Intercalation of Dyes Containing SO3H Groups into Zn–Al Layered Double Hydroxide

  • Klára Melánová
  • Ludvík BenešEmail author
  • Vítzslav Zima
  • Jan Svoboda


The intercalates of Naphthol Yellow S, Tropaeolin 000, and Tropaeolin 00 were prepared by heating [Zn0.67Al0.33(OH)2](CO3)0.165 · 0.5H2O with acidic forms of the dye solutions in an open reaction vessel. The intercalates were characterized by chemical and thermal analysis, X-ray powder diffraction and UV–VIS spectroscopy. A possible arrangement of the dye molecules in the intercalates was suggested on the basis of their chemical compositions and interlayer distances, by taking into account van der Waals dimensions of the guest molecules and by assuming that the structure of the host layers is not changed during the intercalation process.


dye hydrotalcite-like compounds intercalate 


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.


  1. 1.
    A de Roy, C. Forano, K. El Malki, and J.-P. Besse: In M.L. Ocelli and E.R. Robson (eds.), Anionic Clays: Trends in Pillaring Chemistry, Synthesis of Microporous Materials, Van Nostrand Reinhold, New York, (1992), vol 2, p. 108.Google Scholar
  2. 2.
    Cavani, F., Trifiro, F., Vaccari, A. 1991Catal. Today11173Google Scholar
  3. 3.
    Newman, S.P., Jones, W. 1998New J. Chem.22105Google Scholar
  4. 4.
    F. Trifiro, A. Vaccari: In G. Alberti and T. Bein (eds.), Comprehensive Supramolecular Chemistry, Pergamon, Elsevier Science, Oxford, (1996), vol. 7, chapter 8.Google Scholar
  5. 5.
    U. Costantino and M. Nocchetti: In V. Rives (ed.), Layered double hydroxides: present and future, Nova Science Pu., New York, (2001), chapter 12.Google Scholar
  6. 6.
    Meyn, M., Beneke, K., Lagaly, G. 1990Inorg. Chem.295201Google Scholar
  7. 7.
    Costantino, U., Coletti, N., Nocchetti, M., Aloisi, G.G., Elisei, F. 1999Langmuir154454Google Scholar
  8. 8.
    Miyata, S. 1983Clays Clay Miner.31305Google Scholar
  9. 9.
    Costantino, U., Coletti, N., Nocchetti, M., Aloisi, G.G., Elisei, F., Latterini, L. 2000Langmuir1610351Google Scholar
  10. 10.
    Rives, V., Ullibari, M.A. 1999Coord. Chem. Rev.18161Google Scholar
  11. 11.
    Clearfield, A., Kieke, M., Kwan, J., Colon, J.L., Wang, R.-C. 1991J. Incl. Phenom.11361Google Scholar
  12. 12.
    Kanezaki, E., Sugiyama, S., Ischikawa, Y. 1995J. Mater. Chem.51969Google Scholar
  13. 13.
    Chibwe, K., Jones, W. 1989J. Chem. Soc. Chem. Commun. 926Google Scholar
  14. 14.
    Kanezaki, E. 1995J. Mater. Sci.304926Google Scholar
  15. 15.
    Kaneyoshi, M., Jones, W. 1999J. Mater. Chem.9805Google Scholar
  16. 16.
    Aloisi, G.G., Costantino, U., Elisei, F., Latterini, L., Natali, C., Nocchetti, M. 2002J. Mater. Chem.123316Google Scholar
  17. 17.
    Costantino, U., Marmottini, F., Nocchetti, M., Vivani, R. 1998Eur. J. Inorg. Chem. 1439Google Scholar
  18. 18.
    Melánová, K., Beneš, L., Zima, V., Vlek, M. 2002Sci. Pap. Univ. Pardubice, Ser. A8103Google Scholar

Copyright information

© Springer 2005

Authors and Affiliations

  • Klára Melánová
    • 1
  • Ludvík Beneš
    • 1
    Email author
  • Vítzslav Zima
    • 1
  • Jan Svoboda
    • 1
  1. 1.Joint Laboratory of Solid State Chemistry of Institute of Macromolecular Chemistry of Academy of SciencesUniversity of PardubicePardubiceCzech Republic

Personalised recommendations