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Journal of Electroceramics

, Volume 40, Issue 3, pp 257–269 | Cite as

Structural, dielectric and magnetic properties of particulate composites of relaxor (BaTi0.85Sn0.15O3) and ferrite (NiFe2O4) synthesized by gel-combustion method

  • Md. Jawed Ansaree
  • Upendra Kumar
  • Shail Upadhyay
Article
  • 114 Downloads

Abstract

Particulate composites of (1-x) BaTi0.85Sn0.15O3 – x NiFe2O4 (with x = 5, 10,15 and 20 wt%) were synthesized using the solid-state reaction method by sintering at 1350 °C for 4 h. Formation of the diphase composites was confirmed by X-ray diffraction (XRD) and Fourier Transform Infra-red (FTIR) techniques. Temperature (RT-200 °C) and frequency (20 Hz- 1 MHz) dependent of AC conductivity, dielectric constant and dissipation have been studied. The dielectric constant exhibits strong frequency dispersion in the range 20 Hz-1 kHz which is attributed to Maxwell-Wagner interfacial polarization occurring at grain-grain-boundaries interface/interface of grains of BTS-NF. The M-H curve of all the composites exhibited a hysteresis loops typical charcateistic of a ferromagnetic material. The ferromagnetic ordering in the composites on account of NiFe2O4 as a constituent is explained using bound magnetic polarons (BMPs) model. The experimental magnetic data have been fitted to BMP model. Value of Ms is smaller, whereas of Hc and Mr are higher of the composites compared to value for NiFe2O4. The temperature at which divergence in the M vs. T plot in ZFC and FC starts is higher for the composites than for NiFe2O4.

Keywords

BTS-NF composite FTIR Dielectric constant M-H loop 

Notes

Acknowledgements

The authors are grateful to the Head, Department of Physics, Head, Department of Pharmaceutics Head, and Coordinator, Central Instrument Facility Center (CIFC), IIT(BHU), Varanasi for providing the experimental facilities required for the characterization of the synthesized samples. Mr. Md. Jawed Ansaree and Mr. Upendra Kumar are thankful to the Ministry of Human Resource and Development (MHRD), Government of India for the financial support in terms of Senior Research Fellowship (SRF).

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© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  • Md. Jawed Ansaree
    • 1
  • Upendra Kumar
    • 1
  • Shail Upadhyay
    • 1
  1. 1.Department of Physics, Indian Institute of TechnologyBanaras Hindu UniversityVaranasiIndia

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