Transient liquid phase (TLP) bonding is a relatively new bonding process that joins materials using an interlayer. On heating, the interlayer melts and the interlayer element (or a constituent of an alloy interlayer) diffuses into the substrate materials, causing isothermal solidification. The result of this process is a bond that has a higher melting point than the bonding temperature. This bonding process has found many applications, most notably the joining and repair of Ni-based superalloy components. This article reviews important aspects of TLP bonding, such as kinetics of the process, experimental details (bonding time, interlayer thickness and format, and optimal bonding temperature), and advantages and disadvantages of the process. A wide range of materials that TLP bonding has been applied to is also presented. Partial transient liquid phase (PTLP) bonding is a variant of TLP bonding that is typically used to join ceramics. PTLP bonding requires an interlayer composed of multiple layers; the most common bond setup consists of a thick refractory core sandwiched by thin, lower-melting layers on each side. This article explains how the experimental details and bonding kinetics of PTLP bonding differ from TLP bonding. Also, a range of materials that have been joined by PTLP bonding is presented.
Transient liquid phase (TLP) bonding
Transient liquid phase (TLP) bonding is a joining process that was developed to improve upon existing bonding technologies. Specifically, this process was patented by Paulonis et al. in 1971  to overcome deficiencies of then current bonding techniques in joining Ni-based superalloys [2–6]. TLP bonding’s main advantage is that resulting bonds have a higher melting point than the bonding temperature. This bonding process characteristically lies between diffusion bonding and brazing—for this reason, it is commonly called diffusion brazing. The process is also referred to by names such as transient insert liquid metal bonding  and is sometimes mistakenly referred to as diffusion bonding (which by definition relies solely on solid-state diffusion). See reference  for a detailed history of TLP bonding and its many names.
TLP bonding process
The TLP bonding process involves the following steps:
setting up the bond
heating to the specified bonding temperature to produce a liquid in the bond region
holding the assembly at the bonding temperature until the liquid has isothermally solidified due to diffusion
homogenizing the bond at a suitable heat-treating temperature.
Bond setup usually consists of placing a thin interlayer between the substrates, but the interlayer material is occasionally placed outside the joint to flow in by capillarity [6, 7, 9–15] as is done in many brazing processes. The interlayer material can be in many different formats:
evaporating an element out of the substrate material to create a “glazed” surface .
A pressure is usually applied to the bonding assembly to keep the substrates aligned and to promote bonding; specific pressures are categorized in Table 1 by their nearest order of magnitude. For example, pressures in the nearest order range of 10 MPa [log(10) = 1] lie between 3.1623 MPa [log(3.1623) = 0.5] and 31.623 MPa [log(31.623) = 1.5]. Occasionally, the substrates are held a fixed distance apart rather than applying a pressure, but this tends to cause porosity in the final bond [6, 19, 43].
Heating of the bond assembly and homogenizing of the bond is performed with many different equipment setups and can occur by the following methods:
The bonding process is usually confined in a vacuum [3–5, 7, 12, 14–17, 20–30, 35, 38–40, 46–58, 61–63, 65, 66, 68–72, 76–83, 86–88, 93–100, 103–105, 108, 110, 112–115, 117, 119, 122–127, 130, 132–138, 140–157], although an inert atmosphere, such as argon, can be used [6, 11, 14, 32, 33, 43, 45, 60, 67, 74, 75, 90, 111, 121, 134, 158, 159]. On rare occasions, TLP bonding is performed under a different atmosphere, such as nitrogen , hydrogen , nitrogen and hydrogen , or open air . The vacuum pressures used in the experiments referenced above are normally distributed about 0.1 μmHg (millitorr) with minimum and maximum values of 0.00015 and 34 μmHg, respectively.
TLP bonding kinetics
melting of the interlayer
dissolution of the substrate material
homogenization of the bond region.
Figure 1 is a schematic of TLP bonding kinetics for a binary system with complete solid solubility.Footnote 1 The concentration profiles in the lower part of the figure are numbered according to the current temperature of the bond, which is shown in the phase diagram above them. The following analysis assumes that (1) the interlayer and substrate materials are pure elements (2) the bond region has a uniform temperature as it is being heated (3) the diffusion rates of liquid metals are infinite, and (4) the substrate melts back and solidifies as a plane. The second assumption is likely true since the interlayer is quite thin and generally composed of metallic elements that characteristically have moderate to high thermal conductivities. The third assumption is based on liquid diffusivity data often being orders of magnitude greater than solid diffusivity data . The fourth assumption is necessary to characterize the process in one dimension.
Concentration profile 1 (CP1) in Fig. 1 shows the TLP bonding setup at room temperature. The interlayer element (i) is sandwiched between two pieces of the substrate material element (s). The thickness of the bond region in Fig. 1 has been exaggerated to display changes in the concentration profile. The interlayer can be composed of a single element, an alloy, or a multi-layer combination of elements and/or alloys.
Interlayer thicknesses for TLP bonding are summarized in Table 2. Besides the frequency of each range, common thicknesses are also included for those ranges derived from at least ten references. These common thicknesses comprise at least one-third of the specified range and include plus or minus two percent to account for differences between metric and English units (e.g., 0.004 inches equals 101.6 μm and should be categorized with 100 μm). The most common interlayer thickness is 50 μm, comprising almost 90% of the 40–60 μm range, or about 20% of all reported TLP bond thicknesses.
As the bond assembly is heated, the interlayer begins to diffuse into the substrate materials (CP2). The amount of diffusion that occurs is dependent upon the interdiffusion coefficient between the substrate and interlayer materials as well as the heating rate.
Upon reaching the interlayer element’s melting point (CP3), the pure portion of the interlayer liquefies (L). Heating of the bond region continues until the bonding temperature has been reached. The bonding temperature is usually well above the interlayer’s melting point to ensure complete melting of the interlayer and to increase the rate of diffusion (see Optimal bonding temperature).
During heating past the melting point, the concentrations of the liquid region follow the solidus (c4,S) and liquidus (c4,L) lines of the phase diagram (CP4). This causes the liquid region to melt back, or dissolve, the substrate material to conserve mass. The movement of the solid–liquid interface continues until the bonding temperature has been reached (CP5a); at this point the liquid has attained its maximum width and has consumed some of the diffused solute. The amount of melt-back is dependent upon the solidus (c5,S) and liquidus (c5,L) compositions for the given material system at the bonding temperature (see Optimal bonding temperature). The main two effects that lower melt-back distance are (1) significant diffusion of the interlayer material into the substrate before melting (see Critical interlayer thickness) and (2) loss of liquid due to wetting of the substrate’s sides  or a high bonding pressure that squeezes liquid out [22, 44, 62, 134, 165].
Many materials that are joined by TLP bonding have carefully designed microstructures to achieve certain mechanical properties. Too much melt-back of the substrate by the liquid interlayer can have detrimental effects on the final bond in addition to lengthening the isothermal solidification time (see Critical interlayer thickness). And, in some systems melt-back can reach five to fifteen times the original interlayer thickness [43, 121, 146]. To prevent drastic melt-back that can adversely affect the microstructure, the interlayer should be thin [57, 62], of a eutectic composition , or of a composition similar to the substrate material .
