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Facile construction of hierarchically porous carbon nanofiber aerogel for high-performance supercapacitor

  • Xi Yang
  • Lingyu Kong
  • Jianfeng Ma
  • Xinge Liu
Research Article
  • 38 Downloads
Part of the following topical collections:
  1. Capacitors

Abstract

Nanofibrillated cellulose with the features of nano-scale fibers and self-assembly has attracted significant attention to acquire porous structure for low-cost and high-performance electrode materials. Here, a carbon nanofiber aerogel was prepared by self-assembling the building-blocks of nanofibrillated cellulose into controlled macro and mesoporous structure. A typical activation was further applied to engineer abundant micropores, which led to narrowed carbon walls as well as improved surface area (1726 m2 g−1). Due to the facile-constructed hierarchical pore structure and large ion-accessible surface area, the resultant carbon aerogel exhibited comparable performance to reported electrodes from porous bio-carbons. It displayed a high specific capacitance of 169 F g−1 at a high current of 20 A g−1, retaining 73% of that at 0.2 A g−1 (231 F g−1). Furthermore, the symmetric supercapacitor showed a high capacitance retention during the long-term charge–discharge. This work provides a facile and renewable way to develop hierarchical porous bio-carbons with high charge storage capability.

Graphical abstract

Keywords

Biomass carbon aerogel Nanofibrillated cellulose Activation Hierarchical pore structure Supercapacitor 

Notes

Acknowledgements

This work was financially supported by the National Key Research and Development Program of China (2017YFD0600804).

