Advertisement

Journal of Materials Science

, Volume 44, Issue 24, pp 6617–6628 | Cite as

SBA-15 modified with Al, Ti, or Zr as supports for highly active NiW catalysts for HDS

  • Lilia Y. Lizama
  • Tatiana E. KlimovaEmail author
Mesostructured Materials

Abstract

A series of SBA-15-type materials modified with Al, Ti, and Zr were prepared and used as supports for hydrodesulfurization (HDS) catalysts based on NiW. Prepared supports and catalysts were characterized by N2 physisorption, small- and wide-angle XRD, UV–Vis DRS, FT-IR, IEP, TPR, TPD, HRTEM, and SEM–EDX. Sulfided catalysts were evaluated in HDS of dibenzothiophene (DBT). Catalytic activity tests show that the creation of defined anchoring points for the W species by modifying the surface of SBA-15 with Al, Ti, and Zr results in a considerable improvement in catalysts’ performance compared to pure SBA-supported analog. The possible reasons for this behavior are discussed.

Keywords

Acid Site Tungsten Oxide H3PW12O40 Sulfided Catalyst Catalytic Activity Test 

Notes

Acknowledgements

Financial support by DGAPA-UNAM (grant IN-110609) is gratefully acknowledged. The authors thank M. Aguilar, I. Puente, and C. Salcedo for technical assistance.