After the liquid interlayer has reached its maximum width, the interlayer material diffuses into the substrates at a rate somewhere between the diffusivity of the liquid and solid [25, 43, 85, 163]. As this diffusion occurs isothermally, the liquid region contracts (CP5b) to conserve mass as the solidus and liquidus concentrations are now fixed. Isothermal solidification occurs until all of the liquid has disappeared (CP5c). At this point, the TLP bonding process can be stopped if desired . The bond already has an elevated remelting temperature (T 5) compared to the melting temperature of the interlayer (T 3).
In most cases TLP bonding is continued in order to homogenize the bond. This can be an extended time in the same heating apparatus or a post-bond heat treatment applied at some other time . Furthermore, if the substrate material’s microstructure is extremely sensitive, this stage can be conducted at a lower temperature [2, 9]. In either case, the bond undergoes homogenization for some predetermined time which causes smoothing of the solute peak (CP5d) that remained at the end of isothermal solidification (CP5c). The resulting remelting temperature of the bond in this case is TR,P. If the peak concentration (c5,P) is within the room-temperature solid-solubility limit of the binary system, the precipitation of strength-reducing intermetallic compounds upon cooling will be avoided [12, 110, 147, 150, 160].
If the bond is homogenized for a sufficient amount of time, there is no gradient in the concentration profile (CP5e) and the bond’s remelting temperature is even higher (T R,F). However, despite the increases in bond remelting temperature that can be achieved by complete homogenization, an adequate homogenization time is usually determined by a sufficiently high bond strength [2, 24, 26, 42, 83, 103, 122, 123, 146, 150] or economic considerations that limit furnace time [77, 125, 173]. Nonetheless, the bond’s remelting temperature is often hundreds of degrees (°C) above the melting point of the interlayer and can be about 1000 °C higher if refractory metals such as Ir, Mo, Nb, Os, Re, Ta, or W are used as the substrate or if low melting-point metals such as Al, Ga, In, Mg, Pb, Sb, Sn, or Zn are used as the interlayer.
Time frame of TLP bonding
The time frame of TLP bonding is highly dependent on the material system (e.g., phase diagram particulars, diffusion coefficients, grain size [18, 25, 142]) and the experimental parameters (e.g., interlayer thickness, bonding pressure, bonding temperature). The duration of each discrete stage of TLP bonding lies within the following ranges:
Heating to the bonding temperature, CP1–5a: less than a minute to about an hour; dependent on the method of heating, the heating rate of the heating apparatus, and the substrate material’s thermal properties
Isothermal solidification, CP5a–5c: minutes [7, 25, 36, 37, 56, 74, 77, 95, 96, 105, 121, 125, 153] to hours [7, 11, 33, 36, 37, 43, 57, 58, 105, 146, 157, 175], although it can occur in less than a minute [73, 161] or take more than a day 
The general trend is that initial melting of the interlayer occurs an order of magnitude faster than melting back of the substrate, which occurs an order of magnitude faster than isothermal solidification, which occurs an order of magnitude faster than complete homogenization. Isothermal solidification ends up being the limiting, or controlling, time in producing a successful TLP bond [12, 36, 104, 125, 135, 138, 166, 167]. While the homogenization stage takes longer if carried to completion, it rarely is. As previously stated, homogenization can be performed during a subsequent heat treatment or skipped in some cases; it can even occur once the part is in service.
The foregoing explanation of TLP bonding kinetics also applies to eutectic systems when the interlayer is a eutectic composition alloy. The kinetics are slightly different (and more importantly, TLP bonding takes much longer) for a eutectic system when pure elements are used. (See references [19, 44] for particulars of eutectic system kinetics). Tuah-Poku et al.  reported a drastic decrease in time to isothermally solidify by changing the interlayer: 200 h when using the pure element as compared to 8 h when using the eutectic composition. This occurs because (1) the interlayer has to undergo a certain amount of solid-state diffusion with the substrate at the bonding temperature before any liquid appears and (2) melt-back of the substrate is then greater.
Critical interlayer thickness
During initial heating, the interlayer element diffuses into the substrates. The magnitude of diffusion depends upon the specific material combination, but all solid-state diffusion rates increase as the temperature rises. Depending on the heating rate and the thickness of the interlayer, the amount of diffusion can significantly decrease the interlayer’s width. In fact, for a combination of high diffusion rate, slow heating, and/or thin interlayer, it is possible to diffuse all of the interlayer material into the substrate before reaching the interlayer melting point [114, 173], although this is a rare occurrence. Because TLP bonding requires the formation of a bulk liquid phase [9, 109, 114] to create a consolidated, void-free bond while also increasing diffusion rates, the interlayer must exceed a minimum, or critical, thickness [105, 114].
In addition to the parameters listed above, the critical interlayer thickness has been shown to depend on other variables such as applied clamping force, solid/liquid surface tension, surface roughness of the substrate, and intermetallic formation [18, 94, 114]. In short, experiments must be conducted for each material combination to empirically reveal its critical interlayer thickness.
On the other hand, analytical models of TLP bonding indicate that the isothermal solidification process time is roughly proportional to the square of the interlayer thickness [9, 18, 19, 25, 36, 44, 86, 104, 110, 114, 124, 138, 161, 173, 175, 176]; experimental data often corroborates this trend [3, 26, 43, 44, 71, 86, 88, 153]. Therefore, to minimize bonding time, an interlayer slightly thicker than the critical thickness is ideal.
Optimal bonding temperature
The bonding temperature is sometimes completely limited by the microstructural stability of the substrate material [7, 9, 87, 125]. If, however, the substrate material allows flexibility in selecting an optimized bonding temperature, a minimum isothermal solidification time (and therefore bonding time) can be achieved at a certain temperature.
If phase diagram and diffusion data are available for the material system in question, the isothermal solidification time can be characterized with respect to temperature. However, it is usually the case that experiments are the only way to discover this relationship. In general, the relationship is parabolic, yielding a minimum isothermal solidification time at a given intermediate temperature (between the melting points of the interlayer and substrate materials) [9, 18, 43, 50, 78, 79, 159, 162]. And yet, in some cases the variables of the system yield either (1) a monotonically increasing time, in which case the optimal bonding temperature is just above the interlayer’s melting point, [6, 9, 43, 114, 158, 162] or (2) a monotonically decreasing time, in which case the optimal bonding temperature is as high as the substrate material allows [4, 104, 114, 135, 141].
The behavior of this trend is highly system dependent and results in part from the interplay of the diffusion rate and the phase diagram of the system [19, 43, 50]. As the temperature is increased, the rate of diffusion increases exponentially. In addition, intermetallic regions, which tend to slow down the rate of diffusion [60, 110], can often be avoided by raising the temperature. As shown in Fig. 2, Pb diffusing into Pd at 400 °C (T 1) would pass through five intermetallic regions. T 2 and T 3 are ideal temperatures for passing through just two and one intermetallic regions, respectively. T 4 completely avoids the intermetallic regions while still providing a wide solubility range for the liquid to solidify.
