Determination of Esters in Motor and Industrial Oils by IR Spectrometry
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Abstract
IR spectra of mixtures of mineral oil and isopropyl myristate modeling motor oils with different concentrations of esters were studied. A relationship between the absorption band intensities at 1737, 1180, and 1110 cm−1 and the ester concentration in the oil was revealed. A procedure was proposed for the determination of esters in motor oils by IR spectrometry (cmin = 1%; RSD ≤ 8.6%). The procedure was tested on several commercially available samples of lubricants (RSD ≤ 12%).
Keywords
Ester Analytical Chemistry Absorption Band Isopropyl Band Intensity
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REFERENCES
- 1.Baltenas, R., Safonov, A.S., Ushakov, A.I., and Shergalis, V., Motornye masla (Motor Oils), Moscow: Alpha-Lab, 2000.Google Scholar
- 2.Smith, A., Applied Infrared Spectroscopy, New York: Wiley, 1979. Translated under the title Prikladnaya IK-spektroskopiya, Moscow: Mir, 1982.Google Scholar
- 3.Smith, A.L. and Kiley, L.B., Appl. Spectrosc., 1964, vol. 18, p. 38.Google Scholar
- 4.Zalkind, O.A., Kolosov, V.N., Matychenko, E.S., and Orlov, V.M., Zh. Anal. Khim., 2001, vol. 56, no.11, p. 1163 [J. Anal. Chem. (Engl. Transl.), vol. 56, no. 11, p. 1020].Google Scholar
- 5.Shagidulin, R.R., Avvakumova, L.V., Doroshkina, G.M., and Selyanina, S.G., Zh. Anal. Khim., 2002, vol. 57, no.3, p. 250 [J. Anal. Chem. (Engl. Transl.), vol. 57, no.3, p. 203].Google Scholar
- 6.Evtushenko, Yu.M., Ivanov, V.M., and Zaitsev, B.E., Zh. Anal. Khim., 2003, vol. 58, no.4, p. 392 [J. Anal. Chem. (Engl. Transl.), vol. 58, no. 4, p. 347].Google Scholar
- 7.Pisareva, S.I., Pynchenkov, V.I., Ryabova, N.V., et al., Zh. Anal. Khim., 2001, vol. 56, no.10, p. 1106 [J. Anal. Chem. (Engl. Transl.), vol. 56, no. 10, p. 971].Google Scholar
- 8.Tovarnye nefteprodukty, svoistva i primenenie. Spravochnik (Commercial Petroleum Products, Properties, and Application: Reference Book), Shkol’nikov, V.M., Ed., Moscow: Khimiya, 1978.Google Scholar
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