Solid Electrolyte Materials, Devices, and Applications
- 220 Downloads
- 16 Citations
Abstract
This paper outlines the development status, issues, and applications of several solid electrolyte electrochemical devices currently being developed by Ceramatec and its partners. Ceramatec and its commercial partner Air Products and Chemicals, Inc., (APCI) have successfully developed and demonstrated an electrochemical device that utilizes a ceria-based, solid electrolyte to separate oxygen from air [1, 2]. Other oxygen separator projects utilize ion transport membrane(s) (ITM) composed of mixed ionic and electronic conductors to transport oxygen ions across the membrane by means of a pressure differential driving force to generate high purity oxygen or a chemical reaction driving force to produce synthesis gas from methane (ITM Syngas).
Ceramatec, in partnership with SOFCo, demonstrated kilowatt class solid oxide fuel cell (SOFC) stacks operating on a variety of fuels such as pipeline natural gas and reformed diesel. Ceramatec is presently working with Cummins and SOFCo to develop low cost modular fuel cells under the Department of Energy’s Solid-state Energy Conversion Alliance (SECA) initiative. Some of Ceramatec’s other programs are focused on development of gallate electrolyte based fuel cells [3] and metallic bipolar plates [4] for lower temperature operation.
Keywords
fuel cells ion transport membranes oxygen separators solid state ionic devicesPreview
Unable to display preview. Download preview PDF.
References
- D.L. Meixner, et al., J. Electrochem. Soc. 149(9), D132 (2002).Google Scholar
- P.N. Dyer, et al., Solid State Ionics 134, 21 (2000).Google Scholar
- S. Elangovan et al., in Proc. SOFC VIII (The Electrochemical Society, NJ Pennington 2003).Google Scholar
- S. Elangovan et al., in Proc. SOFC VIII (The Electrochemical Society, NJPennington 2003).Google Scholar
- A.V. Joshi, U.S. Patent 4,879,016, Nov. 7 (1989).Google Scholar
- A.V. Joshi, et al., U.S. Patent 5,021,137, June 4 (1991).Google Scholar
- J.A. Nachlas, et al., U.S. Patent 5,298,138, March 29 (1994).Google Scholar
- J.A. Nachlas, et al., U.S. Patent 5,338,623, Aug. 16 (1994).Google Scholar
- D.M. Taylor, et al., U.S. Patent 5,378,345, Jan. 3 (1995).Google Scholar
- J.A. Nachlas, et al., U.S. Patent 5,479,700, Jan. 2 (1996).Google Scholar
- M.F. Carolan, et al., U.S. Patent 5,750,279, May 12 (1998).Google Scholar
- S. Adler, et al., U.S. Patent 5,868,918, Feb. 9 (1999).Google Scholar
- S. Adler, et al., U.S. Patent 6,042,703, March 28 (2000).Google Scholar
- S. Adler, et al., U.S. Patent 6,117,288, Sept. 12 (2000).Google Scholar
- H. Inaba and H. Tagawa, Solid State Ionics 83, 1 (1996).CrossRefGoogle Scholar
- S.J. Skinner and J.A. Kilner, Materials Today (31-37), March (2003).Google Scholar
- S.P.S. Badwal, F.T. Ciacchi, and J. Drennan, Solid State Ionics 121, 253 (1999).Google Scholar
- M. Mogensen, N.M. Sammes, and G.A. Tompsett, Solid State Ionics 129, 63 (2000).CrossRefGoogle Scholar
- J.M. Ralph and J.A., Kilner, in Solid Oxide Fuel Cells V (SOFC V) edited by U. Stimming, S.C. Singhal, H. Tagawa, W. Lehnert, PV 97–40 (The Electrochemical Society Proceedings Series, NJ, Pennington 1997), p. 1021.Google Scholar
- D.L. Meixner and R.A. Cutler, Solid State Ionics 146, 273 (2002).Google Scholar
- D.L. Meixner and R.A. Cutler, Solid State Ionics 146, 285 (2002).Google Scholar
- A.J. Bard and L.R. Faulkner, Electrochemical Methods Fundamentals and Applications (John Wiley and Sons, NY, NY, 1980), p. 91.Google Scholar
- T. Ishihara, M. Higuchi, H. Furutani, T. Fukushima, H. Nishiguchi, and Y. Takita, J. Electrochem. Soc. 5, 144 (1997).Google Scholar
- K. Huang, M. Feng, and J.B. Goodenough, J. Am. Cer. Soc., 79, 4 (1996).Google Scholar
- K. Huang and J.Goodenough, Final Report to EPRI, Report No. TR-108742, Oct. 1997.Google Scholar
- J.W. Yan, Z.G. Lu, Y. Jiang, Y.L. Dong, C.Y. Yu, and W.Z. Li, J. Electrochem. Soc. 149(9), A1132 (2002).Google Scholar
- S. Balagopal, I. Bay, and S. Elangovan, in Proc. Fifth European SOFC Forum (2002), p. 233.Google Scholar
- U.S. Patent 6,265,095—Interconnect for Solid Oxide Fuel Cells.Google Scholar
- E. Batawi, W. Glatz, W. Kraussler, M. Janousek, B. Doggwiler, and R. Diethelm, in Proc. SOFC VI, Electrochem. Soc., editedGoogle Scholar
- V.E. Stein and R.E. Richards, 7th Clean Coal Technology Conference, June 21, 1999.Google Scholar
- V.E. Stein and R.E. Richards, 16th International Pittsburgh Coal Conference Oct. 11, 1999.Google Scholar
- D. Khang, et al. U.S. Patent 5516359, 1996.Google Scholar
- R.M. Thorogood, et al., U.S. Patent 5240480, 1993.Google Scholar
- S.L. Russek et al., U.S. Patent 5562754, 1996.Google Scholar
- S.L. Russek et al., U.S. Patent 5565017, 1996.Google Scholar
- D. Khang, et al., U.S. Patent 5657624, 1997.Google Scholar
- M.F. Carolan, C.M. Chen, and S.W. Rynders, ACS Spring Meeting, New Orleans, LA, USA, March 26, 2003.Google Scholar
- S. Nataraj, R.B. Moore, and S.L. Russek, U.S. Patent 6048472, 2000.Google Scholar
- S. Nataraj and S.L. Russek, U.S. Patent 6077323, 2000.Google Scholar
- S. Nataraj and S.L. Russek, U.S. Patent 6110979, 2000.Google Scholar
- S. Nataraj, P.N. Dyer, and S.L. Russek, U.S. Patent 6114400, 2000.Google Scholar