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Journal of Materials Science

, Volume 44, Issue 17, pp 4553–4556 | Cite as

Synthesis and characterization of NiO nanoparticles and their PMMA nanocomposites obtained by in situ bulk polymerization

  • L. A. García-CerdaEmail author
  • L. E. Romo-Mendoza
  • M. A. Quevedo-López
Article

Abstract

A nickel oxide (NiO) precursor was prepared using Pechini method. The NiO nanoparticles were prepared by calcination of NiO precursor at temperatures ranging from 300 to 700 °C. The resulting NiO nanoparticles were characterized by X-ray photoelectron spectroscopy, X-ray diffraction (XRD), and transmission electron microscopy. To hamper NiO nanoparticles aggregation, the NiO nanoparticles surface was treated using (3-mercaptopropyl)-trimethoxysilane as a coupling agent. Next, nanocomposites of poly(methyl methacrylate) and modified NiO nanoparticles were successfully prepared by in situ bulk polymerization with 2,2′-azobis(isobutylonitrile) as initiator. The obtained nanocomposites were characterized by XRD and thermogravimetric analysis.

Keywords

PMMA Methyl Methacrylate Nickel Oxide Bulk Polymerization Metallic Nickel 

Notes

Acknowledgements

This work was supported by the CONACYT—México under Grant No. 46302 and the scholarship 213935 for L.E. Romo-Mendoza.

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Copyright information

© Springer Science+Business Media, LLC 2009

Authors and Affiliations

  • L. A. García-Cerda
    • 1
    Email author
  • L. E. Romo-Mendoza
    • 1
  • M. A. Quevedo-López
    • 2
    • 3
  1. 1.Departmento de Materiales AvanzadosCentro de Investigación en Química AplicadaSaltilloMexico
  2. 2.Department of Materials ScienceUniversity of Texas at DallasRichardsonUSA
  3. 3.University of SonoraSonoraMexico

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