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Journal of Materials Science

, Volume 44, Issue 12, pp 3211–3217 | Cite as

In situ preparation of self-bonded zeolite MCM-22 bodies by vapor-phase transport method

  • Xingsheng Liu
  • Yingxia LiEmail author
  • Biaohua Chen
  • Tianying Niu
Article

Abstract

Self-bonded bodies of zeolite MCM-22 were prepared by vapor-phase transport method. The resultant materials were characterized by means of X-ray diffraction, scanning electron microscope, mercury porosimetry, and nitrogen porosimetry. Self-bonded MCM-22 bodies were in situ prepared at pH 10.0 with the molar composition of 0.05Na2O:SiO2:0.033Al2O3. It was found that the bodies, prepared by aluminosilicate gel, had been transformed into zeolite MCM-22. The MCM-22 bodies of which the mechanical resistance was 126 N/cm avoided binder accession. By adding auxiliary chemical–PEG20000 to the aluminosilicate gel, the pore size distributions of MCM-22 bodies could be adjusted. The average pore radius of MCM-22 bodies reached in the 149.41–653.64 nm range when AC/SiO2 ratio was 1.5 × 10−4–9.0 × 10−4.

Keywords

Zeolite Pore Size Distribution Relative Crystallinity Zeolite Particle Beijing Chemical Reagent 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Notes

Acknowledgement

The authors gratefully acknowledge the financial assistance from the National Natural Science Foundation of China (Nos. 20676011 and 20625621).

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Copyright information

© Springer Science+Business Media, LLC 2009

Authors and Affiliations

  • Xingsheng Liu
    • 1
  • Yingxia Li
    • 1
    Email author
  • Biaohua Chen
    • 1
  • Tianying Niu
    • 1
  1. 1.State Key Laboratory of Chemical Resource EngineeringBeijing University of Chemical TechnologyBeijingPeople’s Republic of China

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