In addition to intermetallics, the shape of the solidus and liquidus lines plays an important role in TLP bonding kinetics and the optimal bonding temperature. Figure 3 demonstrates extremes of solidus and liquidus lines in a binary system with complete solid solubility. The composition profiles below each set of phase diagrams demonstrate the initial melting and isothermal solidification behavior of the interlayer for each case. It is assumed that all four systems (1) have the same diffusion coefficient and (2) are heated instantaneously. The latter assumption is accurate for many material systems since complete melt-back often consumes much of the solute that has diffused into the substrate (see CP5a in Fig. 1). The top concentration profiles illustrate initial melt-back of a pure interlayer—the dotted line is the initial interlayer and the solid line is the molten interlayer. The bottom concentration profiles illustrate isothermal solidification for all four systems after a set time.
The partition coefficient (k) is included in the diagram and is defined as:
where c S and c L are the solidus and liquidus compositions of the interlayer element.
Systems a and b in Fig. 3 have the same convex-shaped liquidus line and therefore experience the same amount of melt-back (see the top concentration profiles). The same is true for the concave-shaped liquidus line in systems c and d. Systems a and c have the same partition coefficient (0.9). The same is true for systems b and d (0.4).
A few principles of TLP bonding kinetics can be gleaned from this figure. First, the convex-shaped liquidus line (a and b) prevents melt-back from occurring to a large extent, whereas the concave-shaped liquidus line (c and d) causes much more melt-back. Second, isothermal solidification occurs faster in systems with a higher partition coefficient (a and c). To conserve mass, the volume of solidified liquid is equal to the change in the concentration profile of the solid region. The width of isothermal solidification in an arbitrary time period is equal to the ratio of this volume to the difference between the liquidus and solidus compositions, or, written another way:
Although systems a and c have the same partition coefficient, because the liquidus and solidus compositions of system c are closer to zero, they are also closer to each other, causing isothermal solidification to occur slightly faster (see Fig. 3).
If the substrate material has a sensitive microstructure that could be damaged by significant melt-back, then phase diagrams such as systems c and d should be avoided. Systems b and d will take much longer to isothermally solidify, raising operating costs.
Systems a and c are quite similar in rate of isothermal solidification. Because the solidus composition of system c is closer to the completely homogenized composition (shown as an x on the gray line), homogenization of the solute peak after isothermal solidification will likely proceed more rapidly than in system a. However, because the solidus line of system a has a convex shape, increases in bond remelting temperature due to homogenization will likely occur faster and be larger in this system.
Modeling of TLP bonding
Analytical models have been developed by many researchers for the four stages of TLP bonding to provide quick estimates or general trends, such as those illustrated in the previous section. Equations for and descriptions of TLP bonding analytical models are included in references [8, 19, 162, 178]. Assumptions made for these models are similar to those made in this article (see TLP bonding kinetics). In some cases these equations provide good results, but for many systems these simplified, binary-system approaches do not supply accurate estimates [5, 8, 38, 78, 79, 86]. This is due in part to the diffusion coefficients being assumed independent of composition.
Some complexities of TLP bonding are quite difficult to model. For example, grain boundaries can cause isothermal solidification to occur at a different rate than that predicted by analytical models using a bulk diffusion coefficient [25, 36, 37]. Indeed, grain boundary diffusion is faster than bulk diffusion in a certain temperature range (based on the alloy’s melting point) . Grain boundary diffusion rates also increase as the substrate material’s grain size decreases . Further, grain boundaries can be penetrated by the liquid to cause a non-planar solidification front, thereby increasing the area over which diffusion occurs [5, 11, 18, 138]. See references [180, 181] for more information on the effect of grain boundaries in TLP bonding.
Another interesting deviation is that isothermal solidification can occur in two different “regimes” [38, 50, 138]. The faster solute element of a multi-component interlayer controls the rate of solidification for the first regime. Then, a second solute element controls the rate of solidification during the second regime, resulting in complex concentration–time profiles.
Numerical models can account for some of the complexities of TLP bonding to accurately predict bonding kinetics [7, 8, 161, 162, 168, 173, 176, 179, 182, 183] and can even be extended to multi-component systems [174, 184]. Despite the complexities and extra time required in numerical modeling, especially for multi-component systems, the limiting factor is most often the lack of necessary diffusion data [7, 8, 178]. But, when the necessary data is available, modeling of TLP bonding can drastically reduce the number of experiments required to determine optimal bonding parameters [37, 162, 166].
Advantages and disadvantages of TLP bonding
The most distinctive advantage of TLP bonding is that the resulting bond can operate at the bonding temperature or higher temperatures. In other words, materials can be bonded at a temperature equal to or lower than what the assembled part will experience in service. This is especially important for temperature-sensitive materials whose microstructures can be damaged by too much thermal energy input  and therefore need to be joined at lower temperatures.
Another advantage is that the resulting TLP bonds often have microstructural, and therefore mechanical, properties similar to the properties of the base materials [7, 12–14, 24, 32, 42, 49, 61, 62, 75, 77, 81, 95, 105, 109, 115, 119, 123, 141, 149, 153, 166, 175]. In fact, in some cases the bond area becomes indistinguishable from other grain boundaries [18, 35, 37, 68, 108, 109, 130, 185] due to significant diffusion at high temperature. Such bonds are often as strong as the bulk substrate material [14, 164], or stronger, causing the joined assembly to fail in the substrate material rather than in the bond [14, 31, 71, 76].
Advantages of TLP bonding include:
the process is highly tolerant to the presence of a faying surface oxide layer [2, 6, 7, 11, 13, 21, 42, 47, 48, 56, 67, 80, 93, 136, 147–149, 186] and therefore requires less joint preparation and no fluxing agents [11, 18, 42, 173, 187]; in a few rare cases surface oxides are actually beneficial to the process 
For some material systems, bond properties and performance capabilities that are difficult or impractical to achieve using conventional joining methods are more accessible .
However, TLP bonding is a specialized bonding technique that can be time-consuming and expensive compared to other joining methods—the time required for isothermal solidification and sufficient bond homogenization can be unfeasibly long and/or uneconomical [36, 37, 104, 141]. TLP bonding is not always suitable, specifically in the following cases:
See reference  for examples of specific difficulties that occur in TLP bonding applications. Although many disadvantages of TLP bonding can be overcome by optimized bonding parameters, the optimization process often requires much experimentation.
Applications of TLP bonding
Since TLP bonding was developed, it has successfully been applied to join a broad range of materials and structures including the following:
TLP bonding is often used in high-stress, high-temperature applications where brazing, welding, and diffusion brazing cannot be used for various reasons (e.g., low melting temperature bond, insufficient resulting mechanical properties, unacceptable plastic deformation) [4, 11, 12, 14, 19, 44, 49–51, 69, 85, 86, 92, 119, 130, 136, 141, 146, 149, 164, 186]. Specific applications are the repair of Ni-based superalloy turbine blade components [7, 9, 39, 74, 104, 105, 135, 142] and the joining of heat-resistant alloys that are inherently susceptible to hot cracking or post-weld heat treatment cracking [5, 11, 20, 38, 59, 78, 80, 135, 136, 140, 173]. Table 3 presents a spectrum of TLP bonds as of now, including bonds of dissimilar materials.
