Journal of Materials Science

, Volume 49, Issue 22, pp 7688–7696 | Cite as

Characterization of porous graphitic monoliths from pyrolyzed wood

  • A. Gutiérrez-Pardo
  • J. Ramírez-Rico
  • A. R. de Arellano-López
  • J. Martínez-Fernández


Porous graphitic carbons were obtained from wood precursors using Ni as a graphitization catalyst during pyrolysis. The structure of the resulting material retains that of the original wood precursors with highly aligned, hierarchical porosity. Thermal characterization was performed by means of thermogravimetry and differential scanning calorimetry, and the onset temperature for graphitization was determined to be ~900 °C. Structural and microstructural characterization was performed by means of electron microscopy, electron and x-ray diffraction, and Raman spectroscopy. The effect of maximum pyrolysis temperature on the degree of graphitization was assessed. No significant temperature effect was detected by means of Raman scattering in the range of 1000–1400 °C, but at temperatures over the melting point of the catalyst, the formation of graphite grains with long-range order was detected.


Pyrolysis Pyrolysis Temperature Electrochemical Energy Storage Lower Pyrolysis Temperature Carbon Monolith 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.



This work was supported by the Junta de Andalucía under grant No. P09-TEP-5152. Electron microscopy and x-ray diffraction measurements were performed at the CITIUS central services of the University of Seville. Raman scattering measurements were performed at the ICMS. A. Gutiérrez-Pardo is grateful to the Junta de Andalucía for a predoctoral grant.