References

  1. 1.
    Song C, Ma X (2003) Appl Catal B 41:207CrossRefGoogle Scholar
  2. 2.
    Knudsen KG, Cooper BH, Topsøe H (1999) Appl Catal A 189:205CrossRefGoogle Scholar
  3. 3.
    Song C (2003) Catal Today 86:211CrossRefGoogle Scholar
  4. 4.
    Yoshimura Y, Toba M, Farag H, Sakanishi K (2004) Catal Surv Asia 8:47CrossRefGoogle Scholar
  5. 5.
    Ito E, van Veen JAR (2006) Catal Today 116:446CrossRefGoogle Scholar
  6. 6.
    Fujikawa T, Kimura H, Kiriyama K, Hagiwara K (2006) Catal Today 111:188CrossRefGoogle Scholar
  7. 7.
    Gates BC, Topsøe H (1997) Polyhedron 16:3213CrossRefGoogle Scholar
  8. 8.
    Spojakina A, Palcheva R, Jiratova K, Tyuliev G, Petrov L (2005) Catal Lett 104:45CrossRefGoogle Scholar
  9. 9.
    Hensen EJM, van der Meer Y, van Veen JAR, Niemantsverdriet JW (2007) Appl Catal A 322:16CrossRefGoogle Scholar
  10. 10.
    Kim CH, Yoon WL, Lee IC, Woo SI (1996) Appl Catal A 144:159CrossRefGoogle Scholar
  11. 11.
    Breysse M, Cattenot M, Decamp T, Frety R, Gachet C, Lacroix M, Leclercq C, de Mourgues L, Portefaix JL, Vrinat M, Houari M, Grimbolt J, Kasztelan S, Bonelle JP, Housni S, Bachelier J, Duchet JC (1988) Catal Today 4:39CrossRefGoogle Scholar
  12. 12.
    van der Vlies AJ, Prins R, Weber Th (2002) J Phys Chem B 106:9277CrossRefGoogle Scholar
  13. 13.
    van der Meer Y, Hensen EJM, van Veen JAR, van der Kraan AM (2004) J Catal 228:433CrossRefGoogle Scholar
  14. 14.
    Vissenberg MJ, van der Meer Y, Hensen EJM, de Beer BHJ, van der Kraan AM, van Santen RA, van Veen JAR (2001) J Catal 198:151CrossRefGoogle Scholar
  15. 15.
    Chiranjeevi T, Kumar P, Maity SK, Rana MS, Murali Dhar G, Prasada Rao TSR (2001) Microporous Mesoporous Mater 44–45:547CrossRefGoogle Scholar
  16. 16.
    Lizama L, Pérez M, Klimova T (2008) Stud Surf Sci Catal 174:1251CrossRefGoogle Scholar
  17. 17.
    Hensen EJM, Kooyman PJ, van der Meer Y, van der Kraan AM, de Beer VHJ, van Veen JAR, van Santen RA (2001) J Catal 199:224CrossRefGoogle Scholar
  18. 18.
    Klimova T, Calderón M, Ramírez J (2003) Appl Catal A 240:29CrossRefGoogle Scholar
  19. 19.
    Klimova T, Lizama L, Amezcua JC, Roquero P, Terrés E, Navarrete J, Domínguez JM (2004) Catal Today 98:141Google Scholar
  20. 20.
    Amezcua JC, Lizama L, Salcedo C, Puente I, Domínguez JM, Klimova T (2005) Catal Today 107–108:578CrossRefGoogle Scholar
  21. 21.
    Klimova T, Reyes J, Gutiérrez O, Lizama L (2008) Appl Catal A 335:159CrossRefGoogle Scholar
  22. 22.
    Lizama L, Amezcua JC, Klimova T (2008) Stud Surf Sci Catal 174:1351CrossRefGoogle Scholar
  23. 23.
    Gutiérrez OY, Fuentes GA, Salcedo C, Klimova T (2006) Catal Today 116:485CrossRefGoogle Scholar
  24. 24.
    Muthu Kumaran G, Garg S, Soni K, Kumar M, Sharma LD, Murali Dhar G, Rama Rao KS (2006) Appl Catal A 305:123CrossRefGoogle Scholar
  25. 25.
    Garg S, Soni K, Muthu Kumaran G, Kumar M, Gupta JK, Sharma LD, Murali Dhar G (2008) Catal Today 130:302CrossRefGoogle Scholar
  26. 26.
    Zepeda T (2008) Appl Catal A 347:148CrossRefGoogle Scholar
  27. 27.
    Zhao D, Huo Q, Feng J, Chmelka BF, Stucky GD (1998) J Am Chem Soc 120:6024CrossRefGoogle Scholar
  28. 28.
    Zhao D, Feng J, Huo Q, Melosh N, Fredrickson GH, Chmelka BF, Stucky GD (1998) Science 279:548CrossRefGoogle Scholar
  29. 29.
    Fenelonov VB, Romannikov VN, Derevyankin AY (1999) Microporous Mesoporous Mater 28:57CrossRefGoogle Scholar
  30. 30.
    Cheng M, Wang Z, Sakurai K, Kumata F, Saito T, Komatsu T, Yashima T (1999) Chem Lett 2:131CrossRefGoogle Scholar
  31. 31.
    Damyanova S, Dimitrov L, Mariscal R, Fierro JLG, Petrov L, Sobrados I (2003) Appl Catal A 256:183CrossRefGoogle Scholar
  32. 32.
    Shenderovich IG, Buntkowsky G, Schreiber A, Gedat E, Sharif S, Albrecht J, Golubev NS, Findenegg GH, Limbach H (2003) J Phys Chem B 107:11924CrossRefGoogle Scholar
  33. 33.
