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Journal of Materials Science

, Volume 46, Issue 18, pp 5940–5947 | Cite as

Synthesis and characterization of a new liquid polymer precursor for Si–B–C–N ceramics

Article

Abstract

A new liquid polyborosilazane precursor for Si–B–C–N ceramic was synthesized by co-condensation reaction of boron trichloride, organodichlorosilanes, and hexamethyldisilazane. The structure and properties of polyborosilazane were studied by means of Fourier transform-infrared spectroscopy (FT-IR), nuclear magnetic resonance (NMR), rheology, and thermogravimetric analysis (TGA). The conversion of polymer to ceramic and the high-temperature behavior of the new polymer-derived ceramic were investigated by TG–MS, FT-IR, X-ray diffraction (XRD) and high-temperature TGA (HTGA). The ceramics showed good oxidative resistance and thermal stability with weight gain of 1.8 wt% at 1350 °C under air atmosphere and weight loss of 2.6% at 1900 °C under Ar atmosphere.

Keywords

Pyrolytic Product Polymer Precursor Excellent Thermal Stability Trichlorosilane Dicumyl Peroxide 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Notes

Acknowledgement

The authors would thank the National Science Foundation of China (NSFC, No. 50973113) for financial support.

References

  1. 1.
    Colombo P, Mera G, Riedel R, Sorarù GD (2010) J Am Ceram Soc 93:1805Google Scholar
  2. 2.
    Yajima S, Hayashi J, Okamura K (1977) Nature 266:522CrossRefGoogle Scholar
  3. 3.
    Yajima S, Hayashi J, Omori M, Okamura K (1976) Nature 261:6833CrossRefGoogle Scholar
  4. 4.
    Kroke E, Li Y, Konetschny C, Lecomte E, Fasel C, Reidel F (2000) Mater Sci Eng 26:97CrossRefGoogle Scholar
  5. 5.
    Sung IK, Christian, Mitchell M, Kim DP, Kenis PJA (2005) Adv Funct Mater 15:1336CrossRefGoogle Scholar
  6. 6.
    Greil P (2000) Adv Eng Mater 2:339CrossRefGoogle Scholar
  7. 7.
    Riedel R, Kienzle A, Dressler W, Ruwisch L, Bill J, Aldinger F (1996) Nature 382:796CrossRefGoogle Scholar
  8. 8.
    Baldus HP, Jansen M, Sporn D (1999) Science 285:699CrossRefGoogle Scholar
  9. 9.
    Christ M, Zimmermann A, Zern A, Weinmann M, Aldinger F (2001) J Mater Sci 36:5767. doi: 10.1007/s10853-006-0112-x CrossRefGoogle Scholar
  10. 10.
    Kumar R, Cai Y, Gerstel P, Rixecker G, Aldinger F (2006) J Mater Sci 41:7088. doi: 10.1007/s10853-006-0934-6 CrossRefGoogle Scholar
  11. 11.
    Takamizawa M, Kobayashi T, Hayashida A, Takeda Y (1986) US Patent 4,604,367Google Scholar
  12. 12.
    Baldus HP, Jansen M (1997) Angew Chem Int Ed 7:328Google Scholar
  13. 13.
    Riedel R, Bill J, Kienzle A (1996) Appl Organomet Chem 10:241CrossRefGoogle Scholar
  14. 14.
    Weinmann M, Bill J, Deguire M, Aldinger F (1998) Appl Organometal Chem 12:725CrossRefGoogle Scholar
  15. 15.
    Müller A, Gerstel P, Weinmann M, Bill J, Aldinger F (2000) J Eur Ceram Soc 20:2655CrossRefGoogle Scholar
  16. 16.
    Müller A, Gerstel P, Weinmann M, Bill J, Aldinger F (2001) J Eur Ceram Soc 21:2171CrossRefGoogle Scholar
  17. 17.
    Lee J, Butt DP, Baney RH, Bowers CR, Tulenko JS (2005) J Non-Cryst Solids 351:2995CrossRefGoogle Scholar
  18. 18.
    Tang Y, Wang J, Li XD, Wang H, Li WH, Wang XZ (2008) J Appl Polym Sci 110:921CrossRefGoogle Scholar
  19. 19.
    Li Y, Krobe E, Riedel R, Fasel C, Gervais C, Babonneau F (2001) Appl Organomet Chem 15:820CrossRefGoogle Scholar
  20. 20.
    Schuhmacher J, Berger F, Weinmann M, Bill J, Aldinger F, Müller K (2001) Appl Organomet Chem 15:809CrossRefGoogle Scholar
  21. 21.
    Schmidt WR, Narsavage-Heald DM, Jones DM, Marchetti PS, Raker D, Maciel GE (1999) Chem Mater 11:1455CrossRefGoogle Scholar
  22. 22.
    Cheng F, Toury B, Archibald SJ, Bradley JS (2002) J Organomet Chem 657:71CrossRefGoogle Scholar
  23. 23.
    Gervais C, Maquet J, Babonneau F, Durez C, Framery E, Vaultier M, Florian P, Massiot D (2001) Chem Mater 13:1700CrossRefGoogle Scholar
  24. 24.
    Toury B, Gervais C, Dibandjo P, Cornu D, Miele P, Babonneau F (2004) Appl Organomet Chem 18:227CrossRefGoogle Scholar
  25. 25.
    Schuhmacher J, Berger F, Weinmann M, Bill J, Aldinger F, Müller K (2001) Appl Organomet Chem 15:809CrossRefGoogle Scholar
  26. 26.
    Schiavon MA, Sorarù GD, Yoshida IVP (2004) J Non-Cryst Solids 348:156CrossRefGoogle Scholar
  27. 27.
    Wang ZC, Aldinger F, Riedel R (2001) J Am Ceram Soc 84:2179CrossRefGoogle Scholar
  28. 28.
    Bernard S, Weinmann M, Gerstel P, Miele P, Aldinger F (2005) J Mater Chem 15:289CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC 2011

Authors and Affiliations

  1. 1.Center for Molecular ScienceInstitute of Chemistry, Chinese Academy of SciencesBeijingPeople’s Republic of China
  2. 2.Graduate University of Chinese Academy of SciencesBeijingPeople’s Republic of China

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