Advertisement

Journal of Materials Science

, Volume 49, Issue 24, pp 8478–8486 | Cite as

Mechanochemically assisted synthesis of pristine Ca(II)Sn(IV)-layered double hydroxides and their amino acid intercalated nanocomposites

  • Zsolt Ferencz
  • Márton Szabados
  • Mónika Ádok-Sipiczki
  • Ákos Kukovecz
  • Zoltán Kónya
  • Pál Sipos
  • István Pálinkó
Original Paper

Abstract

Syntheses of Ca(II)Sn(IV)-layered double hydroxides (LDHs) are attempted by the traditional co-precipitation as well as mechanochemical methods. Both the co-precipitation method and the one-step milling operation proved to be unsuccessful; these methods only produced physical mixtures of hydroxides and carbonates of the two metal ions. However, a two-step milling operation (dry milling followed by milling in the presence of minute amount of water) led to successful synthesis, verified by a range of characterisation methods. Surprisingly, it was found that ball-milling was not even necessary; the reaction proceeded on manual grinding of the components in an agate mortar with a pestle. The preparation of nanocomposites through intercalation of the anions of cystine or valine into Ca(II)Sn(IV)-LDH could also be achieved by the two-step milling method verified again by a range of instrumental methods.

Keywords

Milling Interlayer Spacing Layered Double Hydroxide CoCl2 6H2O Amino Acid Anion 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Notes

Acknowledgements

This research was financed by the OTKA NK106234 and the TÁMOP 4.2.2.A-11/1/KONV-2012-0047 Grants. M.(Á.)S. and M.Sz. gratefully acknowledge the support of TÁMOP 4.2.4.A/2-11-1-2012-0001 National Excellence Program. All these supports are highly appreciated.