Variants of TLP bonding
A few variants of TLP bonding also exist:
Wide-gap TLP bonding: gaps of 100–500 μm can be bonded or repaired by the use of a melting and a non-melting constituent (multiple layers or mixed powders) [7, 16, 57, 92, 94–96, 100, 101, 136, 149, 173, 195]. This technique can also be used in conventional TLP bonding to accelerate isothermal solidification [13, 99, 140]
Active TLP bonding: a ceramic and metal can be joined by a multi-component interlayer; at least one constituent reacts with the ceramic while another diffuses into the metal to cause isothermal solidification [28, 42, 52, 54, 116, 132, 196]
Partial TLP bonding (see next section).
Bonds made using temperature gradient, wide-gap, and active TLP bonding have been included in Table 3.
Partial transient liquid phase (PTLP) bonding
Partial transient liquid phase (PTLP) bonding is a variant of TLP bonding mainly used to join ceramics. PTLP bonding overlaps both wide-gap and active TLP bonding, although articles defining PTLP bonding predate the other two techniques by a few years. Many advantages of conventional TLP bonding carry over to PTLP bonding . The ensuing sections focus on how PTLP bonding differs from TLP bonding.
PTLP bonding process
In PTLP bonding, the interlayer consists of thin layers of low-melting-point metals or alloys on each side of a much thicker refractory metal or alloy layer [188, 200–203]. Figure 4 presents a general, three-layer PTLP bond setup. (In some cases, there can be multiple thin layers on each side of the refractory core (see Table 4), but the general principles of the process remain the same.) Upon heating to the bonding temperature, a liquid is formed (through melting or a eutectic reaction with the refractory core [202–206]) by each thin layer. The liquid that is formed wets each ceramic substrate while concomitantly diffusing into the solid refractory core. As in TLP bonding, the liquid regions solidify isothermally and homogenization of the entire bond region leads to a refractory bond.
The refractory core tends to be a foil that is 20–30 μm [143, 207–214] or 100–127 μm thick [116, 188, 189, 201, 207, 211–213, 215–222], although it can be in the 200–1000 μm range [202–205, 208, 223–225]. The refractory core element is often Ni [144, 189, 196, 201–204, 207–210, 218, 224, 226, 227]; other elements (and an alloy) that have been used include Au, Co, Cu, Nb, Ni–Cr, Pd, Pt, Si, Ta, Ti, and V [117, 188, 189, 200–202, 205–208, 214–218, 222, 227–229]. The thin layers can be most of the formats used for TLP bonding interlayers (see TLP bonding process) and are often in the 1–10 μm thick range. The ratio of the thin layer thickness over the refractory core thickness is usually 1–5% [143, 188, 189, 201–204, 207, 208, 211–213, 215–218, 220, 222–225, 230, 231], although it can be 6–20% [207, 210–213, 219, 221, 223], and some PTLP bond experiments have utilized a ratio of 50% or higher [116, 144, 208, 214, 226].
PTLP bonding kinetics
Figures 5 and 6 depict the two ends of the PTLP bonding process. The following additional assumptions are made in this analysis: (1) thin layer A (tlA), the refractory core (rc), and thin layer B (tlB) are different pure elements (2) there is no diffusion into the ceramic substrates (3) the ternary system (tlA–rc–tlB) can be approximated by the two associated binary systems (tlA–rc and rc–tlB), and (4) the interlayers wet the substrate with a thin layer of intermetallic formation that conserves the amount of liquid and results in a refractory intermetallic.
The second and fourth assumptions highlight the major differences between TLP and PTLP bonding. First, the multi-layer interlayer used during PTLP bonding has been termed “self-contained”  because the liquid phases must diffuse into the rc, rather than the much larger substrate materials, to induce isothermal solidification. Second, the liquid phases must wet the ceramic substrates to create a strong bond. This tends to be difficult due to the chemical inertness of ceramics [117, 180, 196, 216] and usually requires the use of active elements such as Al, Cr, Hf, Nb, Ni, Sc, Ta, Ti, V, or Zr [65, 117, 187, 189, 198, 200–202, 206, 215, 216, 218, 222, 228, 232, 233]. Also, when analyzing the critical interlayer thickness of the thin layers, a portion of the liquid that forms from those thin layers will react with the ceramic substrate and add to the critical thickness.
The PTLP bonding setup at room temperature is shown in Figs. 5 and 6 as concentration profiles 1A and 1B, CP1A and CP1B, respectively. Both binary systems exhibit complete solid solubility. As the temperature of the bond is raised to the melting points of each thin layer (T 4 for tlA and T 3 for tlB), both thin layers diffuse into the rc (see CP2A and CP3A as well as CP2B). Despite the small amount of liquid that initially forms from tlB due to its high diffusivity (CP3B), the liquid drastically melts back the rc on further heating (CP4B) due to the concave shape of the liquidus. This melt-back continues until the assembly is heated to the bonding temperature (T 5) shown in CP5aB. On the other hand, the liquid formed from tlA (CP4A) widens slightly to be about the same width as the original thin layer (CP5aA) due to that system’s convex liquidus.
At this point, isothermal solidification occurs on both sides of the multi-layer interlayer. It proceeds much faster for tlB due to its high partition coefficient and diffusivity. In fact, isothermal solidification is complete for tlB (CP5bB) when the other liquid region has only solidified about halfway (CP5bA), despite the considerable melt-back of the rc.
The liquid formed from tlA eventually solidifies isothermally (CP5cA). On the other side of the bond, the solute peak has been smoothed due to homogenization (CP5cB), and the remelting temperature on that side has increased to T R,P.
Further homogenization causes the remaining gradient in the tlB element to disappear (CP5dB), thereby raising the remelting temperature of the bond next to substrate B to its final value, T R,F. A similar melting temperature increase (to T R,P1) simultaneously occurs on the other side of the bond due to smoothing of its solute peak (CP5dA).
Prolonging the homogenization process continues to raise the remelting temperature of the left side of the bond. However, once its remelting temperature has reached T R,P2 (CP5eA), which is higher than T R,F for the right side of the bond, further homogenization will have little effect on raising the bond’s remelting temperature. From an optimization standpoint, homogenization should be stopped at this time. However, real-world considerations usually determine the homogenization time, which can be less than—or greater than—the optimized time due to various factors, such as cost, microstructural considerations, or resulting bond strength.
The time frame of PTLP bonding is very similar to that of TLP bonding. Isothermal solidification and homogenization times for TLP bonding depend on high-diffusivity elements diffusing into “infinite” substrate materials. In PTLP bonding, the elements tend to have lower diffusivities, but the maximum diffusion path is on the order of 100 μm, resulting in similar bonding times.
Advantages and disadvantages of PTLP bonding
The “self-contained”  nature of the PTLP bonding multi-layer interlayer provides benefits and impediments. Specific advantages include the following:
because diffusion occurs on a smaller scale (on the order of 100 μm), bonding using slow-diffusing elements occurs in a reasonable amount of time.
Major disadvantages are:
matching the thermal expansion coefficients of the ceramic substrates and metallic interlayer elements is sometimes necessary to prevent thermally induced stresses and cracking [117, 143, 188, 196, 203, 215]
However, most disadvantages of PTLP bonding can be overcome by proper design. In the end, the limiting factor is wettability on the specific ceramic material.
