Journal of Materials Science

, Volume 42, Issue 9, pp 2917–2933 | Cite as

Geopolymer technology: the current state of the art

  • P. Duxson
  • A. Fernández-Jiménez
  • J. L. Provis
  • G. C. Lukey
  • A. Palomo
  • J. S. J. van Deventer
Advances in Geopolymer Science & Technology

Abstract

A brief history and review of geopolymer technology is presented with the aim of introducing the technology and the vast categories of materials that may be synthesized by alkali-activation of aluminosilicates. The fundamental chemical and structural characteristics of geopolymers derived from metakaolin, fly ash and slag are explored in terms of the effects of raw material selection on the properties of geopolymer composites. It is shown that the raw materials and processing conditions are critical in determining the setting behavior, workability and chemical and physical properties of geopolymeric products. The structural and chemical characteristics that are common to all geopolymeric materials are presented, as well as those that are determined by the specific interactions occurring in different systems, providing the ability for tailored design of geopolymers to specific applications in terms of both technical and commercial requirements.

References

  1. 1.
    Davidovits J (1991) J Therm Anal 37:1633CrossRefGoogle Scholar
  2. 2.
    Van Wazer JR (1970) Inorg Macromol Rev 1:89Google Scholar
  3. 3.
    Gartner E (2004) Cem Conc Res 34:1489CrossRefGoogle Scholar
  4. 4.
    Rahier H, Van Mele B, Biesemans M, Wastiels J, Wu X (1996) J Mater Sci 31:71CrossRefGoogle Scholar
  5. 5.
    Palomo A, De La Fuente JIL (2003) Cem Conc Res 33:281CrossRefGoogle Scholar
  6. 6.
    Krivenko PV (1994) In: Krivenko PV (ed) Proceedings of the first international conference on alkaline cements, concretes. VIPOL Stock Company, Kiev, Ukraine, pp 11–129Google Scholar
  7. 7.
    Mallicoat S, Sarin P, Kriven WM (2005) Ceram Eng Sci Proc 26:37CrossRefGoogle Scholar
  8. 8.
    Sofi M, Van Deventer JSJ, Mendis PA, Lukey GC (2006) J Mater Sci (this issue)Google Scholar
  9. 9.
    Bao Y, Grutzeck MW, Jantzen CM (2005) J Am Ceram Soc 88:3287CrossRefGoogle Scholar
  10. 10.
    Phair JW, Smith JD, Van Deventer JSJ (2003) Mater Lett 57:4356CrossRefGoogle Scholar
  11. 11.
    Gordon M, Bell JL, Kriven WM (2005) Ceram Trans 165:95Google Scholar
  12. 12.
    Xu H, Van Deventer JSJ (2000) Int J Miner Proc 59:247CrossRefGoogle Scholar
  13. 13.
    Purdon AO (1940) J Soc Chem Ind Trans Commun 59:191Google Scholar
  14. 14.
    Roy D (1999) Cem Conc Res 29:249CrossRefGoogle Scholar
  15. 15.
    Iwahiro T, Nakamura Y, Komatsu R, Ikeda K (2001) J Eur Ceram Soc 21:2515CrossRefGoogle Scholar
  16. 16.
    Wagh AS (2005) Ceram Trans 165:107Google Scholar
  17. 17.
    Duxson P, Provis JL, Lukey GC, Mallicoat SW, Kriven WM, Van Deventer JSJ (2005) Colloid Surf A 269:47CrossRefGoogle Scholar
  18. 18.
