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Synthesis, structure and magnetic properties of manganese(II) and cobalt(II) coordination polymers with bis(4-pyridyl)benzylamine

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Abstract

Coordination polymers [Mn2(bpba)3(NO3)4]n·nCH3CN·nCH3CH2OCH2CH3 (1) and [Co2(bpba)3(NO3)4]n·nCH3CN·nCH3CH2OCH2CH3 (2) were synthesized by the reaction of Mn(NO3)2·4H2O or Co(NO3)2·6H2O with bis(4-pyridyl)benzylamine (bpba) in CH3CN/CH3OH. The polymers were characterized by elemental analysis, spectroscopy, magnetic measurement, and single crystal X-ray diffraction. The manganese(II) ion of 1 was coordinated by three N atoms of three different bpba ligands and four O atoms of NO3− anions and displays a T-shaped geometry via bpba ligands. The extended structure of 1 shows a wave-like distorted brick wall configuration. The structure of 2 is isomorphous to that of 1. Polymers 1 and 2 showed weak antiferromagnetic interactions between the metal ions, respectively.

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Acknowledgements

This research was supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education, Science and Technology (No. 2015R1D1A1A01059872 and 2018R1D1A1B07043305).

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Authors and Affiliations

  1. Department of Chemistry Education, Kyungpook National University, Daegu, 41566, Republic of Korea

    Su Young Kim & Kil Sik Min

  2. Department of Chemistry, Kyungpook National University, Daegu, 41566, Republic of Korea

    Ah Rim Jeong

  3. Department of Chemistry, Kumamoto University, Kumamoto, 860-8555, Japan

    Yuki Komatsumaru & Shinya Hayami

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  1. Su Young Kim
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  3. Yuki Komatsumaru
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Correspondence to Kil Sik Min.

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Kim, S.Y., Jeong, A.R., Komatsumaru, Y. et al. Synthesis, structure and magnetic properties of manganese(II) and cobalt(II) coordination polymers with bis(4-pyridyl)benzylamine. J Incl Phenom Macrocycl Chem 94, 167–174 (2019). https://doi.org/10.1007/s10847-019-00890-1

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