Applications of PTLP bonding
PTLP bonding has been used to successfully join some ceramic and composite materials. Table 4 presents a spectrum of PTLP bonds as of now, including bonds of dissimilar materials. The interlayer combination of the general PTLP bond setup shown in Fig. 4 would be notated tlA | rc | tlB.
TLP bonding is a relatively new bonding process that results in a bond with a higher melting temperature than that used to join the materials. Specific details of this process, including experimental details, process kinetics, and optimal bonding temperature, have been outlined in this article. Also, the broad range of materials that have been joined by TLP bonding was presented.
PTLP bonding, a more recent variant of TLP bonding used to bond hard-to-join materials, was also outlined. PTLP bonding has been successful in joining a smaller range of materials, most notably, ceramics.
Both TLP and PTLP bonding are specialized joining processes that require more resources to implement compared to typical bonding processes. However, in some cases these bonding processes are the best—or only—way to join materials for specialized applications.
A numerical model was developed to calculate one-dimensional solid-state diffusion in conjunction with a liquid region that expands or contracts, assuming infinite diffusivity for the liquid region. The model also accounts for a heating period and diffusivity data as a function of concentration and temperature. Diffusivity data along with solidus and liquidus profiles for a hypothetical binary system were used to output concentration profiles that were the basis for the concentration profiles in Figs. 1, 3, 5, and 6.
Paulonis D, Duvall D, Owczarski W (1971) US Pat 3,678,570 1 Apr 2010
Zhang L, Hou J, Zhang S (2007) China Weld 16(1):63
Lee BK, Song WY, Kim DU, Woo IS, Kang CY (2007) Met Mat Int 13(1):59
Abdelfatah M, Ojo OA (2009) Mat Sci Technol 25(1):61
Ojo OA, Richards NL, Charturvedi MC (2004) Sci Technol Weld Join 9(3):209
Dinkel MK, Heinz P, Pyczak F, Volek A, Ott M, Affeldt E, Vossberg A, Göken M, Singer RF (2008) In: Proceedings of the international symposium on superalloys. TMS, Warrendale, p 211
Gale WF, Butts DA (2004) Sci Technol Weld Join 9(4):283
Kuntz ML (2006) Quantifying isothermal solidification kinetics during transient liquid phase bonding using differential scanning calorimetry. Ph. D dissertation, University of Waterloo
Schnell A, Stankowski A, deMarcos E (2006) In: Proceedings of GT2006, ASME Turbo Expo 2006: power for land, sea, air, Barcelona, 8–11 May 2006
Peaslee RL (1976) Weld J 55(8):695
Wu X, Chandel RS, Li H (2001) J Mat Sci 36:1539. doi:https://doi.org/10.1023/A:1017513200502
Gale WF (1999) J Mat 51(2):49
Gale WF (2003) Mat Sci Forum 426–432:1891
Duvall DS, Owczarski WA, Paulonis DF (1974) Weld J 53(4):203
Tian J, Kim T, Lu TJ, Hodson HP, Queheillalt DT, Sypeck DJ, Wadley HNG (2004) Int J Heat Mass Trans 47(14/16):3171
Laux B, Piegert S, Rösler J (2009) Metall Mat Trans A 40(1):138
Metzger GE (1976). In: Technical report AFML-TR-75-210, Air Force Materials Lab, Wright-Patterson Air Force Base, Ohio, 1976
MacDonald WD, Eagar TW (1998) Metal Mat Trans 29A(1):315
MacDonald WD, Eagar TW (1992) Ann Rev Mat Sci 22:23
Xu Q, Chaturvedi MC, Richards NL, Goel N (1997) In: ISSI: Structural intermetallics 1997, proceedings of the 2nd international symposium on structural intermetallics, champion, p 323, 21–25 Sept 1997
Shirzadi AA (1998) Weld World 41(5):435
Suzumura A, Xing Y (1996) Jpn Inst Met Mat Trans 37(5):1109
AlHazaa A, Khan TI, Haq I (2010) Mat Charact 61(3):312
Ekrami A, Khan TI, Malik H (2003) Mat Sci Technol 19:132
Padron T, Khan TI, Kabir MJ (2004) Mat Sci Eng A 385(1–2):220
Nishimoto K, Saida K, Kim D, Asai S, Furukawa Y, Nakao S (1998) Weld World 41(2):121
Johnsen MR (2007) Weld J 86(3):76
Wang J, Li Y, Huang W (2009) Mat Sci 45(1):125
Duan H, Bohm KH, Ventzke V, Koçak M (2005) Trans Nonferrous Met Soc China 15(2):375
Yang CF, Chiu LH, Lee SC, Sun JY (1998) Proc Natl Sci Counc Repub China A Phys Sci Eng 22(1):132
Brochu M, Wanjara P (2007) Int J Refract Met Hard Mat 25(1):67
Kejanli H, Taskin M, Kolukisa S, Topuz P (2010) Int J Adv Manuf Technol 44(7/8):695
Maity J, Pal TK, Maiti R (2009) J Mat Process Technol 209:3568
Freedman AH (1971) Weld J 50:343s
Krishnardula VG, Sofyan NI, Gale WF, Fergus JW (2006) Metall Mat Trans A 37A(2):497
Li H, Li ZX (2008) J Sandw Struct Mat 10(3):247
Li H, Li ZX (2008) J Mat Eng Perform 17(6):849
Wikstrom NP, Idowu OA, Ojo OA, Chaturvedi MC (2006) In: Proceedings of the 3rd international brazing and soldering conference, Crowne Plaza Riverwalk Hotel, San Antonio, 2006
Zhai Y, North TH (1997) J Mat Sci 32(21):5571. doi:https://doi.org/10.1023/A:1018624507922
Guedes A, Viana F, Pinto AMP, Vieira MF (2008) Mat Sci Forum 587–588:425
Huang X, Richards NL (2004) Weld J 83(3):73s
Zhang G, Zhang J, Pei Y, Li S, Chai D (2008) Mat Sci Eng A 488(1–2):146
Tuah-Poku I, Dollar M, Massalski TB (1988) Metall Trans A 19A(3):675
Kuntz ML, Zhou Y, Corbin SF (2006) Metall Mat Trans A 37A(8):2493
Ojo OA, Abdelfatah MM (2008) Mat Sci Technol 24(6):739
Dolgov YS, Sidokhin AF, Sidokhin YF (1968) Weld Prod 15(12):24
