Design of Supramolecular Cyclodextrin Complex Sensors for Ion and Molecule Recognition in Water

  • Takashi Hayashita
  • Akiyo Yamauchi
  • Ai-Jun Tong
  • Jong Chan Lee
  • Bradley D. Smith
  • Norio Teramae
Mini Review

Abstract

The design and function of novel supramolecular fluoroionophore/cyclodextrin (CyD) complex sensors for ion and molecule recognition in water are reviewed. For the crown ether fluoroionophore/γ-CyD complex, the dimerization of the fluoroionophore inside the γ-CyD is found to be selectively promoted by alkali metal ion binding, thereby resulting in metal-ion-selective pyrene dimer emission in water. This supramolecular function is successfully utilized in the design of a podand fluoroionophore/γ-CyD complex for sensing toxic lead ion in water. The boronic acid fluoroionophore/β-CyD complex binds sugars and produces increased fluorescence emission in water. The response mechanism appears to be due to the suppression of the photoinduced electron transfer (PET) from pyrene donor to trigonal phenylboronic acid acceptor. This is a novel emission function provided by the boronic acid fluoroionophore/β-CyD complex sensors in water.

Keywords

alkali metal ion cyclodextrin fluoroionophore lead ion sugar supramolecular sensor 

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Copyright information

© Kluwer Academic Publishers 2004

Authors and Affiliations

  • Takashi Hayashita
    • 1
  • Akiyo Yamauchi
    • 1
  • Ai-Jun Tong
    • 2
  • Jong Chan Lee
    • 3
  • Bradley D. Smith
    • 4
  • Norio Teramae
    • 1
  1. 1.Department of Chemistry, Graduate School of ScienceTohoku UniversityAoba-kuJapan
  2. 2.Department of ChemistryTsinghua UniversityBeijingChina
  3. 3.Department of ChemistryChung-Ang UniversitySeoulKorea
  4. 4.Department of Chemistry and BiochemistryUniversity of Notre DameNotre DameUSA

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