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Journal of Materials Science

, Volume 43, Issue 5, pp 1723–1729 | Cite as

Modifier ligands effects on the synthesized TiO2 nanocrystals

  • Abbas Sadeghzadeh Attar
  • Morteza Sasani GhamsariEmail author
  • Fereshteh Hajiesmaeilbaigi
  • Shamsoddin Mirdamadi
Article

Abstract

In this study, the preparation of titanium dioxide nanocrystals by sol–gel method has been considered. Then, the effect of modifier ligands such as acetylacetone (AcAc) and acetic acid (AcOH) on synthesis of TiO2 nanocrystalline powders has been investigated. The experimental results showed that the reaction of tetraisopropoxide titanium, Ti(OPri)4, with acetylacetone and acetic acid leads to formation of complexes that can prevent the precipitation of undesired phases from highly reactive precursors. Whereas, the band of ligands to TiO2 nanocrystals is not broken easily at temperatures lower than about 400 °C. So these ligands may remain in the final TiO2 nanostructures and affect the morphology and structure of prepared materials. The studied samples were characterized using Fourier transform infrared spectroscopy (FT-IR), Thermogravimetric and Differential thermal analysis (TG-DTA), X-ray diffraction (XRD) and scanning electron microscopy (SEM).

Keywords

TiO2 AcAc TiO2 Nanoparticles Acetylacetone AcOH 

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Copyright information

© Springer Science+Business Media, LLC 2007

Authors and Affiliations

  • Abbas Sadeghzadeh Attar
    • 1
  • Morteza Sasani Ghamsari
    • 2
    Email author
  • Fereshteh Hajiesmaeilbaigi
    • 3
  • Shamsoddin Mirdamadi
    • 1
  1. 1.Department of Metallurgy and Materials EngineeringIran University of Science and TechnologyTehranIran
  2. 2.Solid State Lasers Research Group, Laser and Optics Research SchoolNSTRITehranIran
  3. 3.Solid State Lasers Research GroupLaser Research CenterTehranIran

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