  1. 1.
    Sevilla M, Fuertes AB (2013) Fabrication of porous carbon monoliths with a graphitic framework. Carbon 56:155–166CrossRefGoogle Scholar
  2. 2.
    Ruiz V, Blanco C, Santamaria R et al (2009) An activated carbon monolith as an electrode material for supercapacitors. Carbon 47:195–200CrossRefGoogle Scholar
  3. 3.
    Garcia-Gomez A, Miles P, Centeno TA, Rojo JM (2010) Why carbon monoliths are better supercapacitor electrodes than compacted pellets. Electrochem Solid State 13:A112–A114CrossRefGoogle Scholar
  4. 4.
    Sevilla M, Fuertes AB, Mokaya R (2011) Preparation and hydrogen storage capacity of highly porous activated carbon materials derived from polythiophene. Int J Hydrogen Energy 36:15658–15663CrossRefGoogle Scholar
  5. 5.
    Gogotsi Y, Portet C, Osswald S et al (2009) Importance of pore size in high-pressure hydrogen storage by porous carbons. Int J Hydrogen Energy 34:6314–6319CrossRefGoogle Scholar
  6. 6.
    Eltmimi AH, Barron L, Rafferty A et al (2010) Preparation, characterisation and modification of carbon-based monolithic rods for chromatographic applications. J Sep Sci 33:1231–1243Google Scholar
  7. 7.
    Church TL, Fallani S, Liu J, Zhao M, Harris AT (2012) Novel biomorphic Ni/SiC catalysts that enhance cellulose conversion to hydrogen. Catal Today 190:98–106CrossRefGoogle Scholar
  8. 8.
    Guo YG, Hu JS, Wan LJ (2008) Nanostructured materials for electrochemical energy conversion and storage devices. Adv Mater 20:2878–2887CrossRefGoogle Scholar
  9. 9.
    Sevilla M, Sanchis C, Valdes-Solis T, Morallon E, Fuertes AB (2007) Synthesis of graphitic carbon nanostructures from sawdust and their application as electrocatalyst supports. J Phys Chem C 111:9749–9756CrossRefGoogle Scholar
  10. 10.
    Sevilla M, Fuertes AB (2009) The production of carbon materials by hydrothermal carbonization of cellulose. Carbon 47:2281–2289CrossRefGoogle Scholar
  11. 11.
    Sevilla M, Fuertes AB (2010) Graphitic carbon nanostructures from cellulose. Chem Phys Lett 490:63–68CrossRefGoogle Scholar
  12. 12.
    Glatzel S, Schnepp Z, Giordano C (2013) From paper to structured carbon electrodes by inkjet printing. Angew Chem Int Edit 52:2355–2358CrossRefGoogle Scholar
  13. 13.
    Peng C, Yan XB, Wang RT, Lang JW, Ou YJ, Xue QJ (2013) Promising activated carbons derived from waste tea-leaves and their application in high performance supercapacitors electrodes. Electrochim Acta 87:401–408CrossRefGoogle Scholar
  14. 14.
    Liu MC, Kong LB, Zhang P, Luo YC, Kang L (2012) Porous wood carbon monolith for high-performance supercapacitors. Electrochim Acta 60:443–448CrossRefGoogle Scholar
  15. 15.
    Byrne CE, Nagle DC (1997) Cellulose derived composites—A new method for materials processing. Mater Res Innov 1:137–144CrossRefGoogle Scholar
  16. 16.
    Byrne CE, Nagle DC (1997) Carbonization of wood for advanced materials applications. Carbon 35:259–266CrossRefGoogle Scholar
  17. 17.
    Oya A, Marsh H (1982) Phenomena of catalytic graphitization. J Mater Sci 17:309–322. doi: 10.1007/BF00591464 CrossRefGoogle Scholar
  18. 18.
    Byrne CE, Nagle DC (1997) Carbonized wood monoliths—characterization. Carbon 35:267–273CrossRefGoogle Scholar
  19. 19.
    Cheng HM, Endo H, Okabe T, Saito K, Zheng GB (1999) Graphitization behavior of wood ceramics and bamboo ceramics as determined by X-ray diffraction. J Porous Mater 6:233–237CrossRefGoogle Scholar
  20. 20.
    Pappacena KE, Gentry SP, Wilkes TE et al (2009) Effect of pyrolyzation temperature on wood-derived carbon and silicon carbide. J Eur Ceram Soc 29:3069–3077CrossRefGoogle Scholar
  21. 21.
    Johnson MT, Faber KT (2011) Catalytic graphitization of three-dimensional wood-derived porous scaffolds. J Mater Res 26:18–25CrossRefGoogle Scholar
  22. 22.
    Sadezky A, Muckenhuber H, Grothe H, Niessner R, Poschl U (2005) Raman micro spectroscopy of soot and related carbonaceous materials: spectral analysis and structural information. Carbon 43:1731–1742CrossRefGoogle Scholar
  23. 23.
    Steiner SA, Baumann TF, Bayer BC et al (2009) Nanoscale zirconia as a nonmetallic catalyst for graphitization of carbon and growth of single- and multiwall carbon nanotubes. J Am Chem Soc 131:12144–12154CrossRefGoogle Scholar
  24. 24.
    Kercher AK, Nagle DC (2002) Evaluation of carbonized medium-density fiberboard for electrical applications. Carbon 40:1321–1330CrossRefGoogle Scholar
  25. 25.
    Kercher AK, Nagle DC (2003) Microstructural evolution during charcoal carbonization by X-ray diffraction analysis. Carbon 41:15–27CrossRefGoogle Scholar
  26. 26.
    Masters KJ, Mcenaney B (1984) The development of structure and microporosity in cellulose carbon. Carbon 22:595–601CrossRefGoogle Scholar
  27. 27.
    Oya A, Yoshida S, Alcanizmonge J, Linaressolano A (1995) Formation of mesopores in phenolic resin-derived carbon-fiber by catalytic activation using cobalt. Carbon 33:1085–1090CrossRefGoogle Scholar
  28. 28.
    Kaarik M, Arulepp M, Karelson M, Leis J (2008) The effect of graphitization catalyst on the structure and porosity of SiC derived carbons. Carbon 46:1579–1587CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 2014

Authors and Affiliations

  • A. Gutiérrez-Pardo
    • 1
  • J. Ramírez-Rico
    • 1
  • A. R. de Arellano-López
    • 1
  • J. Martínez-Fernández
    • 1
  1. 1.Departamento Física de la Materia Condensada – ICMSUniversidad de Sevilla-CSICSevillaSpain

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