Journal of Applied Spectroscopy

, Volume 72, Issue 1, pp 104–110 | Cite as

Analysis of hydrogen bonds by the IR spectra of thymine and N1,N3-deuterothymine

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Abstract

Calculations of the frequencies and absolute intensities of the IR bands of plane vibrations of thymine and N1,N3-deuterothymine in various phase states have been carried out. It has been shown that in the polycrystalline state thymine forms hydrogen bonds C2=O8...HN1 and C2=O8...HN3, and in an aqueous solution the intermolecular interaction is realized by means of the hydrogen bonds O8...HO and O...HN1.

Keywords

thymine N1,N3-deuterothymine IR spectrum calculation hydrogen bond 
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Copyright information

© Springer Science+Business Media, Inc. 2005

Authors and Affiliations

  1. 1.N. G. Chernyshevskii Saratov State UniversitySaratovRussia
  2. 2.V. I. Vernadsky Institute for Geochemistry and Analytical ChemistryMoscowRussia

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