pairs tested here, despite the fact that the radii of the spherical bodies differ somewhat. And despite the fact that the specific shapes of the tracks will be different. This holds both initially, at first contact, and during the subsequent mechanical deformation occurring during the tribological testing. In other words, the much harder steel and W will merely serve to shape the surface of the track in Ag, on which the crucial tribological mechanisms will take place, i.e., material transfer, graphene retention or decomposition, oxidation, etc.

However, once material transfer commence, the shape of the components will degrade. This is very clearly demonstrated by the Ag/Ag pair where the initially spherical against flat geometry is completely lost due to excessive material transfer. A strong intermetallic bond, as in the Ag/Ag pair, is of course very effective in initiating material transfer. All other pairs tested, and especially those with interfaces containing graphene, will be less prone to material transfer. But once it is initiated, the surfaces will begin to degrade and the effectiveness of any graphene present in the surface will be reduced further.

Consequently, we conclude that the most likely explanation for the observed trend in tribological behavior is variations in the chemical interactions between metal and graphene.


In this study, the potential use of GL as a solid lubricant on sliding Ag electrical contact was investigated. It has been shown that small amount of graphene flakes, which can easily and quickly be deposited by evaporating a commercial solution in air, can dramatically reduce friction in dry sliding Ag/Ag contacts. With the lubricating effect of the graphene flakes, the friction coefficient was reduced by a factor of ~10 (e.g., from 1.15 to 0.12). Moreover, the track was much smoother, showing almost no signs of adhesive material transfer. The lifetime of the lubricating graphene was very long and the contact resistance for graphene/Ag surface was similar to pure Ag.

The lubricating effect was dependent on the counter surface. The Ag/GL/Ag contact exhibited the lowest friction coefficient and longest lifetime (>40,000 cylces at 2 N). In contrast, the steel/GL/Ag and W/GL/Ag exhibited higher friction coefficients and shorter lifetimes. The lifetime of the W/GL/Ag pair was only 500 cycles. Metal–graphene interaction is believed to be the main reason for the differences in friction reduction, where W-graphene shows the strongest bonds and Ag the weakest. Fe-based alloys such as steel exhibits intermediate bond strength to graphene. Therefore, the friction reduction with graphene lubrication increased in the sequence Ag ball > steel ball > W ball. Alternative models to explain the trend, such as variations in hardness between the counter surfaces could be excluded due to the softness of the Ag surface. Overall, the deposited GL holds a great promise as an effective solid lubricant to significantly reduce friction in sliding Ag electrical contacts, especially in such a simple, quick, energy-saving, and cost-efficient way.



The authors wish to acknowledge the financial support of the KIC InnoEnergy and the Swedish Centre for Smart Grids and Energy Storage (SweGRIDS). We also want to thank Pedro Berastegui for his technical support. Ulf Jansson also acknowledges Knut och Alice Wallenberg (KaW) foundation for support. Urban Wiklund also acknowledges the Swedish Foundation for Strategic Research (via the program Technical advancement through controlled tribofilms) for the financial support.


