In this study, ZrP2O7 was synthesized by the solid state reaction of ZrO2 and NH4H2PO4 at 900 °C. Then, in set 1; 10, 5, 1, 0.5, 0.1, 0.05, 0.03% previously prepared Sr2P2O7 were doped into ZrP2O7, and Sr2P2O7 slightly affect the unit cell parameter of cubic ZrP2O7 (a = 8.248(6)–8.233(8) Å). The reverse of this process was also applied to Sr2P2O7 system (set 2). ZrP2O7 changes the unit cell parameters of orthorhombic Sr2P2O7 in between a = 8.909(5)–8.877(5) Å, b = 13.163(3)–13.12(1) Å, and c = 5.403(2)–5.386(4) Å. Analysis of the vibrations of the P2O74− ion and approximate band assignments for IR and Raman spectra are also reported in this work. Some coincidences in infrared and Raman spectra both sets were found and strong P–O–P bands were observed. Surface morphology, EDX analysis, and thermoluminescence properties of both sets were given the first time in this paper.
Raman Spectrum Pyrophosphate Unit Cell Parameter Glow Curve Ammoxidation
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This work was supported by BAP-01-03-DPT-03K-120920/09. The authors also dedicated this paper to the memory of Meral Kızılyallı.