Journal of Materials Science

, Volume 48, Issue 11, pp 4097–4108 | Cite as

Comparison of two soft chemistry routes for the synthesis of mesoporous carbon/β-SiC nanocomposites

  • Xavier Deschanels
  • Damien Hérault
  • Guilhem Arrachart
  • Cyrielle Rey
  • Agnès Grandjean
  • Guillaume Toquer
  • Renaud Podor
  • Thomas Zemb
  • Geneviève Cerveau
  • Robert Corriu
Article

Abstract

We compare the influence of using either molecular or colloidal precursors on the synthesis of a ceramic material containing SiC and porous carbon. Remarkably, the temperature of synthesis for crystalline SiC is independent of the route chosen. The excess carbon in the initial mixture is the source of the excess porous carbon that binds to the crystalline domains of SiC in the final products. Interestingly, increasing the initial area of surface contact between carbon and silicon in the ceramic precursor results in different porosities in the ‘meso’ range. Simultaneous control of the size and the relative amounts of Si and C in the precursors allows control to be exerted over the nature and texture of the final powders. A simple and general mechanism is herein proposed to explain the evolution of the surface area as a function of the volume fraction of residual carbon in the synthesised ceramic.

Supplementary material

10853_2013_7222_MOESM1_ESM.doc (76 kb)
Supplementary material 1 (DOC 76 kb)

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Copyright information

© Springer Science+Business Media New York 2013

Authors and Affiliations

  • Xavier Deschanels
    • 1
  • Damien Hérault
    • 2
  • Guilhem Arrachart
    • 1
  • Cyrielle Rey
    • 1
  • Agnès Grandjean
    • 1
  • Guillaume Toquer
    • 1
  • Renaud Podor
    • 1
  • Thomas Zemb
    • 1
  • Geneviève Cerveau
    • 3
  • Robert Corriu
    • 3
  1. 1.ICSM-UMR 5257, CEA/CNRS/UM2/ENSCM MarcouleBagnols-sur-CèzeFrance
  2. 2.Centrale Marseille, Aix Marseille UniversitéMarseilleFrance
  3. 3.Institut Charles Gerhardt, UMR 5253Université de Montpellier 2MontpellierFrance

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