Yuan X, Kim MB, Kang CY (2009) Mat Charact 60(11):1289
Askew JR, Wilde JF, Khan TI (1998) Mat Sci Technol 14(9–10):920
Elrefaey A, Tillmann W (2009) Adv Eng Mat 11(7):556
Wikstrom NP, Egbewande AT, Ojo OA (2008) J Alloys Compd 460(1/2):379
Duan H, Koçak M, Bohm KH, Ventzke V (2004) Sci Technol Weld Join 9(6):513
Dezellus O, Andrieux J, Bosselet F, Sacerdote-Peronnet M, Baffie T, Hodaj F, Eustathopoulos N, Viala JC (2008) Mat Sci Eng A 495(1/2):254
Ghoneim A, Ojo OA (2010) Intermet 18(4):582
Zhai Y, North TH, Serrato-Rodrigues J (1997) J Mat Sci 32(6):1393. doi:https://doi.org/10.1023/A:1018624507922
Abdo ZAM, Guan Y, Gale WF (1999) In: High-temperature ordered intermetallic alloys VIII, MRS Fall Meeting, Boston, 1998
Guan Y, Gale WF (1999) Mat Sci Technol 15(2):207
Gale WF, Guan Y (1999). In: 5th International conference: Trends in Welding Research; Pine Mountain, 1998
Gale WF, Guan Y, Orel SV (1998) Int J Mat Prod Technol 13(1–2):1
Nakahashi M, Suenaga S, Shirokane M, Takeda H (1992) Jpn Inst Met Mat Trans 33:60
Chen SJ, Tang HJ, Jing XT (2009) Mat Sci Eng A 499(1–2):114
Khan TI, Kabir MJ, Bulpett R (2004) Mat Sci Eng A 372(1–2):290
Khan TI, Wallach ER (1996) Mat Sci Technol 12(7):603
Khan TI, Wallach ER (1996) J Mat Sci 31(11):2937. doi:https://doi.org/10.1007/BF00356005
Wei S (1996) Rare Met 15(1):16
Nishimoto K, Saida K, Shinohara Y (2003) Sci Technol Weld Join 8(1):29
Mosallaee M, Ekrami A, Ohsasa K, Matsuura K (2008) Mat Sci Technol 24(4):449
Zhang G, Zhang J, Pei Y (2006) China Weld 15(1):16
Pouranvari M, Ekrami A, Kokabi AH (2008) J Alloys Compds 461(1/2):641
Orel SV, Parous LC, Gale WF (1995) Weld J 74(9):319s
Kim DU, Nishimoto K (2003) Mat Sci Technol 19(4):456
Nishimoto K, Saida K, Kim D, Nakao Y (1995) Iron Steel Inst Jpn Int 35(10):1298
Khan TI, Roy BN (2004) J Mat Sci 39(2):741. doi:https://doi.org/10.1023/B:JMSC.0000011546.44307.42
Fukumoto S, Imamura K, Hirose A, Kobayashi KF (1995) Iron Steel Inst Jpn Int 35(10):1307
Di Luozzo N, Fontana M, Arcondo B (2007) J Mat Sci 42(11):4044. doi:https://doi.org/10.1007/s10853-006-0190-9
Epelbaum C, Fontana M, Audebert F, Arcondo B (2005) J Mat Sci 40(18):4867. doi:https://doi.org/10.1007/s10853-005-3883-6
Khan TI, Orhan N, Eroglu M (2002) Mat Sci Technol 18(4):396
Chen H, Gong JM, Tu ST (2009) Sci Technol Weld Join 14(1):32
Idowu OA, Richards NL, Chaturvedi MC (2005) Mat Sci Eng A 397:98
Pouranvari M, Ekrami A, Kokabi AH (2009) J Alloys Compds 469(1–2):270
Mosallaee M, Ekrami A, Ohsasa K, Matsuura K (2008) Metall Mat Trans A 39A(10):2389
Gale WF, Wallach ER (1991) Metall Trans A 22A(10):2451
Pouranvari M, Ekrami A, Kokabi AH (2008) Mat Sci Eng A 490(1/2):229
Zou GS, Xie EH, Bai HL, Wu AP, Wang Q, Ren JL (2009) Mat Sci Eng A 499(1–2):101
Gale WF, Orel SV (1996) J Mat Sci 31(2):345. doi:https://doi.org/10.1007/BF01139150
Tseng MW, Williams DB, Soni KK, Levi-Setti R (1999) J Mat Sci 34:5187. doi:https://doi.org/10.1023/A:1004707812417
Ojo OA, Richards NL, Chaturvedi MC (2004) Sci Technol Weld Join 9(6):532
Chaturvedi MC, Ojo OA, Richards NL (2004) Adv Technol Mat Mat Process J 6(2):206
Ikawa H, Nakao Y, Isai T (1979) Trans Jpn Weld Soc 10(1):25
Lu CD, Chang LS, Lu YF, Lu FH (2009) Ceram Int 35(7):2699
Maity J, Pal TK, Maiti R (2009) Mat Sci Technol 25(12):1489
Wadley H, Dharmasena K, Chen Y, Dudt P, Knight D, Charette R, Kiddy K (2008) Int J Impact Eng 35(9):1102
Gale WF, Wen X (2001) Mat Sci Technol 17(4):459
Huang JH, Wan Y, Zhao HT, Cheng DH, Zhang H (2007) Mat Sci Technol 23(1):87
Gale WF, Butts DA, Di Ruscio M, Zhou T (2002) Metall Mat Trans A 33A(10):3205
Butts DA, Gale WF (2008) Mat Sci Technol 24(12):1492
Zhou T, Gale WF, Butts D, Di Ruscio M (2003) In: Materials solutions ’02, Columbus, 2003
Sukhachev AP, Lashko SV (1971) Weld Prod 18(6):86
Huang J, Wan Y, Zhang H, Zhao X (2007) J Mat Sci 42(23):9746. doi:https://doi.org/10.1007/s10853-007-2016-9
Zhuang WD, Eagar TW (1997) Weld J 76(4):157s
Gale WF, Xu Y, Wen X, Abdo ZAM (1999) Metall Mat Trans A 30(10):2723
Gale WF, Guan Y (1999) Mat Sci Technol 15(4):464
Zhang W, Ruythooren W (2008) J Electron Mat 37(8):1095
Koyama S, Takahashi M, Ikeuchi K (2007) Mat Sci Forum 539–543:3503
Arafin MA, Medraj M, Turner DP, Bocher P (2007) Mat Sci Eng A 447(1–2):125
Li Z, Zhou Y, North TH (1995) J Mat Sci 30(4):1075. doi:https://doi.org/10.1007/BF01178448
Lee JS, Bang WH, Jung JP, Oh KH (2005) Mat Sci Forum 475–479:1869
Niemann JT, Wille GW (1978) Weld J 57(10):285s
Saha RK, Khan TI (2009) Mat Charact 60(9):1001
Kay WD (1993) ASM Handbook: welding, brazing, soldering, vol. 6. ASM International, Metals Park
Sangha SPS, Jacobson DM, Peacock AT (1998) Weld J 77(10):432s
Rezchik NV, Kheifets RG (1988) Weld Int 2(2):118
Chernitsyn AI, Kufaikin AA, Rastorguev LN, Lozeev GE (1975) Weld Prod 22(7):36
Moore TJ, Kalinowski JM (1993) In: High-temperature ordered intermetallic alloys V, Boston, 1992
Bosco NS, Zok FW (2004) Acta Mater 52:2965
Gale WF, Orel SV (1996) Metall Mat Trans A 27A(7):1925
Liu GW, Valenza F, Muolo ML (2010) J Mat Sci 45:4299. doi:https://doi.org/10.1007/s10853-010-4337-3
Tillmann W, Lugscheider E (1996) Int J Join Mat 8(2):56
Lo PL, Chang LS, Lu YF (2009) Ceram Int 35(8):3091
Li W, Jin T, Sun X, Guo Y, Guan H, Hu Z (2002) J Mat Sci Technol 18:54