    Srinivasan S, Datye AK, Smith MH, Peden CHF (1994) J Catal 415:565CrossRefGoogle Scholar
  34. 34.
    Laha SC, Mukherjee P, Sainkar SR, Kumar R (2002) J Catal 207:213CrossRefGoogle Scholar
  35. 35.
    Alba MD, Luan Z, Klinowski J (1996) J Phys Chem B 100:2178CrossRefGoogle Scholar
  36. 36.
    Smirnov KS, van de Graaf B (1996) Microporous Mater 7:133CrossRefGoogle Scholar
  37. 37.
    Chaudhari K, Bal R, Das TK, Chandwadkar A, Srinivas D, Sivasanker S (2000) J Phys Chem B 104:11066CrossRefGoogle Scholar
  38. 38.
    Zeng S, Blanchard J, Breysse M, Shi Y, Shu X, Nie H, Li D (2005) Microporous Mesoporous Mater 85:297CrossRefGoogle Scholar
  39. 39.
    Gómez-Cazalilla M, Mérida-Robles JM, Gurbani A, Rodríguez-Castellón E, Jiménez-López A (2007) J Solid State Chem 180:1130CrossRefGoogle Scholar
  40. 40.
    Davis RJ, Liu Z (1997) Chem Mater 9:2311CrossRefGoogle Scholar
  41. 41.
    De Witte K, Busuioc AM, Meynen V, Mertens M, Bilba N, Van Tendeloo G, Cool P, Vansant EF (2008) Microporous Mesoporous Mater 110:100CrossRefGoogle Scholar
  42. 42.
    Cozzolino M, Di Serio M, Tesser R, Santacesaria E (2007) Appl Catal A 325:256CrossRefGoogle Scholar
  43. 43.
    Gao X, Wachs IE (1999) Catal Today 51:233CrossRefGoogle Scholar
  44. 44.
    Infantes-Molina A, Mérida-Robles J, Maireles-Torres P, Finocchio E, Busca G, Rodríguez-Castellón E, Fierro JLG, Jiménez-López A (2004) Microporous Mesoporous Mater 75:23CrossRefGoogle Scholar
  45. 45.
    Chen LF, Zhou XL, Noreña LE, Wang JA, Navarrete J, Salas P, Montoya A, Del Angel P, Llanos ME (2006) Appl Surf Sci 253:2443CrossRefGoogle Scholar
  46. 46.
    Rodríguez-Castellón E, Jiménez-López A, Maireles-Torres P, Jones DJ, Rozière J, Trombetta M, Busca G, Lenarda M, Storaro L (2003) J Solid State Chem 175:159CrossRefGoogle Scholar
  47. 47.
    Ko JB, Lee SW, Kim DE, Kim YU, Li G, Lee SG, Chang TS, Kim D, Joo YL (2006) J Porous Mater 13:325CrossRefGoogle Scholar
  48. 48.
    Klein S, Weckhuysen BM, Martens JA, Maier WF, Jacobs PA (1996) J Catal 163:489CrossRefGoogle Scholar
  49. 49.
    Gao X, Fierro JLG, Wachs IE (1999) Langmuir 15:3169CrossRefGoogle Scholar
  50. 50.
    Luan Z, Maes EM, van der Heide PAW, Zhao D, Czernuszewicz RS, Kevan L (1999) Chem Mater 11:3680CrossRefGoogle Scholar
  51. 51.
    Peña ML, Dellarocca V, Rey F, Corma A, Coluccia S, Marchese L (2001) Microporous Mesoporous Mater 44–45:345CrossRefGoogle Scholar
  52. 52.
    Newalkar BL, Olanrewaju J, Komarneni S (2001) Chem Mater 13:552CrossRefGoogle Scholar
  53. 53.
    Rakshe B, Ramaswamy V, Hegde SG, Vetrivel R, Ramaswamy AV (1997) Catal Lett 45:41CrossRefGoogle Scholar
  54. 54.
    Ciuparu D, Ensuque A, Shafeev G, Bozon-Verduaz F (2000) J Mater Sci Lett 19:931CrossRefGoogle Scholar
  55. 55.
    Benitez VM, Figoli NS (2002) Catal Commun 3:487CrossRefGoogle Scholar
  56. 56.
    Vermaire DC, Van Berge PC (1989) J Catal 116:309CrossRefGoogle Scholar
  57. 57.
    Logie V, Maire G, Michel D, Vignes JL (1999) J Catal 188:90CrossRefGoogle Scholar
  58. 58.
    Chen XR, Chen CL, Xu NP, Mou CY (2004) Catal Today 93–95:129CrossRefGoogle Scholar
  59. 59.
    Yang XL, Dai WL, Gao R, Fan K (2007) J Catal 249:278CrossRefGoogle Scholar
  60. 60.
    Hodnett BK, Moffat JB (1985) J Catal 91:93CrossRefGoogle Scholar
  61. 61.
    Palcheva R, Spojakina A, Tyuliev G, Jiratova K, Petrov L (2007) Kinet Catal 48:847CrossRefGoogle Scholar
  62. 62.
    Tuel A (1999) Microporous Mesoporous Mater 27:151CrossRefGoogle Scholar
  63. 63.
    Girgis MJ, Gates BC (1991) Ind Eng Chem Res 30:2021CrossRefGoogle Scholar
  64. 64.
    Houalla M, Nag NK, Sapre AV, Broderick DH, Gates BC (1978) AIChE J 24:1015CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC 2009

Authors and Affiliations

  1. 1.Facultad de QuímicaUniversidad Nacional Autónoma de MéxicoMéxicoMéxico

Personalised recommendations