    Duxson P, Mallicoat SW, Lukey GC, Kriven WM, Van Deventer JSJ (2006) Coll Surf A (in press), DOI: 10.1016/j.colsurfa.2006.05.044Google Scholar
  19. 19.
    Rowles M, O’connor B (2003) J Mater Chem 13:1161CrossRefGoogle Scholar
  20. 20.
    Glukhovsky VD (1959) Soil silicates. Gosstroyizdat, Kiev, 154ppGoogle Scholar
  21. 21.
    Fernández-Jiménez A, Palomo A, Criado M (2005) Cem Conc Res 35:1204CrossRefGoogle Scholar
  22. 22.
    Fernández-Jiménez A, Palomo A, Sobrados I, Sanz J (2006) Micropor Mesopor Mater 91:111CrossRefGoogle Scholar
  23. 23.
    Provis JL, Lukey GC, Van Deventer JSJ (2005) Chem Mater 17:3075CrossRefGoogle Scholar
  24. 24.
    Provis JL, Duxson P, Van Deventer JSJ, Lukey GC (2005) Chem Eng Res Des 83:853CrossRefGoogle Scholar
  25. 25.
    Van Deventer JSJ, Provis JL, Duxson P, Lukey GC (2006) J Hazard Mater (in press), DOI 10.1016/j.jhazmat.2006.02.044Google Scholar
  26. 26.
    Blum AE, Lasaga AC (1988) Nature 331:431CrossRefGoogle Scholar
  27. 27.
    Walther JV (1996) Am J Sci 296:693CrossRefGoogle Scholar
  28. 28.
    Oelkers EH (2001) Geochim Cosmochim Acta 65:3703CrossRefGoogle Scholar
  29. 29.
    Smith JV (1998) Proc Natl Acad Sci USA 95:3366CrossRefGoogle Scholar
  30. 30.
    Swaddle TW Salerno J, Tregloan PA (1994) Chem Soc Rev 23:319CrossRefGoogle Scholar
  31. 31.
    Swaddle TW (2001) Coord Chem Rev 219:221–665CrossRefGoogle Scholar
  32. 32.
    Aiello R, Crea F, Nastro A, Subotić B, Testa F (1991) Zeolites 11:767CrossRefGoogle Scholar
  33. 33.
    Ivanova II, Aiello R, Nagy JB, Crea F, Derouane EG, Dumont N, Nastro A, Subotić B, Testa F (1994) Micropor Mater 3:245CrossRefGoogle Scholar
  34. 34.
    Faimon J (1996) Geochim Cosmochim Acta 60:2901CrossRefGoogle Scholar
  35. 35.
    Provis JL, Van Deventer JSJ (2006) J Mater Sci (this issue)Google Scholar
  36. 36.
    Provis JL (2006) PhD Thesis, University Of Melbourne, 310ppGoogle Scholar
  37. 37.
    Duxson P, Lukey GC, Van Deventer JSJ (2006) J Mater Sci (this issue)Google Scholar
  38. 38.
    Lee WKW, Van Deventer JSJ (2002) Cem Conc Res 32:577CrossRefGoogle Scholar
  39. 39.
    Alonso S, Palomo A (2001) Mater Lett 47:55CrossRefGoogle Scholar
  40. 40.
    Yip CK, Lukey GC, Van Deventer JSJ (2003) Ceram Trans 153:187Google Scholar
  41. 41.
    Yip CK, Van Deventer JSJ (2003) J Mater Sci 38:3851CrossRefGoogle Scholar
  42. 42.
    Granizo ML, Alonso S, Blanco-Varela MT, Palomo A (2002) J Am Ceram Soc 85:225CrossRefGoogle Scholar
  43. 43.
    Duxson P (2006) PhD Thesis, University Of Melbourne, 287ppGoogle Scholar
  44. 44.
    Davidovits J (1988) In: Davidovits J, Orlinski J (eds) Proceedings of geopolymer ‘88—first European conference on soft mineralurgy. Universite De Technologie De Compeigne, Compeigne, France, pp 149–166Google Scholar
  45. 45.
    Duxson P, Lukey GC, Separovic F, Van Deventer JSJ (2005) Ind Eng Chem Res 44:832CrossRefGoogle Scholar
  46. 46.