Elthalabawy W, Khan T (2010) Mat Charact 61:703
Sun DQ, Liu WH, Gu XY (2004) Mat Sci Technol 20(12):1595
Gu XY, Sun DQ, Liu L (2008) Mat Sci Eng A 487(1–2):86
Gu XY, Sun DQ, Liu L, Duan ZZ (2009) J Alloys Compds 476(1–2):492
Le Blanc A, Mevrel R (1990) In: High temperature materials for power engineering 1990, II. Kluwer Academic, Liege
Saha RK, Khan TI (2007) J Mat Sci 42(22):9187. doi:https://doi.org/10.1007/s10853-007-1922-1
Khan TI, Wallach ER (1995) J Mat Sci 30(20):5151. doi:https://doi.org/10.1007/BF00356063
Lee YS, Seo KW, Lee CH, Lim CH, Lee CH (2006) Mat Sci Forum 510–511:390
Liu JD, Jin T, Zhao NR, Wang ZH, Sun XF, Guan HR, Hu ZQ (2010) Sci Technol Weld Join 15(3):194
Shirzadi AA, Saindrenan G (2003) Sci Technol Weld Join 8(2):149
Krishnardula VG, Sofyan NI, Fergus JW, Gale WF (2006) In: Trends in welding research, Proceedings of the 7th International Conference, Cancun
Noh S, Kasada R, Oono N, Iwata N, Kimura A (2010) Fusion Eng Des 85:1033
Zhou S, Li X, Xiong W, Zhou Y (2009) J Wuhan Univ Technol Mat Sci Ed 24(3):432
Rhee BH, Kim DU (2002) Met Mat 8(5):427
Lashko NF, Lashko SV, Grishin VL (1968) Weld Prod 15(3):5
Egbewande AT, Chukwukaeme C, Ojo OA (2008) Mat Charact 59(8):1051
Aluru R, Sofyan NI, Fergus JW, Gale WF (2006) In: Trends in welding research, Proceedings of the 7th International Conference, Auburn, p 879
Bach FW, Deisser TA, Hollaender U, Moehwald K, Nicolaus M (2007) Weld J 86(12):373s
Ramirez JE, Liu S (1992) Weld J 71(10):365s
Bobzin K, Lugscheider E, Ernst F, Nickel R, Bagcivan N, Parkot D, Schlegel A, Ferrara S, Kashko T, Leick N (2008) Microsyst Technol 14(12):1887
Kwon YS, Kim JS, Moon JS, Suk MJ (2000) J Mat Sci 35(8):1917. doi:https://doi.org/10.1023/A:1004762318057
Saha RK, Khan TI (2006) J Mat Eng Perform 15(6):722
Zhou Y, North TH (1993) Model Simul Mat Sci Eng 1(4):505
Ksiazek M, Sobczak N, Mikulowski B, Radziwill W, Winiarski B, Wojcik M (2005) J Mat Sci 40:2513. doi:https://doi.org/10.1007/s10853-005-1984-x
Chen R, Zuo D, Wang M (2006) J Mat Sci Technol 22(3):291
Sun D, Liu W, Wu J, Jia S, Qiu X (2002) China Weld 11(1):9
Sun D, Liu W, Jia S, Qiu X (2004) Trans Nonferrous Met Soc China 14(1):105
Jalilian F, Jahazi M, Drew RAL (2006) Mat Sci Eng A 423(1–2):269
Natsume Y, Ohsasa K, Tayu Y, Momono T, Narita T (2003) Iron Steel Inst Int 43(12):1976
Aluru R, Gale WF, Chitti SV, Sofyan N, Love RD, Fergus JW (2008) Mat Sci Technol 24(5):517
Sun DQ, Gu XY, Liu WH (2005) Mat Sci Eng A 391(1–2):29
Bosco NS, Zok FW (2005) Acta Mater 53(7):2019
Johnson RW, Wang C, Liu Y, Scofield JD (2007) IEEE Trans Electron Packag Manuf 30(3):182
Rhee B, Roh S, Kim D (2003) Mat Trans 44(5):1014
Schwartz MM (1978) Weld J 57:35
Grishin VL, Lashko SV (1986) Weld Prod 33:23
Jalilian F (2006) The influence of process parameters on TLP bonding of inconel 617 superalloy. Ph. D dissertation, McGill University
Campbell CE, Boettinger WJ (2000) Metall Mat Trans A 31A(11):2835
Heinz P, Volek A, Singer RF, Dinkel M, Pyczak F, Göken M, Ott M, Affeldt E, Vossberg A (2008) Diffus Defect Data A 273–276:294
Abdelfatah MM, Ojo OA (2009) Metall Mat Trans A 40(2):377
Peaslee RL (2002) Weld J 81(2):170
Li JF, Agyakwa PA, Johnson CM (2010) J Mat Sci 45(9):2340. doi:https://doi.org/10.1007/s10853-009-4199-8
Abdelfattah M (2008) An experimental and theoretical study of transient liquid phase bonding of nickel based materials. Ph. D dissertation, University of Manitoba
Cain SR, Wilcox JR, Venkatraman R (1997) Acta Mater 45(2):701
Assadi H, Shirzadi AA, Wallach ER (2001) Acta Mater 49(1):31
Tillmann W, Osmanda AM, Wojarski L (2009) Q J Jpn Weld Soc 27(2):179s
Natsume Y, Ohsasa K, Narita T (2003) Mat Trans 44(5):819
Shinmura T, Ohsasa K, Narita T (2001) Mat Trans 42(2):292
Ohsasa K, Shinmura T, Narita T (1999) J Phase Equilib 20(3):199
Yuan X, Kim MB, Kang CY (2011) Metal Mat Trans A 42(5):1310
Kato H, Kageyama K (1998) Mat Sci Technol 14(7):712
Iseki T, Yamashita K, Suzuki H (1981) J Am Ceram Soc 64(1):C-13
Atabaki M (2010) J Nucl Mat 406:330
Zhou Y, Gale WF, North TH (1995) Int Mater Rev 40(5):181
Sinclair CW (1999) J Phase Equilib 20(4):361
Zhou Y (2001) J Mat Sci Lett 20:841
Illingworth TC, Golosnoy IO, Clyne TW (2007) Mat Sci Eng A 445–446:493
Okamoto H (1997) J Phase Equilib 18(5):491
Wikstrom NP (2006) The effect of process parameters on microstructure of transient liquid phase bonded superalloys inconel 738 and waspaloy. Ph. D dissertation, University of Manitoba
Zhou Y, North TH (1994) Zeitschrift fur Metallkunde 85(11):775
Hong SM (2009) Transient-liquid-phase (TLP) bonding of Al2O3 using Nb-based multilayer interlayers. Ph. D dissertation, University of Calif, Berkeley
Saha RK (2008) Transient liquid phase diffusion bonding of an oxide dispersion strengthened nickel superalloy. Ph. D dissertation, University of Calgary
Illingworth TC, Golosnoy IO, Gergely V, Clyne TW (2005) J Mat Sci 40(9–10):2505. doi:https://doi.org/10.1007/s10853-005-1983-y
Jen TC, Jiao Y (2001) Num Heat Trans A 39(2):123
Sinclair CW, Purdy GR, Morral JE (2000) Metall Mat Trans A 31A(4):1187
Loehman R (1981) In: Pask J, Evans A (eds) Proceedings of the 17th University Conference on Ceramics held University of California, Berkeley, p 701