References

  1. 1.
    Molls SJ, Christy AG, Génin J-MR, Kameda T, Colombo F (2012) Nomenclature of the hydrotalcite supergroup: natural layered double hydroxides. Miner Mag 76:1289–1336CrossRefGoogle Scholar
  2. 2.
    Evans GD, Slade RCT (2006) Structural aspects of layered double hydroxides. Struct Bond 119:1–87Google Scholar
  3. 3.
    Besserguenev AV, Fogg AM, Francis RJ, Price SJ, O’Hare D, Isupov VP, Tolochko BP (1997) Synthesis and structure of the gibbsite intercalation compounds [LiAl2(OH)6]X {X = Cl, Br, NO3} and [LiAl2(OH)6]Cl·H2O using synchrotron X-ray and neutron powder diffraction. Chem Mater 9:241–247CrossRefGoogle Scholar
  4. 4.
    Velu S, Ramaswamy V, Ramani A, Chanda BM, Sivasanker S (1997) New hydrotalcite-like anionic clays containing Zr4+ in the layers. Chem Commun 21:2107–2108Google Scholar
  5. 5.
    Velu S, Suzuki K, Okazaki M, Osaki T, Tomura S, Ohashi F (1999) Synthesis of new Sn-incorporated layered double hydroxides and their thermal evolution to mixed oxides. Chem Mater 11:2163–2172CrossRefGoogle Scholar
  6. 6.
    Velu S, Suzuki K, Kapoor MP, Tomura S, Ohashi F, Osaki T (2000) Effect of Sn incorporation on the thermal transformation and reducibility of M(II)Al-layered double hydroxides [M(II)) Ni or Co]. Chem Mater 12:719–730CrossRefGoogle Scholar
  7. 7.
    Velu S, Suzuki K, Osaki T (2000) A comparative study of reactions of methanol over catalysts derived from NiAl- and CoAl-layered double hydroxides and their Sn-containing analogues. Catal Lett 69:43–50CrossRefGoogle Scholar
  8. 8.
    Intissar M, Jumas JC, Besse J-P, Leroux F (2003) Reinvestigation of the layered double hydroxide containing tetravalent cations: unambiguous response provided by XAS and Mössbauer spectroscopies. Chem Mater 15:4625–4632CrossRefGoogle Scholar
  9. 9.
    Intissar M, Briois V, Besse J-P, Leroux F (2005) Evidence by XAS of tin oxide coating layered double hydroxide. Phys Scripta T115:288–290CrossRefGoogle Scholar
  10. 10.
    Yang ZQ, Park SE (2007) Baeyer–Villiger reaction of adamantanone over Sn-containing hydrotalcite-like catalysts. Solid State Phenom 119:163–166CrossRefGoogle Scholar
  11. 11.
    Tong DS, Zhou CH, Li MY, Yu WH, Beltramini J, Lin CX, Xu ZP (2010) Structure and catalytic properties of Sn-containing layered double hydroxides synthesized in the presence of dodecylsulfate and dodecylamine. Appl Clay Sci 48:569–574CrossRefGoogle Scholar
  12. 12.
    Saber O (2007) Preparation and characterization of a new nano-structural material: Co–Sn LDH. J Phys Conf Ser 61:825–830CrossRefGoogle Scholar
  13. 13.
    Al Jaafari AI (2010) Controlling the morphology of nano-hybrid materials. Am J App Sci 7:171–177CrossRefGoogle Scholar
  14. 14.
    Cavani F, Trifiró F, Vaccari A (1991) Hydrotalcite-type anionic clays: preparation, properties and applications. Catal Today 11:173–301CrossRefGoogle Scholar
  15. 15.
    Tongamp W, Zhang Q, Saito F (2008) Mechanochemical route for synthesizing nitrate form of layered double hydroxide. Powder Technol 185:43–48CrossRefGoogle Scholar
  16. 16.
    Woo MA, Woo KT, Paek M-J, Ha H-W, Choy J-H, Hwang S-J (2011) Phosphate-intercalated Ca–Fe-layered double hydroxides: crystal structure, bonding character, and release kinetics of phosphate. J Solid State Chem 184:171–176CrossRefGoogle Scholar
  17. 17.
    Fogg AM, Dunn JS, Shyu SG, Cary DR, O’Hare D (1998) Selective ion-exchange intercalation of isomeric dicarboxylate anions into the layered double hydroxide [LiAl2(OH)6]Cl·H2O. Chem Mater 10:351–355CrossRefGoogle Scholar
  18. 18.
    Nakayama H, Wada N, Tsuhako M (2004) Intercalation of amino acids and peptides into Mg–Al layered double hydroxide by reconstruction method. Int J Pharm 269:469–478CrossRefGoogle Scholar
  19. 19.
    Qi F, Zhang X, Li S (2013) A novel method to get methotrexatum/layered double hydroxides intercalation compounds and their release properties. J Phys Chem Solids 74:1101–1108CrossRefGoogle Scholar
  20. 20.
    Jimenez-Sanchidrian C, Hidalgo J, Llamas R, Ruiz J (2006) Baeyer–Villiger oxidation of cyclohexanone with hydrogen peroxide/benzonitrile over hydrotalcites as catalysts. Appl Catal A 312:86–94CrossRefGoogle Scholar
  21. 21.
    Seftel EM, Popovici E, Mertens M, Stefaniak EA, van Grieken R, Cool P, Vansant EF (2008) Sn(IV)-containing layered double hydroxides as precursors for nano-sized ZnO/SnO2 photocatalysts. Appl Catal B 84:699–705CrossRefGoogle Scholar
  22. 22.
    Dvininov E, Ignat M, Barvinschi P, Smithers MA, Popovici EN (2010) New SnO2/MgAl-layered double hydroxide composites as photocatalysts for cationic dyes bleaching. J Hazard Mater 177:150–158CrossRefGoogle Scholar
  23. 23.
    Kapoor MP, Matsumura Y (2004) Liquid-phase methanol carbonylation catalyzed over tin promoted nickel–aluminium layered double hydroxide. Catal Today 93–95:287–291CrossRefGoogle Scholar
  24. 24.
    Gracin D, Štrukil V, Frisčić Tomislav, Halasz I, Užarevic K (2014) Laboratory real-time and in situ monitoring of mechanochemical milling reactions by Raman spectroscopy. Angew Chem Int Ed 53:6193–6197CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 2014

Authors and Affiliations

  • Zsolt Ferencz
    • 1
    • 2
  • Márton Szabados
    • 1
    • 2
  • Mónika Ádok-Sipiczki
    • 1
    • 2
  • Ákos Kukovecz
    • 3
    • 4
  • Zoltán Kónya
    • 3
    • 5
  • Pál Sipos
    • 2
    • 6
  • István Pálinkó
    • 1
    • 2
  1. 1.Department of Organic ChemistryUniversity of SzegedSzegedHungary
  2. 2.Materials and Solution Structure Research Group, Institute of ChemistryUniversity of SzegedSzegedHungary
  3. 3.Department of Applied and Environmental ChemistryUniversity of SzegedSzegedHungary
  4. 4.MTA-SZTE “Lendület” Porous Nanocomposites Research GroupSzegedHungary
  5. 5.MTA-SZTE Reaction Kinetics and Surface Chemistry Research GroupSzegedHungary
  6. 6.Department of Inorganic and Analytical ChemistryUniversity of SzegedSzegedHungary

Personalised recommendations