Advertisement

Intercalation of 1,2-Alkanediols into α-Zirconium Hydrogenphosphate

  • Klára Melánová
  • Ludvík BenešEmail author
  • Vítězslav Zima
  • Jan Svoboda
  • Miroslava Trchová
  • Jiří Dybal
Article

Abstract

Intercalation compounds of α-Zr(HPO4)2 · H2O with 1,2-alkanediols (from C3 to C16) have been prepared by replacing 1-propanol in α-Zr(HPO4)2 · 2C3H7OH with the desired 1,2-alkanediols by a treatment in a microwave field. It was found that the intercalates contain 1.5 molecules of diol per formula unit. The diol molecules are placed between the host layers in a bimolecular way with their aliphatic chains tilted at an angle of 51°. The diol molecules are anchored in the interlayer space by H-bonds. A mixed intercalate, containing 1,2-butanediol and 1,2-decanediol in a roughly equimolar ratio, is formed when the α-Zr(HPO4)2 · 2C3H7OH intercalate, suspended in a mixture of 1,2-butanediol and 1,2-decanediol, is exposed to microwave radiation. No new phase containing both types of the guest molecules was observed when the 1-propanol intercalate, suspended in a mixture of 1-propanol and 1,2-octanediol, is exposed to microwave radiation.

Keywords

1,2-alkanediol intercalation α-zirconium hydrogen phosphate 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Notes

Acknowledgements

This study was supported by the Academy of Sciences of the Czech Republic (AVOZ40500505) and the Ministry of Education, Youth and Sports of the Czech Republic (MSM 0021627501) and by the Grant Agency of the Czech republic (GA 203/05/2306).

References

  1. 1.
    Alberti G., Casciola M., Costantino U., Vivani R., (1996) Adv. Mater. 8:291CrossRefGoogle Scholar
  2. 2.
    Alberti G., Costantino U., (1984) J. Mol. Catal. 27:235CrossRefGoogle Scholar
  3. 3.
    Clearfield A., (1988) Chem. Rev. 88:125CrossRefGoogle Scholar
  4. 4.
    G. Alberti and U. Costantino: In J.L. Atwood, J.E.D. Davies and D.D. Mac Nicol (eds), Inclusion Compounds, Vol. 5, Oxford University Press (1991), pp. 136–176Google Scholar
  5. 5.
    A. Clearfield: In W. Müller-Warmuth and R. Schöllhorn (eds), Progress in Intercalation Research, Vol. 17, Kluwer Academic Publishers (1994), pp. 240–253Google Scholar
  6. 6.
    A. Clearfield and U. Costantino: In G. Alberti and T. Bein (eds), Comprehensive Supramolecular Chemistry, Vol. 7, Pergamon (1996), pp. 107–149Google Scholar
  7. 7.
    Hoppe R., Alberti G., Costantino U., Dionigi C., Schulz-Ekloff G., Vivani R., (1997) Langmuir 13:7252CrossRefGoogle Scholar
  8. 8.
    Cao G., Garcia M.E., Alcalà M., Burges L.F., Mallouk T.E., (1992) J. Am. Chem. Soc. 114:7574CrossRefGoogle Scholar
  9. 9.
    Kumar V., Chaudari A., (2000) J. Am. Chem. Soc. 122:830CrossRefGoogle Scholar
  10. 10.
    Bellezza F., Cipiciani A., Costantino U., Negozio M.E., (2002) Langmuir 18:8737CrossRefGoogle Scholar
  11. 11.
    Bellezza F., Cipiciani A., Costantino U., Nicolis S., (2004) Langmuir 20:5019CrossRefGoogle Scholar
  12. 12.
    U. Costantino: J. Chem. Soc. Dalton Trans. 402 (1979)Google Scholar
  13. 13.
    Hasegawa Y., Kontani S., Tomita I., (1993) J. Inclusion Phenom. 16:329CrossRefGoogle Scholar
  14. 14.
    Costantino U., Vivani R., Zima V., Beneš L., Melánová K., (2002) Langmuir 18:1211CrossRefGoogle Scholar
  15. 15.
    Alberti G., Torracca E., (1968) J. Inorg. Nucl. Chem. 30:317CrossRefGoogle Scholar
  16. 16.
    Beneš L., Votinský J., Kalousová J., Klikorka J., (1986) Inorg. Chim. Acta 114:47CrossRefGoogle Scholar
  17. 17.
    Beneš L., Zima V., Melánová K., (2001) J. Inclusion Phenom. 40:131CrossRefGoogle Scholar
  18. 18.
    Čapková P., Melánová K., Beneš L., Schenk H., (2000) J. Mol. Model. 6:9CrossRefGoogle Scholar
  19. 19.
    La Ginestra A., Ferragina C., Massucci M.A., Patrono P., Di Rocco R., Tomlinson A.A.G., (1983) Gaz. Chim. Ital. 113:357Google Scholar
  20. 20.
    Costantino U., Vivani R., Zima V., Černošková E., (1997) J. Solid State Chem. 132:17CrossRefGoogle Scholar
  21. 21.
    Trchová M., Čapková P., Matějka P., Melánová K., Beneš L., (1999) J. Solid State Chem. 145:1CrossRefGoogle Scholar
  22. 22.
    Hezel A., Ross S.D., (1966) Spectrochimica Acta 22:1949CrossRefGoogle Scholar
  23. 23.
    Pinchas S., Sadeh D., (1968) J. Inorg. Nucl. Chem. 30:1785CrossRefGoogle Scholar
  24. 24.
    Horsley S.E., Nowell D.V., Stewart D.T., (1974) Spectrochimica Acta 30A:535Google Scholar
  25. 25.
    Pimentel G.C., McClellan A.L., (1960) The Hydrogen Bond. Freeman W.H. and Company, San Francisco and LondonGoogle Scholar
  26. 26.
    R.M. Silverstein, G.C. Bassler, and T.C. Morrill: Spectrometric Identification of Organic Compounds, 5th edn., John Wiley & Sons, Inc., New YorkGoogle Scholar
  27. 27.
    Snyder R.G., (1960) J. Mol. Spectr. 4:411CrossRefGoogle Scholar
  28. 28.
    Votinský J., Beneš L., Kalousová J., Klikorka J., (1987) Inorg. Chim. Acta 126:19CrossRefGoogle Scholar
  29. 29.
    Melánová K., Beneš L., Zima V., Kalousová J., Votinský J., (1999) J. Inclusion Phenom. 33:391CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, Inc. 2006

Authors and Affiliations

  • Klára Melánová
    • 1
  • Ludvík Beneš
    • 1
    Email author
  • Vítězslav Zima
    • 1
  • Jan Svoboda
    • 1
  • Miroslava Trchová
    • 2
  • Jiří Dybal
    • 2
  1. 1.Joint Laboratory of Solid State Chemistry of Institute of Macromolecular Chemistry of Academy of Sciences and University of PardubicePardubiceCzech Republic
  2. 2.Institute of Macromolecular Chemistry of Academy of Sciences of the Czech RepublicPrague 6Czech Republic

Personalised recommendations