Shirzadi AA, Wallach ER (1999) Acta Mater 47(13):3551
Lugscheider E, Ferrara S (2004) Adv Eng Mat 6(3):160
Shalz ML, Dalgleish BJ, Tomsia AP, Glaeser AM (1993) J Mat Sci 28:1673. doi:https://doi.org/10.1007/BF00363367
Shalz ML, Dalgleish BJ, Tomsia AP, Glaeser AM (1994) J Mat Sci 29(12):3200. doi:https://doi.org/10.1007/BF00356663
Nicholas M (1998) Joining processes. Kluwer Academic, Boston, p 95
Peaslee RL (1999) Weld J 78(3):237
Agarwal R, Zhang W, Limaye P, Ruythooren W (2009) In: Proceedings—electronic components and technology conference, San Diego
Wilcoxon RK, Boone AP, Wooldridge JR (2010) US Pat 7,830,021 9 Nov 2010
Jabbareh MA, Assadi H (2009) Scr Mater 60(9):780
Zhou T, Gale WF (2003) Mat Sci Technol 19(8):1084
Kim JJ, Park JW, Eagar TW (2003) Mat Sci Eng A 344:240
Fergus JW, Salazar VL, Long CJ, Harris NL, Zhou T, Gale WF (2005) J Mater Sci 40(23):6139. doi:https://doi.org/10.1007/s10853-005-3166-2
Lugscheider E, Ferrara S, Janssen H, Reimann A, Wildpanner B (2004) Microsyst Technol 10:233
Chang LS, Huang CF (2004) Ceram Int 30:2121
Zhang Y, Feng D, He Z, Chen X (2006) J Iron Steel Res Int 13(2):1
Locatelli MR, Nakashima K, Dalgleish BJ, Tomsia AP, Glaeser AM (1994) In: Advances in ceramic-matrix composites II; proceedings of the symposium, ACS 96th Annual Meeting, Indianapolis, 25–27 Apr 1994
Brochu M, Pugh MD, Drew RAL (2002) In: Proceedings from joining of advanced and specialty materials, 5–8 November 2001, Indianapolis, ASM International, 2002
Chen Z, Cao MS, Zhao QZ, Zou JS (2004) Mat Sci Eng A 380:394
Brochu M, Pugh MD, Drew RAL (2004) Int J Refract Met Hard Mat 22:95
Brochu M, Drew RAL, Pugh MD (2002). In: Metal/Ceramic Interactions: as held at the 41st annual conference of metallurgists of CIM (COM 2002), Montreal, 11–14 Aug 2002
Peteves SD, Paulasto M, Ceccone G, Stamos V (1998) Acta Mater 46(7):2407
Ceccone G, Nicholas MG, Peteves SD, Tomsia AP, Dalgleish BJ, Glaeser AM (1996) Acta Mater 44(2):657
Zou GS, Wu AP, Ren JL, Yang J, Zhao WQ (2004) Trans Nonferrous Met Soc China 14(1):93
Yan J, Xu Z, We G, Yang S (2005) J Mat Sci 40(19):5307. doi:https://doi.org/10.1007/s10853-005-4394-1
Dalgleish BJ, Tomsia AP, Glaeser AM (1994) In: Advances in ceramic-matrix composites II; Proceedings of the symposium, ACS 96th Annual Meeting, Indianapolis, 25–27 Apr 1994
Dalgleish BJ, Tomsia AP, Nakashima K, Locatelli MR, Glaeser AM (1994) Scr Metall Mater 31(8):1043
Locatelli MR, Dalgleish BJ, Nakashima K, Tomsia AP, Glaeser AM (1997) Ceram Int 23(4):313
Locatelli MR, Tomsia AP, Nakashima K, Dalgleish BJ, Glaeser AM (1995) Key Eng Mater 111–112:157
Tillmann W, Lugscheider E, Buschke I (1996). In: Processing and fabrication of advanced materials V, Cincinnati, 6–10 Oct 1996
Shalz ML, Dalgleish BJ, Tomsia AP, Cannon RM, Glaeser AM (1994) J Mat Sci 29:3678. doi:https://doi.org/10.1007/BF00357335
Hong SM, Bartlow CC, Reynolds TB, McKeown JT, Glaeser AM (2008) Adv Mat 20(24):4799
Ceccone G, Paulasto M, Nicholas MG, Peteves SD, Glaeser AM (1995) In: 4th European ceramic society Conference vol 9 coatings, Riccione, 1995
Locatelli MR, Dalgliesh BJ, Tomsia AP, Glaeser AM, Mastumoto H, Nakashima K (1995) In: 4th European ceramic society conference vol. 9 coatings, Riccione, 1995
Cook III GO (2011) Joining polycrystalline cubic boron nitride and tungsten carbide by partial transient liquid phase bonding. Ph. D dissertation, Brigham Young University
Nakashima K, Makino T, Mori K, Glaeser AM (1998) J Mater Synth Process 6(4):271
Matsumoto H, Locatelli MR, Nakashima K, Glaeser AM, Mori K (1995) Mater Trans JIM 36(4):555
Hong SM, Reynolds TB, Bartlow CC, Glaeser AM (2010) Int J Mat Res 101(1):133
Iino Y (1991) J Mater Sci Lett 10(2):104
Zheng C, Lou H, Fei Z, Li Z (1997) J Mat Sci Lett 16(24):2026
Iino Y, Usami H, Oshimoda M, Saito T (1992). In: The first Pacific rim international conference on advanced materials and processing (PRICM-1): proceedings of a meeting held in Hangzhou, 23–27 June 1992
Xiong JT, Li JL, Zhang FS, Wang ZP (2007) Key Eng Mat 336–338:1260
Loehman RE (1999) Key Eng Mat 161–163:657
Naidich YV, Zhuravlev VS, Gab II, Kostyuk BD, Krasovskyy VP, Taranets NY (2006) In: Brazing and soldering: proceedings of the 3rd international brazing and soldering conference, Crowne Plaza Riverwalk Hotel, San Antonio
Liang MW, Hsieh TE, Chang SY, Chuang TH (2003) J Electron Mat 32(9):952
Sugar J, McKeown J, Akashi T, Hong S, Nakashima K, Glaeser AM (2006) J Eur Ceram Soc 26(4–5):363
Akashi T, Nukui T, Kiyono H (2009) J Ceram Soc Jpn 117(9):983
Hong SM, Glaeser AM (2006). In: Proceedings of the 3rd international brazing and soldering conference, Crowne Plaza Riverwalk Hotel, San Antonio, 24–26 Apr 2006
Benko E, Bielanska E, Pereverteilo VM, Loginova OB (1997) Diam Relat Mat 6:931
This study was funded by the Office of Naval Research under grant number N00014-07-1-0872, Dr. William Mullins, Program Officer.
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Cook, G.O., Sorensen, C.D. Overview of transient liquid phase and partial transient liquid phase bonding. J Mater Sci 46, 5305–5323 (2011). https://doi.org/10.1007/s10853-011-5561-1
- Bonding Temperature
- Bonding Time
- Transient Liquid Phase
- Isothermal Solidification
- Bond Region