References

  1. 1.
    Chen W, Zhang Q, Uetani K, Li Q, Lu P, Cao J, Wang Q, Liu Y, Li J, Quan Z, Zhang Y, Wang S, Meng Z, Yu H (2016) Sustainable carbon aerogels derived from nanofibrillated cellulose as high-performance absorption materials. Adv Mater Interfaces 3(10)Google Scholar
  2. 2.
    Fellinger T, White RJ, Titirici M, Antonietti M (2012) Borax-mediated formation of carbon aerogels from glucose. Adv Funct Mater 22(15):3254–3260CrossRefGoogle Scholar
  3. 3.
    Yu M, Han Y, Li J, Wang L (2017) One-step synthesis of sodium carboxymethyl cellulose-derived carbon aerogel/nickel oxide composites for energy storage. Chem Eng J 324:287–295CrossRefGoogle Scholar
  4. 4.
    Zu G, Shen J, Zou L, Wang F, Wang X, Zhang Y, Yao X (2016) Nanocellulose-derived highly porous carbon aerogels for supercapacitors. Carbon 99:203–211CrossRefGoogle Scholar
  5. 5.
    Xie Z, Wu ZF, Tan B, Lin X, Peng L (2016) Ionothermal synthesis of microporous and mesoporous carbon areogels from fructose as electrode materials for supercapacitors. J Mater Chem A 4:4497–4505CrossRefGoogle Scholar
  6. 6.
    Hao P, Zhao Z, Tian J, Li H, Sang Y, Yu G, Cai H, Liu H, Wong CP, Umar A (2014) Hierarchical porous carbon aerogel derived from bagasse for high performance supercapacitor electrode. Nanoscale 6(20):12120–12129CrossRefGoogle Scholar
  7. 7.
    Xu X, Zhou J, Nagaraju DH, Jiang L, Marinov VR, Lubineau G, Alshareef HN, Oh M (2015) Flexible, highly graphitized carbon aerogels based on bacterial cellulose/lignin: Catalyst-free synthesis and its application in energy storage devices. Adv Funct Mater 25:3193–3202CrossRefGoogle Scholar
  8. 8.
    Wu Z, Li C, Liang H, Chen J, Yu S (2013) Ultralight, flexible, and fire-resistant carbon nanofiber aerogels from bacterial cellulose. Angew Chem 52(10):2925–2929CrossRefGoogle Scholar
  9. 9.
    Sehaqui H, Zhou Q, Berglund LA (2011) High-porosity aerogels of high specific surface area prepared from nanofibrillated cellulose (NFC). Compos Sci Technol 71(13):1593–1599CrossRefGoogle Scholar
  10. 10.
    Moon RJ, Martini A, Nairn J, Simonsen J, Youngblood J (2011) Cheminform abstract: cellulose nanomaterials review: structure, properties and nanocomposites. Chem Soc Rev 42(42):3941CrossRefGoogle Scholar
  11. 11.
    Klemm D, Kramer F, Moritz S, Lindström T, Ankerfors M, Gray D, Dorris A (2011) Nanocelluloses: a new family of nature-based materials. Angew Chem Int Ed 50(24):5438–5466CrossRefGoogle Scholar
  12. 12.
    Ye GC, Zhu XY, Chen S, Li DH, Yin YF, Lu Y, Komarneni S, Yang DJ (2017) Nanoscale engineering of nitrogen-doped carbon nanofiber aerogels for enhanced lithium ion storage. J Mater Chem A 5(18):8247–8254CrossRefGoogle Scholar
  13. 13.
    Zhao J, Lu C, Xu H, Zhang X, Wei Z, Zhang X (2015) Polyethylenimine-grafted cellulose nanofibril aerogels as versatile vehicles for drug delivery. ACS Appl Mater Interfaces 7(4):2607–2615CrossRefPubMedGoogle Scholar
  14. 14.
    Köklükaya O, Carosio F, Wågberg L (2017) Superior flame-resistant cellulose nanofibril aerogels modified with hybrid layer-by-layer coatings. ACS Appl Mater Interfaces 9:29082–29092CrossRefGoogle Scholar
  15. 15.
    Wang M, Anoshkin IV, Nasibulin AG, Korhonen JT, Seitsonen J, Pere J, Kauppinen E, Ras R, Ikkala O (2013) Modifying native nanocellulose aerogels with carbon nanotubes for mechanoresponsive conductivity and pressure sensing. Adv Mater 25(17):2428–2432CrossRefGoogle Scholar
  16. 16.
    Chen XL, Paul R, Dai LM (2017) Carbon-based supercapacitors for efficient energy storage. Natl Sci Rev 0:1–37Google Scholar
  17. 17.
    Gao KZ, Shao ZQ, Li J, Wang X, Peng XQ, Wang WJ, Wang FJ (2013) Cellulose nanofiber–graphene all solid-state flexible supercapacitors. J Mater Chem A 1(1):63–67CrossRefGoogle Scholar
  18. 18.
    Zheng QF, Cai ZY, Ma ZQ, Gong SQ (2015) Cellulose nanofibril/reduced graphene oxide/carbon nanotube hybrid aerogels for highly flexible and all-solid-state supercapacitors. ACS Appl Mater Interfaces 7(5):3263–3271CrossRefGoogle Scholar
  19. 19.
    Ma LN, Liu R, Niu HJ, Xing LX, Liu L, Huang YD (2016) Flexible and freestanding supercapacitor electrodes based on nitrogen-doped carbon networks/graphene/bacterial cellulose with ultrahigh areal capacitance. ACS Appl Mater Interfaces 8(49):33608–33618CrossRefGoogle Scholar
  20. 20.
    Enterría M, Castro-Mu ~ niz A, Suarez-García F, Martínez-Alonso A, Tascon JMD, Kyotani T (2014) Effects of mesostructure order on electrochemical performance of hierarchical micro-mesoporous carbons. J Mater Chem A 2:12023–12030CrossRefGoogle Scholar
  21. 21.
    Ferrero GA, Sevilla M, Fuertes AB (2015) Mesoporous carbons synthesized by direct carbonization of citrate salts for use as high-performance capacitors. Carbon 88:239–251CrossRefGoogle Scholar
  22. 22.
    Matsui T, Tanaka S, Miyake Y (2013) Correlation between the capacitor performance and pore structure of ordered mesoporous carbons. Adv Powder Technol 24:737–742CrossRefGoogle Scholar
  23. 23.
