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Photoelectric Properties of Film Composites Based on Poly(Vinyl Butyral) and Heterometallic Complexes

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Photosensitive polymeric film composites based on nonphotoconducting poly(vinyl butyral) doped with heterometallic Cu/M complexes (M = Ca, Sr) were synthesized and investigated. These composites possessed photoconducting and photovoltaic properties and electron-type photoconductivity. The greater photocurrent for composites with complexes having shorter distances between the nearest Cu metal centers was attributed to the greater probability of electron transfer between these centers.

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Correspondence to N. A. Davidenko.

Additional information

Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 84, No. 6, pp. 982–986, November–December, 2017.

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Davidenko, N.A., Kokozay, V.N., Studzinsky, S.L. et al. Photoelectric Properties of Film Composites Based on Poly(Vinyl Butyral) and Heterometallic Complexes. J Appl Spectrosc 84, 1056–1060 (2018). https://doi.org/10.1007/s10812-018-0586-8

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Keywords

  • polymeric film composites
  • heterometallic complexes
  • photoconductivity
  • photovoltaic effect
  • photogeneration
  • electron transfer
  • charge-carrier capture