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Journal of Materials Science

, Volume 43, Issue 16, pp 5534–5539 | Cite as

Synthesis and characterization of a polyaniline/HTiNbO5 lamellar hybrid nanocomposite

  • Juanjuan MaEmail author
  • Xiaobo Zhang
  • Chong Yan
  • Zhiwei Tong
  • Haruo Inoue
Article

Abstract

Polyaniline (PANI)/HTiNbO5 lamellar hybrid nanocomposite was synthesized by the intercalation of aniline monomer into the layer structure of HTiNbO5 followed by the subsequent in situ polymerization of aniline in the interlayer spacings. The synthesis process, the structure and morphology characterizations for lamellar hybrid nanocomposite were investigated by means of XRD, FTIR, TG–DTA, and SEM. Based on the experimental results, a detailed description of the conformation of polyaniline chains within the confined galleries of the inorganic host material was presented. TG analysis showed improved thermal stability for the intercalated nanocomposite in comparison with the pure PANI. Electrochemical studies indicated that the nanocomposite exhibited good redox activity and electrochemical-cycling stability.

Keywords

PANI Aniline Glassy Carbon Electrode Layered Compound Pure PANI 

Notes

Acknowledgements

This work was supported by a grant-in-aid for Scientific Research from the Japan Society for the Promotion of Science (JSPS) and the CREST program of the Japan Science and Technology Agency (JST). The authors are also grateful to young and middle aged academic leaders of Jiangsu Province universities’ “blue and green blue project”.

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Copyright information

© Springer Science+Business Media, LLC 2008

Authors and Affiliations

  • Juanjuan Ma
    • 1
    • 2
    Email author
  • Xiaobo Zhang
    • 1
  • Chong Yan
    • 1
  • Zhiwei Tong
    • 1
    • 3
  • Haruo Inoue
    • 3
    • 4
  1. 1.Department of Chemical EngineeringHuaihai Institute of TechnologyLianyungangPeople’s Republic of China
  2. 2.Key Laboratory of Soft Chemistry and Functional Materials, Ministry of EducationNanjing University of Science and TechnologyNanjingPeople’s Republic of China
  3. 3.SORST, Japan Science and Technology (JST) TokyoJapan
  4. 4.Department of Applied Chemistry, Graduate Course of EngineeringTokyo Metropolitan UniversityHachioji CityJapan

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