    Yang X, Fei B, Ma J, Liu X, Yang S, Tian G, Jiang Z (2018) Porous nanoplatelets wrapped carbon aerogel by pyrolysis of regenerated bamboo cellulose aerogels as supercapacitor electrodes. Carbohyd Polym 108:385–392CrossRefGoogle Scholar
  24. 24.
    Svagan AJ, Samir MA, Berglund LA (2008) Biomimetic foams of high mechanical performance based on nanostructured cell walls reinforced by native cellulose nanofibrils. Adv Mater 20(7):1263–1269CrossRefGoogle Scholar
  25. 25.
    Shi C, Hu LT, Guo K, Li HQ, Zhai TY (2017) Highly porous carbon with graphene nanoplatelet microstructure derived from biomass waste for high-performance supercapacitors in universal electrolyte. Adv Sustain Syst 1(1–2):1600011CrossRefGoogle Scholar
  26. 26.
    Lv Y, Zhang F, Dou Y, Zhai Y, Wang J, Liu H, Xia Y, Tu B, Zhao D (2011) A comprehensive study on KOH activation of ordered mesoporous carbons and their supercapacitor application. J Mater Chem 22(1):93–99CrossRefGoogle Scholar
  27. 27.
    Sevilla M, Ferrero GA, Fuertes AB (2017) Beyond KOH activation for the synthesis of superactivated carbons from hydrochar. Carbon 114:50–58CrossRefGoogle Scholar
  28. 28.
    Yin J, Zhang D, Zhao J, Wang X, Zhu H, Wang C (2014) Meso- and micro- porous composite carbons derived from humic acid for supercapacitors. Electrochim Acta 136:504–512CrossRefGoogle Scholar
  29. 29.
    Wang J, Kaskel S (2012) KOH activation of carbon-based materials for energy storage. J Mater Chem 22(45):23710–23715CrossRefGoogle Scholar
  30. 30.
    Feng HB, Hu H, Dong HW, Xiao Y, Cai YJ, Lei BF, Liu YL, Zheng MT (2016) Hierarchical structured carbon derived from bagasse wastes: a simple and efficient synthesis route and its improved electrochemical properties for high-performance supercapacitors. J Power Sources 302:164–173CrossRefGoogle Scholar
  31. 31.
    Yi J, Yan Q, Wu CT, Zeng Y, Wu Y, Lu X, Tong Y (2017) Lignocellulose-derived porous phosphorus-doped carbon as advanced electrode for supercapacitors. J Power Sources 351:130–137CrossRefGoogle Scholar
  32. 32.
    Kishore B, Shanmughasundaram D, Penki TR. Munichandraiah N (2014) Coconut kernel-derived activated carbon as electrode material for electrical double-layer capacitors. J Appl Electrochem 44(8):903–916CrossRefGoogle Scholar
  33. 33.
    Li C, Yu J, Xiao C, Wei C, Rao M, Zhang G (2017) Microporous carbons with three-dimensional interconnected macropores based on corn stigmas for advanced supercapacitors. J Mater Sci 52(5):2816–2824CrossRefGoogle Scholar
  34. 34.
    Yang CS, Yun SJ, Jeong HK (2014) Bamboo-based activated carbon for supercapacitor applications. Curr Appl Phys 14(12):1616–1620CrossRefGoogle Scholar
  35. 35.
    He X, Ling P, Qiu J, Yu M, Zhang X, Yu C, Zheng M (2013) Efficient preparation of biomass-based mesoporous carbons for supercapacitors with both high energy density and high power density. J Power Sources 240(1):109–113CrossRefGoogle Scholar
  36. 36.
    Elmouwahidi A, Bailón-García E, Pérez-Cadenas AF, Maldonado-Hódar FJ, Carrasco-Marín F (2017) Activated carbons from KOH and H3PO4 -activation of olive residues and its application as supercapacitor electrodes. Electrochim Acta 229:219–228CrossRefGoogle Scholar
  37. 37.
    Tian X, Zhu S, Peng J, Zuo YT, Wang G, Guo XH, Zhao NQ, Ma YQ, Ma L (2017) Synthesis of micro- and meso-porous carbon derived from cellulose as an electrode material for supercapacitors. Electrochim Acta 241:170–178CrossRefGoogle Scholar
  38. 38.
    Yu M, Li J, Wang L (2016) KOH-activated carbon aerogels derived from sodium carboxymethyl cellulose for high-performance supercapacitors and dye adsorption. Chem Eng J 310:300–306CrossRefGoogle Scholar
  39. 39.
    Sevilla M, Fuertes AB (2014) Direct synthesis of highly porous interconnected carbon nanosheets and their application as high-performance supercapacitors. ACS Nano 8:5069–5078CrossRefGoogle Scholar
  40. 40.
    Batalla García B, Feaver AM, Zhang Q, Champion RD, Cao G, Fister TT, Nagle KP, Seidler GT (2008) Effect of pore morphology on the electrochemical properties of electric double layer carbon cryogel supercapacitors. J Appl Phys 104:1099CrossRefGoogle Scholar
  41. 41.
    Wang Q, Yan J, Wang Y, Wei T, Zhang M, Jing X, Fan Z (2014) Three-dimensional flower-like and hierarchical porous carbon materials as high-rate performance electrodes for supercapacitors. Carbon 67(2):119–127CrossRefGoogle Scholar
  42. 42.
    Biswal M, Banerjee A, Deo M, Ogale S (2013) From dead leaves to high energy density supercapacitors. Energy Environ Sci 6:1249–1259CrossRefGoogle Scholar
  43. 43.
    Sun X, Cheng P, Wang H, Xu H, Dang L, Liu Z, Lei Z (2015) Activation of graphene aerogel with phosphoric acid for enhanced electrocapacitive performance. Carbon 92:1–10CrossRefGoogle Scholar

Copyright information

© Springer Nature B.V. 2018

Authors and Affiliations

  1. 1.College of Materials Science and EngineeringCentral South University of Forestry and TechnologyChangshaChina
  2. 2.Department of Biomaterials, Key Laboratory of Bamboo and Rattan Science and TechnologyInternational Centre for Bamboo and RattanBeijingChina

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