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Intercalation behavior of calcium phenylphosphonate dihydrate CaC6H5PO3·2H2O

  • L. BenešEmail author
  • K. Melánová
  • J. Svoboda
  • V. Zima
Original Article

Abstract

Intercalates of calcium phenylphosphonate dihydrate with 1-alkylamines (C2–C10), 1-alkanols (C3–C10), 1,ω-amino alcohols (C2–C5), pyridine, morpholine, piperazine, aniline and 1-naphthylamine were prepared and characterized by powder X-ray diffraction and thermogravimetric analysis. The intercalates of alkanols and alkylamines are unstable at ambient conditions and the guest molecules are tilted to the host layers at an angle of 40°. The amino alcohol intercalates are stable and their basal spacings are very similar for all amino alcohols used and, in the case of ethanolamine and propanolamine, they contain co-intercalated water. Also arylamines and nitrogenous heterocycles form stable compounds. The general formula of these intercalates is CaC6H5PO3·xH2y(guest) and their basal spacings are from 15.39 to 15.78 Å.

Keywords

Intercalation Layered phenylphosphonate Amines Alkanols 

Notes

Acknowledgements

This work was supported by the Czech Science Foundation (Project No. GA 203/08/0208), the Academy of Sciences of the Czech Republic (AV0Z40500505) and the Ministry of Education, Youth and Sports of the Czech Republic (MSM 0021627501).

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Copyright information

© Springer Science+Business Media B.V. 2009

Authors and Affiliations

  1. 1.Joint Laboratory of Solid State ChemistryInstitute of Macromolecular Chemistry of AS CR v.v.i. and University of Pardubice (Faculty of Chemical Technology)PardubiceCzech Republic

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