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Journal of Electroceramics

, Volume 41, Issue 1–4, pp 1–8 | Cite as

Sintering and optical properties of transparent ZnS ceramics by pre-heating treatment temperature

  • Seo-Yeong Yeo
  • Tae-Hyeong Kwon
  • Chang-Sun Park
  • Chang-Il Kim
  • Ji-Sun Yun
  • Young-Hun Jeong
  • Youn-Woo Hong
  • Jeong-Ho Cho
  • Jong-Hoo Paik
Article
  • 87 Downloads

Abstract

The main objective of our work is to increase transmittance in the mid infrared region by removing impurities through the pre-heating treatment of zinc sulfide (ZnS) produced by hydrothermal synthesis. The pre-heating treatment proceeded at 450 to 600 °C for 2 h under vacuum atmosphere (10−2 Torr). It was confirmed that the particle size increased as the pre-heating temperature increased. Additionally, all ZnS nano powders had a sphalerite (cubic) structure unaffected by pre-heating treatment. The ZnS nano powders were sintered by hot-press sintering method. As the pre-heating temperature increased, transmittance was improved due to the decreasing of porosity, increase of particle size, and the removal of impurities (carbon and sulfate). However, when the pre-heating treatment temperature was 600 °C, the transmittance slightly decreased due to the formation of a hexagonal phase. The ZnS ceramic with pre-heating treatment at 550 °C showed the highest transmittance (71.6%) and density (99.9%).

Keywords

ZnS Hydrothermal synthesis Hot press Sintering Infrared 

Notes

Acknowledgements

This work was supported by the Materials and Components Technology Development Program of MOTIE/KEIT [No. 10067243, The development of TeO2 based optical glass and sintered ZnS for mid infrared applications in smart devices].

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  • Seo-Yeong Yeo
    • 1
  • Tae-Hyeong Kwon
    • 1
  • Chang-Sun Park
    • 1
  • Chang-Il Kim
    • 1
  • Ji-Sun Yun
    • 1
  • Young-Hun Jeong
    • 1
  • Youn-Woo Hong
    • 1
  • Jeong-Ho Cho
    • 1
  • Jong-Hoo Paik
    • 1
  1. 1.Electronic Convergence Materials DivisionKorea Institute of Ceramic Engineering & TechnologyJinjuSouth Korea

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