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Journal of Materials Science

, Volume 42, Issue 11, pp 4009–4017 | Cite as

Improved visible-light responsive photocatalytic activity of N and Si co-doped titanias

  • Hirotaka Ozaki
  • Shinji IwamotoEmail author
  • Masashi Inoue
Article

Abstract

Thermal reaction of titanium tetraisopropoxide and tetraethyl orthosilicate in 1,4-butanediol afforded nanocrystalline silica-modified titanias having large surface area and superior thermal stability. In this study, the thus-obtained silica-modified titanias were treated in an NH3 flow at high temperatures, and their physical and photocatalytic properties were investigated. Compared with NH3-treated TiO2 without silica modification, the NH3-treated silica-modified titanias showed a stronger absorption in the visible region (400–500 nm) and had a larger peak at 396 eV in the N 1s XPS spectrum. These results indicate that a larger amount of nitrogen was stably doped in the silica-modified titania. The obtained products exhibited a high photocatalytic activity for degradation of Rhodamine B and decomposition of acetaldehyde under visible light irradiation.

Keywords

Photocatalytic Activity Visible Light Irradiation High Photocatalytic Activity Visible Light Region Photocatalytic Decomposition 

Notes

Acknowledgements

This study was supported by a Grant-in-Aid for Scientific Research (No. 16510085) from Ministry of Education, Culture, Sports, Science and Technology, Japan, and by the Kansai Research Foundation for Technology Promotion. One of the authors, S. I., thanks Prof. B. Ohtani for valuable discussions.

Supplementary material

10853_2006_236_MOESM1_ESM.doc (62 kb)
ESM1 (DOC 62 kb)

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Copyright information

© Springer Science+Business Media, LLC 2006

Authors and Affiliations

  1. 1.Department of Energy and Hydrocarbon Chemistry, Graduate School of EngineeringKyoto UniversityKatsura, KyotoJapan

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