Journal of Materials Science

, Volume 49, Issue 20, pp 6967–6974 | Cite as

Behavior of indium oxide in zinc phosphate and borophosphate glasses

  • Ladislav Koudelka
  • Antonín Račický
  • Petr Mošner
  • Ivana Rösslerová
  • Lionel Montagne
  • Betrand Revel


The effect of indium oxide on the structure and properties of zinc phosphate and zinc borophosphate glasses has been investigated in the series (50−x)ZnO–xIn2O3–50P2O5 and 30ZnO–(20−x)B2O3–xIn2O3–50P2O5 with x = 0–20 mol% In2O3 in both series. Their physical properties were measured, and their structure was studied by Raman and NMR spectroscopy. Glass transition temperature in the phosphate glass series increases with increasing In2O3 content as well as their chemical durability. The observed changes in the 31P MAS NMR spectra with increasing In2O3 content revealed the depolymerization of phosphate chains due to the replacement of ZnO by In2O3 resulting in an increase in the O/P ratio in the glass structure. 11B MAS NMR spectra revealed the presence of BO4 units in the glass structure in the borophosphate glass series; these spectra give no evidence for the formation of B–O–In bonds. Their glass transition temperature slightly decreases with increasing In2O3 content. The values of the molar volume in these glasses do not change substantially when B2O3 is replaced by In2O3. This can be ascribed not only to differences in boron (BO4) and indium (InO6) coordination, but also to a higher ionicity of In···O bonds in comparison with B–O bonds. The obtained data resulted in the conclusion that indium oxide behaves as a modifying oxide in both glasses.


B2O3 In2O3 Phosphate Glass Vibrational Band Indium Oxide 
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The Czech authors are grateful for the financial support from the Grant Agency of the Czech Republic (Grant No. 13-00355S). The FEDER, Region Nord Pas-de-Calais, Ministère de l’Education Nationale de l’Enseignement Superieur et de la Recherche, CNRS, and USTL are acknowledged for funding of NMR spectrometers.


  1. 1.
    Clinton JM, Coffeen WW (1984) Low-melting glasses in the system B2O3–ZnO–CaO–P2O5. Am Ceram Soc Bull 63:1401–1404Google Scholar
  2. 2.
    Brow RK, Tallant D (1997) Structural design of sealing glasses. J Non-Cryst Solids 222:396–406CrossRefGoogle Scholar
  3. 3.
    Koudelka L, Mošner P (2000) Borophosphate glasses of the ZnO–B2O3–P2O5 system. Mater Lett 421:194–199CrossRefGoogle Scholar
  4. 4.
    Sales BC, Boatner LA (1987) Optical, structural and chemical characteristics of lead-indium phosphate and lead-scandium phosphate glasses. J Am Ceram Soc 70:615–621CrossRefGoogle Scholar
  5. 5.
    Suzuya K, Loong CK, Price DL, Sales BC, Boatner LA (1999) The structure of lead–indium phosphate and lead–scandium phosphate glasses. J Non-Cryst Solids 258:48–56CrossRefGoogle Scholar
  6. 6.
    Baskaran GS, Flower GL, Rao DK, Veeraiah N (2007) Structural role of In2O3 in PbO–P2O5–As2O3 glass system by means of spectroscopic and dielectric studies. J Alloys Compd 431:303–312CrossRefGoogle Scholar
  7. 7.
    Sharma MVNVD, Sarma AV, Rao RB (2009) Electrical characterization and relaxation behavior of lithium-indium-phosphate glasses via impedance spectroscopy. Turk J Phys 33:87–100Google Scholar
  8. 8.
    Massiot D, Fayon F, Capron M, King I, Le Calvé S, Alonso B, Durand JO, Bujoli B, Gan Z, Hoatson G (2002) Modelling one- and two-dimensional solid-state NMR spectra. Magn Reson Chem 40:70–76CrossRefGoogle Scholar
  9. 9.
    Brow R (2000) Review: the structure of simple phosphate glasses. J Non-Cryst Solids 263–264:1–28CrossRefGoogle Scholar
  10. 10.
    Montagne L, Palavit G, Deleval R (1997) 31P NMR in (100-x)(NaPO3)-xZnO glasses. J Non-Cryst Solids 215:1–10CrossRefGoogle Scholar
  11. 11.
    Nelson BN, Exarhos GJ (1979) Vibrational spectroscopy of cation-site interactions in phosphate glasses. J Chem Phys 71:2739–2747CrossRefGoogle Scholar
  12. 12.
    Brow RK, Tallant DR, Myers ST, Phifer CC (1995) The short-range structure of zinc polyphosphate glasses. J Non-Cryst Solids 191:5–55CrossRefGoogle Scholar
  13. 13.
    Bobovich YS (1962) Issledovanije struktury stekloobraznych fosfatov s pomoshtchju spektrov kombinacionnovo rassejanija sveta. Opt Spectrosk 13:492–497Google Scholar
  14. 14.
    Ducel JF, Videau JJ, Suh KS, Senegal J (1994) 31P MAS and 11B NMR study of sodium rich borophosphate glasses. Phys Chem Glasses 35:10–16Google Scholar
  15. 15.
    Koudelka L, Mošner P, Pospíšil J, Montagne L, Palavit G (2005) Structure and properties of titanium–zinc borophosphate glasses. J Solid State Chem 178:1837–1843CrossRefGoogle Scholar
  16. 16.
    Koudelka L, Pospíšil J, Mošner P, Montagne L, Delevoye L (2008) Structure and properties of potassium niobato-borophosphate glasses. J Non-Cryst Solids 354:129–133CrossRefGoogle Scholar
  17. 17.
    Koudelka L, Rösslerová I, Černošek Z, Mošner P, Montagne L, Revel B, Tricot G (2012) Structure and properties of lead borophosphate glasses doped by molybdenum oxide. Phys Chem Glass Eur J Glass Sci Technol 53:245–253Google Scholar
  18. 18.
    Šubčík J, Koudelka L, Mošner P, Gregora I, Montagne L, Delevoye P (2009) WO3-doped zinc borophosphate glasses. Phys Chem Glass Eur J Glass Sci Technol 50:243–248Google Scholar
  19. 19.
    Strandford GT, Condrate RA Sr, Cornilsen BC (1981) The Raman spectrum of α-zinc pyrophosphate. J Mol Struct 73:231–234CrossRefGoogle Scholar
  20. 20.
    Nyquist RA, Putzig CL, Leugers MA (1997) The handbook of infrared and Raman spectra of inorganic compounds and organic salts, vol 1. Academic Press, San DiegoGoogle Scholar

Copyright information

© Springer Science+Business Media New York 2014

Authors and Affiliations

  • Ladislav Koudelka
    • 1
  • Antonín Račický
    • 1
  • Petr Mošner
    • 1
  • Ivana Rösslerová
    • 1
  • Lionel Montagne
    • 2
  • Betrand Revel
    • 2
  1. 1.Department of General and Inorganic Chemistry, Faculty of Chemical TechnologyUniversity of PardubicePardubiceCzech Republic
  2. 2.UCCS - UMR CNRS 8181, USTLUniversité Lille Nord de FranceVilleneuve d’AscqFrance

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