    Palomo A, Alonso S, Fernández-Jiménez A, Sobrados I, Sanz J (2004) J Am Ceram Soc 87:1141CrossRefGoogle Scholar
  47. 47.
    Duxson P, Provis JL, Lukey GC, Separovic F, Van Deventer JSJ (2005) Langmuir 21:3028CrossRefGoogle Scholar
  48. 48.
    Klinowski J (1984) Prog NMR Spec 16:237CrossRefGoogle Scholar
  49. 49.
    Engelhardt G, Michel D (1987) High-resolution solid-state NMR of silicates and zeolites. Wiley, New York, 485ppGoogle Scholar
  50. 50.
    Lee SK, Stebbins JF (1999) Am Miner 84:937Google Scholar
  51. 51.
    Provis JL, Duxson P, Lukey GC, Van Deventer JSJ (2005) Chem Mater 17:2976CrossRefGoogle Scholar
  52. 52.
    Fernández-Jiménez A, De La Torre AG, Palomo A, López-Olmo G, Alonso MM, Aranda MAG (2006) Fuel 85:625CrossRefGoogle Scholar
  53. 53.
    Fernández-Jiménez A, De La Torre AG, Palomo A, López-Olmo G, Alonso MM, Aranda MAG (2006) Fuel 85: 1960Google Scholar
  54. 54.
    Kriven WM, Bell JL, Gordon M (2003) Ceram Trans 153:227Google Scholar
  55. 55.
    Barbosa VFF, Mackenzie KJD, Thaumaturgo C (2000) Int J Inorg Mater 2:309CrossRefGoogle Scholar
  56. 56.
    Alonso S, Palomo A (2001) Cem Conc Res 31:25CrossRefGoogle Scholar
  57. 57.
    Brinker CJ, Scherer GW (1990) Sol-Gel science: the chemistry and physics of Sol-Gel processing. Academic, London, 980ppGoogle Scholar
  58. 58.
    Yang S, Navrotsky A, Phillips BL (2000) J Phys Chem B 104:6071CrossRefGoogle Scholar
  59. 59.
    Palomo A, Glasser FP (1992) Br Ceram Trans J 91:107Google Scholar
  60. 60.
    Van Jaarsveld JGS, Van Deventer JSJ (1999) Cem Conc Res 29:1189CrossRefGoogle Scholar
  61. 61.
    Barrer RM, Mainwaring DE (1972) J Chem Soc Dalton Trans 1254Google Scholar
  62. 62.
    Barrer RM, Mainwaring DE (1972) J Chem Soc Dalton Trans 2534Google Scholar
  63. 63.
    Barrer RM (1982) Hydrothermal chemistry of zeolites. Academic, London, 360ppGoogle Scholar
  64. 64.
    Baerlocher C, Meier WM, Olson DH (2001) Atlas of zeolite framework types, 5th revised edition. Elsevier, Amsterdam, 308ppGoogle Scholar
  65. 65.
    Provis JL, Duxson P, Lukey GC, Separovic F, Kriven WM, Van Deventer JSJ (2005) Ind Eng Chem Res 44:8899CrossRefGoogle Scholar
  66. 66.
    Kollman PA, Kuntz ID (1972) J Am Chem Soc 94:9236CrossRefGoogle Scholar
  67. 67.
    Swier S, Van Assche G, Van Hemelrijck A, Rahier H, Verdonck E, Van Mele B (1998) J Therm Anal 54:585CrossRefGoogle Scholar
  68. 68.
    Palomo A, Fernández-Jiménez A, Criado M (2004) Mater Construc 54:77CrossRefGoogle Scholar
  69. 69.
    Desiraju GR (2003) Nature 423: 485CrossRefGoogle Scholar
  70. 70.
    Corradini P, Auriemma F, De Rosa C (2006) Acc Chem Res 39:314CrossRefGoogle Scholar
  71. 71.
    Lee WKW, Van Deventer JSJ (2002) Colloid Surf A 211:49CrossRefGoogle Scholar
  72. 72.
    Provis JL, P, Duxson, Lukey GC, Van Deventer JSJ (2005) Chem Mater 17:2976CrossRefGoogle Scholar
  73. 73.
