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Intercalation of Toluidines into α-Zirconium Hydrogenphosphate

  • LUDVÍK BENEŠEmail author
  • KLÁRA MELÁNOVÁ
  • JAN SVOBODA
  • VÍTĚZSLAV ZIMA
Article

Abstract

Intercalates of o-, m-, and p-toluidine into α-Zr(HPO4)2 · H2O were prepared and characterized by powder X-ray diffraction, thermogravimetric analysis and infrared spectroscopy. As follows from IR, toludine molecules are protonated in the interlayer space. Toluidine molecules are arranged in a bimolecular way in the intercalates containing more than 1.5 toluidine molecules per Zr atom. On the other hand, a monolayer of the toluidine molecules is supposed in the intercalates with less than one toluidine molecule per Zr atom.

Keywords

α-zirconium hydrogenphosphate intercalation toluidine 

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Notes

Acknowledgement

This study was supported by the Academy of Sciences of the Czech Republic (AVOZ40500505) and the Ministry of Education, Youth and Sports of the Czech Republic (MSM 0021627501) and by the Grant Agency of the Czech republic (GA 203/05/2306).

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Copyright information

© Springer Science+Business Media, Inc. 2006

Authors and Affiliations

  • LUDVÍK BENEŠ
    • 1
    Email author
  • KLÁRA MELÁNOVÁ
    • 1
  • JAN SVOBODA
    • 1
  • VÍTĚZSLAV ZIMA
    • 1
  1. 1.Joint Laboratory of Solid State Chemistry of the Institute of Macromolecular Chemistry of Academy of SciencesUniversity of PardubicePardubiceCzech Republic

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