  1. 1.
    Arnell S, Andersson G (2001) Silver iodide as a solid lubricant for power contacts. In: Proceedings of the forty-seventh IEEE holm conference on electrical contacts, 239–244. doi: 10.1109/holm.2001.953217
  2. 2.
    Lauridsen J, Eklund P, Lu J, Knutsson A, Odén M, Mannerbro R, Andersson AM, Hultman L (2012) Microstructural and chemical analysis of AgI coatings used as a solid lubricant in electrical sliding contacts. Tribol Lett 46(2):187–193. doi: 10.1007/s11249-012-9938-3 CrossRefGoogle Scholar
  3. 3.
    Sundberg J, Mao F, Andersson A, Wiklund U, Jansson U (2013) Solution-based synthesis of AgI coatings for low-friction applications. J Mater Sci 48(5):2236–2244. doi: 10.1007/s10853-012-6999-5 CrossRefGoogle Scholar
  4. 4.
    Gao Y, Hao P (2009) Mechanical properties of monolayer graphene under tensile and compressive loading. Physica E 41(8):1561–1566. doi: 10.1016/j.physe.2009.04.033 CrossRefGoogle Scholar
  5. 5.
    Geim AK (2009) Graphene: status and prospects. Science 324(5934):1530–1534. doi: 10.1126/science.1158877 CrossRefGoogle Scholar
  6. 6.
    Lee C, Wei X, Kysar JW, Hone J (2008) Measurement of the elastic properties and intrinsic strength of monolayer graphene. Science 321(5887):385–388. doi: 10.2307/20054532 CrossRefGoogle Scholar
  7. 7.
    Stankovich S, Dikin DA, Dommett GHB, Kohlhaas KM, Zimney EJ, Stach EA, Piner RD, Nguyen ST, Ruoff RS (2006) Graphene-based composite materials. Nature 442(7100):282–286. doi: 10.1038/nature04969 CrossRefGoogle Scholar
  8. 8.
    Choudhary S, Mungse HP, Khatri OP (2012) Dispersion of alkylated graphene in organic solvents and its potential for lubrication applications. J Mater Chem 22(39):21032–21039. doi: 10.1039/c2jm34741e CrossRefGoogle Scholar
  9. 9.
    Kandanur SS, Rafiee MA, Yavari F, Schrameyer M, Yu Z-Z, Blanchet TA, Koratkar N (2012) Suppression of wear in graphene polymer composites. Carbon 50(9):3178–3183. doi: 10.1016/j.carbon.2011.10.038 CrossRefGoogle Scholar
  10. 10.
    Lee C, Wei X, Li Q, Carpick R, Kysar JW, Hone J (2009) Elastic and frictional properties of graphene. Phys Status Solidi B 246(11–12):2562–2567. doi: 10.1002/pssb.200982329 CrossRefGoogle Scholar
  11. 11.
    Lin J, Wang L, Chen G (2011) Modification of graphene platelets and their tribological properties as a lubricant additive. Tribol Lett 41(1):209–215. doi: 10.1007/s11249-010-9702-5 CrossRefGoogle Scholar
  12. 12.
    Sandoz-Rosado EJ, Tertuliano OA, Terrell EJ (2012) An atomistic study of the abrasive wear and failure of graphene sheets when used as a solid lubricant and a comparison to diamond-like-carbon coatings. Carbon 50(11):4078–4084. doi: 10.1016/j.carbon.2012.04.055 CrossRefGoogle Scholar
  13. 13.
    Berman D, Erdemir A, Sumant AV (2014) Graphene as a protective coating and superior lubricant for electrical contacts. Appl Phys Lett 105(23):231907. doi: 10.1063/1.4903933 CrossRefGoogle Scholar
  14. 14.
    Berman D, Erdemir A, Sumant AV (2013) Few layer graphene to reduce wear and friction on sliding steel surfaces. Carbon 54:454–459. doi: 10.1016/j.carbon.2012.11.061 CrossRefGoogle Scholar
  15. 15.
    Berman D, Erdemir A, Sumant AV (2013) Reduced wear and friction enabled by graphene layers on sliding steel surfaces in dry nitrogen. Carbon 59:167–175. doi: 10.1016/j.carbon.2013.03.006 CrossRefGoogle Scholar
  16. 16.
    Ferrari AC, Robertson J (2000) Interpretation of Raman spectra of disordered and amorphous carbon. Phys Rev B 61(20):14095–14107CrossRefGoogle Scholar
  17. 17.
    Pócsik I, Hundhausen M, Koós M, Ley L (1998) Origin of the D peak in the Raman spectrum of microcrystalline graphite. J Non-Cryst Solids 227–230, Part 2 (0):1083–1086. doi: 10.1016/S0022-3093(98)00349-4
  18. 18.
    Ferrari AC (2007) Raman spectroscopy of graphene and graphite: disorder, electron–phonon coupling, doping and nonadiabatic effects. Solid State Commun 143(1–2):47–57. doi: 10.1016/j.ssc.2007.03.052 CrossRefGoogle Scholar
  19. 19.
    Ferrari AC, Meyer JC, Scardaci V, Casiraghi C, Lazzeri M, Mauri F, Piscanec S, Jiang D, Novoselov KS, Roth S, Geim AK (2006) Raman spectrum of graphene and graphene layers. Phys Rev Lett. doi: 10.1103/PhysRevLett.97.187401 Google Scholar
  20. 20.
    Muralha VSF, Rehren T, Clark RJH (2011) Characterization of an iron smelting slag from Zimbabwe by Raman microscopy and electron beam analysis. J Raman Spectrosc 42(12):2077–2084. doi: 10.1002/jrs.2961 CrossRefGoogle Scholar
  21. 21.
    Voevodin AA, O’Neill JP, Zabinski JS (1999) Tribological performance and tribochemistry of nanocrystalline WC/amorphous diamond-like carbon composites. Thin Solid Films 342(1–2):194–200. doi: 10.1016/S0040-6090(98)01456-4 CrossRefGoogle Scholar
  22. 22.
    Ferrah D, Penuelas J, Bottela C, Grenet G, Ouerghi A (2013) X-ray photoelectron spectroscopy (XPS) and diffraction (XPD) study of a few layers of graphene on 6H-SiC(0001). Surf Sci 615:47–56. doi: 10.1016/j.susc.2013.04.006 CrossRefGoogle Scholar
  23. 23.
    Aizawa T, Hishita S, Tanaka T, Otani S (2011) Surface reconstruction of W2C(0001). J Phys-Condens Mat 23(30):305007CrossRefGoogle Scholar
  24. 24.
    Castro Neto AH, Guinea F, Peres NMR, Novoselov KS, Geim AK (2009) The electronic properties of graphene. Rev Mod Phys 81(1):109–162CrossRefGoogle Scholar
  25. 25.
    Xu Z, Buehler MJ (2010) Interface structure and mechanics between graphene and metal substrates: a first-principles study. J Phys 22(48):485301Google Scholar
  26. 26.
    Giovannetti G, Khomyakov PA, Brocks G, Karpan VM, van den Brink J, Kelly PJ (2008) Doping graphene with metal contacts. Phys Rev Lett 101(2):026803CrossRefGoogle Scholar
  27. 27.
    Andersen M, Hornekær L, Hammer B (2012) Graphene on metal surfaces and its hydrogen adsorption: a meta-GGA functional study. Phys Rev B 86(8):085405CrossRefGoogle Scholar

Copyright information

© The Author(s) 2015

Open AccessThis article is distributed under the terms of the Creative Commons Attribution 4.0 International License (, which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made.

Authors and Affiliations

  1. 1.Department of Chemistry–Ångström LaboratoryUppsala UniversityUppsalaSweden
  2. 2.Department of Engineering SciencesUppsala UniversityUppsalaSweden
  3. 3.ABB AB, Corporate ResearchVästeråsSweden

Personalised recommendations