    Criado M, Fernández-Jiménez A, Palomo A (2007) Micropor Mesopor Mater (submitted)Google Scholar
  74. 74.
    Criado M, Fernández-Jiménez A, Palomo A, Sobrados I, J Sanz (2007) Micropor Mesopor Mater (submitted)Google Scholar
  75. 75.
    Svensson IL, Sjöberg S, Öhman LO (1986) J Chem Soc Faraday Trans I 82:3635CrossRefGoogle Scholar
  76. 76.
    Rahier H, Simons W, Van Mele B, Biesemans M (1997) J Mater Sci 32:2237CrossRefGoogle Scholar
  77. 77.
    Sindhunata, Van Deventer JSJ, Lukey GC, Xu H (2006) Ind Eng Chem Res 45:3559–73CrossRefGoogle Scholar
  78. 78.
    Criado M (2007) PhD Thesis, Eduardo Torroja Institute (in progress)Google Scholar
  79. 79.
    Mccormick AV, Bell AT, Radke CJ (1989) J Phys Chem 93:1741CrossRefGoogle Scholar
  80. 80.
    Lee WKW, Van Deventer JSJ (2003) Langmuir 19:8726CrossRefGoogle Scholar
  81. 81.
    Fernández-Jiménez A, Palomo A (2005) Cem Concr Res 35:1984CrossRefGoogle Scholar
  82. 82.
    Hos JP, Mccormick PG, Byrne LT (2002) J Mater Sci 37:2311CrossRefGoogle Scholar
  83. 83.
    Xu H, Van Deventer JSJ (2002) Miner Eng 15:1131CrossRefGoogle Scholar
  84. 84.
    Oelkers EH, Gislason SR (2001) Geochim Cosmochim Acta 65:3671CrossRefGoogle Scholar
  85. 85.
    Oelkers EH, Schott J, Devidal JL (1994) Geochim Cosmochim Acta 58:2011CrossRefGoogle Scholar
  86. 86.
    Xu H, Van Deventer JSJ (2003) Colloid Surf A 216:27CrossRefGoogle Scholar
  87. 87.
    Van Jaarsveld JGS, Van Deventer JSJ (1999) Ind Eng Chem Res 38:3932CrossRefGoogle Scholar
  88. 88.
    Fernández-Jiménez A, Palomo A, Criado M (2006) Mater Construc 56:51Google Scholar
  89. 89.
    Barrer RM, White EAD (1952) J Chem Soc 1561Google Scholar
  90. 90.
    Barrer RM, Baynham JW (1956) J Chem Soc 2882Google Scholar
  91. 91.
    Barrer RM, Mccallum N (1953) J Chem Soc 4029Google Scholar
  92. 92.
    Barrer RM, White EAD (1951) J Chem Soc 1267Google Scholar
  93. 93.
    Rahier H, Denayer JF, Van Mele B (2003) J Mater Sci 38:3131CrossRefGoogle Scholar
  94. 94.
    Cockrell CF, Muter RB, Leonard JW, Anderson RE (1970) Potential for recovering unreacted lime from limestone-modified fly ash by agglomerate. Coal Res. Bur.,West Virginia Univ., Morgantown, 267 ppGoogle Scholar
  95. 95.
    Fernández-Jiménez A, Palomo A (2005) Micropor Mesopor Mater 86:207CrossRefGoogle Scholar
  96. 96.
    Keyte LM, Lukey GC, Van Deventer JSJ (2005) In: Nzihou A (ed) Wasteeng 2005. Albi, France. CD-ROM ProceedingsGoogle Scholar
  97. 97.
    Fernández-Jiménez A, Palomo A (2003) Fuel 82:2259CrossRefGoogle Scholar
  98. 98.
    Ejaz T, Jones AG, Graham P (1999) J Chem Eng Data 44:574CrossRefGoogle Scholar
  99. 99.
    Gasteiger HA, Frederick WJ, Streisel RC (1992) Ind Eng Chem Res 31:1183CrossRefGoogle Scholar
  100. 100.
    Dent LS Glasser, Harvey G (1984) J Chem Soc Chem Commun 1250Google Scholar
  101. 101.
    Patra A, Ganguli D (1994) Bull Mater Sci 17:999Google Scholar
  102. 102.
