Journal of Materials Science

, Volume 44, Issue 19, pp 5307–5311 | Cite as

Effect of wall thickness on the ferroelastic domain size of BaTiO3

  • G. CatalanEmail author
  • I. Lukyanchuk
  • A. Schilling
  • J. M. Gregg
  • J. F. Scott


Extremely regular self-organized patterns of 90° ferroelastic domains have been reported in free-standing single crystal thin films of ferroelectric BaTiO3. Lukyanchuk et al. [Phys Rev B 79, 144111 (2009)] have recently shown that the domain size as a function of thickness for such free standing films can be well described assuming that the domains are due to stress caused by a surface tension layer that does not undergo the paraelectric–ferroelectric transition. From the starting point of Lukyanchuk’s model, it is shown here that the “universal” relationship between domain size and domain wall thickness previously observed in ferroelectrics, ferromagnets and multiferroics is also valid for ferroelastic domains. Further analysis of experimental data also shows that the domain wall thickness can vary considerably (an order of magnitude) from sample to sample even for the same material (BaTiO3), in spite of which the domain size scaling model is still valid, provided that the correct, sample dependent, domain wall thickness is used.


Domain Wall BaTiO3 Domain Size BiFeO3 Stripe Domain 



Financial support from EPSRC and the Alliance programme of the British Council is gratefully acknowledged.


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Copyright information

© Springer Science+Business Media, LLC 2009

Authors and Affiliations

  • G. Catalan
    • 1
    Email author
  • I. Lukyanchuk
    • 2
  • A. Schilling
    • 3
  • J. M. Gregg
    • 3
  • J. F. Scott
    • 1
  1. 1.Department of Earth SciencesUniversity of CambridgeCambridgeUK
  2. 2.Laboratory of Condensed Matter PhysicsUniversity of Picardie Jules VerneAmiensFrance
  3. 3.Centre for Nanostructured Media, School of Maths and PhysicsQueen’s University of BelfastBelfastUK

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