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Journal of Materials Science

, Volume 43, Issue 18, pp 6094–6098 | Cite as

Spectroscopic and quantum chemical investigation of the 4Bi2O3 · B2O3 glass structure

  • S. Rada
  • E. Culea
  • V. Rus
Article

Abstract

The structural properties of the 4Bi2O3 · B2O3 glass were investigated by FT-IR spectroscopy and quantum chemical calculations. The main results reveal that the coordination polyhedrons of the bismuth ion from the [BiO6] structural units and of the boron ion from the [BO4] groups are irregular. Accordingly, the [BiO6] and [BO4] structural units in the studied glass matrix have a complex structural role that makes possible the formation of the vitreous system.

Keywords

Fermi Level B2O3 Bi2O3 Glass Network Boroxol 

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Copyright information

© Springer Science+Business Media, LLC 2008

Authors and Affiliations

  1. 1.Department of PhysicsTechnical University of Cluj-NapocaCluj-NapocaRomania

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