    Weng L, Sagoe-Crentsil K, Brown T, Song S (2005) Mater Sci Eng B 117:163CrossRefGoogle Scholar
  103. 103.
    Henry M (2002) Chem Phys Chem 3:561Google Scholar
  104. 104.
    Xu H, Van Deventer JSJ, Roszak S, Leszczynski J (2004) Int J Quant Chem 96:365CrossRefGoogle Scholar
  105. 105.
    Granizo ML, Blanco-Varela MT, Palomo A (2000) J Mater Sci 35:6309CrossRefGoogle Scholar
  106. 106.
    Madani A, Aznar A, Sanz J, Serratosa JM (1990) J Phys Chem 94:760CrossRefGoogle Scholar
  107. 107.
    Rahier H, Wullaert B, Van Mele B (2000) J Therm Anal Calor 62:417CrossRefGoogle Scholar
  108. 108.
    Azizi N, Harris RK, Samadi-Maybodi A (2002) Magn Reson Chem 40:635CrossRefGoogle Scholar
  109. 109.
    Antonić T, Čižmek A, Subotić B (1994) J Chem Soc Faraday Trans 90:3725CrossRefGoogle Scholar
  110. 110.
    Taylor HFW (1964) The chemistry of cements. Academic, LondonGoogle Scholar
  111. 111.
    Shimoda K, Tobu Y, Kanehashi K, Nemoto T, Shimoikeda Y, Saito K (2005) In: Naito A (ed) 1st Asia Pacific Nmr Symposium, Yokohama, Ap130Google Scholar
  112. 112.
    Vance ER, Perera DS, Hanna JV, Pike KJ, Aly Z, Blackford MG, Zhang Y, Zhang Z, Rowles M, Davis J, Uchida O, Yee P, Ly L (2005) International workshop on geopolymers and geopolymer concrete, Perth, Australia. CD-ROM ProceedingsGoogle Scholar
  113. 113.
    Daux V, Guy C, Advocat T, Crovisier J-L, Stille P (1997) Chem Geol 142:109CrossRefGoogle Scholar
  114. 114.
    Fernández-Jiménez A, Palomo A, Macphee DE, Lachowski E (2005) J Am Ceram Soc 88:1122CrossRefGoogle Scholar
  115. 115.
    Fernández-Jiménez AM, Palomo A, López-Hombrados C (2006) ACI Mater J 103:106Google Scholar
  116. 116.
    Hardjito D, Wallah SE, Rangan BV (2002) In: Lukey GC (ed) Geopolymers 2002—turn potential into profit, Melbourne, Australia. CD-ROM ProceedingsGoogle Scholar
  117. 117.
    Fernández-Jiménez A, Garcia-Lodeiro I, Palomo A (2006) J Mater Sci (this issue)Google Scholar
  118. 118.
    Bakharev T (2005) Cem Concr Res 35:1233CrossRefGoogle Scholar
  119. 119.
    Fernández-Jiménez A, Palomo A (2007) Mater Construc (in press)Google Scholar
  120. 120.
    Miranda JM, Fernández-Jiménez A, Gonzalez JA, Palomo A (2005) Cem Concr Res 35:1210CrossRefGoogle Scholar
  121. 121.
    Yip CK, Lukey GC, Van Deventer JSJ (2005) Cem Conc Res 35:1688CrossRefGoogle Scholar
  122. 122.
    Palomo A, Fernández-Jiménez A, Kovalchuk G, Ordóñez LM, Naranjo MC (2006) J Mater Sci (this issue) Google Scholar

Copyright information

© Springer Science+Business Media, LLC 2006

Authors and Affiliations

  • P. Duxson
    • 1
  • A. Fernández-Jiménez
    • 2
  • J. L. Provis
    • 1
  • G. C. Lukey
    • 1
  • A. Palomo
    • 2
  • J. S. J. van Deventer
    • 1
  1. 1.Department of Chemical and Biomolecular EngineeringThe University of MelbourneParkvilleAustralia
  2. 2.Eduardo Torroja Institute (CSIC)MadridSpain

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