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Journal of Materials Science

, Volume 43, Issue 16, pp 5540–5545 | Cite as

Microwave initiated hydrothermal synthesis of nano-sized complex fluorides, KMF3 (K = Zn, Mn, Co, and Fe)

  • Purnendu Parhi
  • Jon Kramer
  • V. ManivannanEmail author
Article

Abstract

A microwave assisted hydrothermal method, where the advantages of both microwave and hydrothermal methods are utilized to synthesize complex fluoride KMF3 (M = Zn, Mn, Co, Fe), materials of technological importance, is proposed. The KMF3 metal fluorides synthesized feature nano-sized particles having well-defined cubic morphologies. The proposed synthesis, in contrast to the existing synthesis methods is very rapid, economical, and less complex in nature. The structural, thermal, optical, and chemical properties of synthesized powders are determined by powder X-ray diffraction, scanning and transmission electron microscopy, X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy, and diffuse reflectance spectra in the UV–VIS range.

Keywords

Diffuse Reflectance Spectrum Triglycine Sulfate Metal Fluoride Local Spin Density Approximation Complex Fluoride 

Notes

Acknowledgements

The authors would like to acknowledge Professor Allan Kirkpatrick, Department Head, Mechanical Engineering, Colorado State University, for his continued help, encouragement, and support.

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Copyright information

© Springer Science+Business Media, LLC 2008

Authors and Affiliations

  1. 1.Department of Mechanical Engineering, Campus Delivery 1374Colorado State UniversityFort CollinsUSA

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