Journal of Materials Science

, Volume 43, Issue 7, pp 2158–2162 | Cite as

Direct synthesis of brookite-type titanium oxide by hydrothermal method using water-soluble titanium complexes

  • Makoto Kobayashi
  • Koji Tomita
  • Valery Petrykin
  • Masahiro Yoshimura
  • Masato Kakihana
Article

Abstract

It was demonstrated that brookite-type titanium oxide can be directly synthesized by the hydrothermal treatment of novel water-soluble titanium complexes under basic conditions in the presence of an additive. In particular, single-phase brookite was synthesized from the titanium–glycolate complex at a pH of about 10 in the presence of excess NH3 aqueous solution or ethylenediamine, and powder thus obtained consisted of rod-like nanosized particles. It was suggested that the structures of titanium complexes are important for the formation of brookite.

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Copyright information

© Springer Science+Business Media, LLC 2007

Authors and Affiliations

  • Makoto Kobayashi
    • 1
  • Koji Tomita
    • 1
    • 2
  • Valery Petrykin
    • 1
  • Masahiro Yoshimura
    • 3
  • Masato Kakihana
    • 1
  1. 1.Institute of Multidisciplinary Research for Advanced MaterialsTohoku UniversitySendaiJapan
  2. 2.Department of Chemistry, School of ScienceTokai UniversityHiratsukaJapan
  3. 3.Materials and Structures Laboratory (Center for Materials Design)Tokyo Institute of TechnologyYokohamaJapan

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