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Journal of Materials Science

, Volume 42, Issue 19, pp 8311–8319 | Cite as

Suspension polymerization casting of lead zirconate titanate, Part II: acrylate system

  • W. Miao
  • J. W. HalloranEmail author
  • D. E. Brei
Article

Abstract

Suspension polymerization casting of lead zirconate titanate (PZT) filled acrylate-based system was investigated using 51 vol% suspension of PZT in an ethoxyethoxy ethyl acrylate-based system. The polymerization process was characterized with chemorheology and differential scanning calorimetry. PZT powder accelerates the process, decreasing the activation energy for polymerization from 132 ± 6 kJ/mol to 98 ± 20 kJ/mol. The influence of monomer ratio, initiator amount, catalyst, and solvent are presented.

Keywords

Storage Modulus Gelation Time Final Conversion Initiator Concentration Ethyl Acrylate 

Notes

Acknowledgments

This work is supported by DARPA (Grant # N00014-97-1-G009).

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Copyright information

© Springer Science+Business Media, LLC 2007

Authors and Affiliations

  1. 1.Department of Materials Science and EngineeringThe University of MichiganAnn ArborUSA
  2. 2.Department of Mechanical Engineering and Applied MechanicsThe University of MichiganAnn ArborUSA

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