Method for the Thermal Characterization of PCM Systems in the Volume Range from 100 ml to 1000 ml

  • A. GöbelEmail author
  • S. Vidi
  • F. Klinker
  • F. Hemberger
  • M. Brütting
  • H.-P. Ebert
  • H. Mehling


The storage of latent heat in phase change materials (PCM) is of great interest in many applications, for example in building applications. However, there is no standard method for the determination of the thermophysical properties of application-sized PCM specimens, i.e., specimens with sizes around 100 ml to 1000 ml. In order to close this metrological gap, a commercially available heat flow meter was modified to perform enthalpy measurements. The feasibility of this method was proven by performing comparative measurements on a stainless steel specimen using both the standard method DSC and the modified heat flow meter. Furthermore, measurements on a gypsum board with microencapsulated PCM were performed with the heat flow meter in order to determine the enthalpy. The coincidence with literature values is within ±4% which demonstrates that this method is a good choice for performing measurements on application-sized PCM specimens.


Calorimetry Heat flow meter PCM Phase change material 



This work is supported by the Federal Ministry for Economic Affairs and Energy under Grant Agreement Number 03ESP230A, Title: PCM-Metro.


  1. 1.
    C. Konstantinidou, et al., Development of measurement setup to determine the dynamic thermal behavior of building components with PCM, in Eurotherm Seminar #99 (Lleida, 2014)Google Scholar
  2. 2.
    H. Mehling, L.F. Cabeza, Heat and Cold Storage with PCM—An Up to Date Introduction into Basics and Applications (Springer, Berlin, 2008)Google Scholar
  3. 3.
    B. Zalba et al., Review on thermal energy storage with phase change: materials, heat transfer analysis and applications. Appl. Therm. Eng. 23, 251–283 (2003)CrossRefGoogle Scholar
  4. 4.
    K.A.R. Ismail, J.N.C. Castro, PCM thermal insulation in buildings. Int. J. Energy Res. 21, 1281–1296 (1997)CrossRefGoogle Scholar
  5. 5.
    D. Zhou, C.Y. Zhao, Y. Tian, Review on thermal energy storage with phase change materials (PCMs) in building applications. Appl. Energy 92, 593–605 (2011)CrossRefGoogle Scholar
  6. 6.
    N. Soares et al., Review of passive PCM latent heat thermal energy storage systems towards buildings’ energy efficiency. Energy Build. 59, 82–103 (2013)CrossRefGoogle Scholar
  7. 7.
    Knauf. Comfortboard Datasheet. 10.12.2015.
  8. 8.
    C. Castellón et al., Determination of the enthalpy of PCM as a function of temperature using a heat-flux DSC—a study of different measurement procedures and their accuracy. Int. J. Energy Res. 32, 1258–1265 (2008)CrossRefGoogle Scholar
  9. 9.
    E. Günther et al., Enthalpy of phase change materials as a function of temperature: required accuracy and suitable measurement methods. Int. J. Thermophys. 30, 1257–1269 (2009)ADSCrossRefGoogle Scholar
  10. 10.
    Y. Zhang, Y. Jiang, Y. Jiang, A simple method, the T-history method, of determining the heat of fusion, specific heat and thermal conductivity of phase-change materials. Meas. Sci. Technol. 10, 201 (1999)CrossRefGoogle Scholar
  11. 11.
    A. Lazaro et al., Verification of a T-history installation to measure enthalpy versus temperature curves of phase change materials. Meas. Sci. Technol. 17, 2168 (2006)ADSCrossRefGoogle Scholar
  12. 12.
    A. Solé et al., Review of the T-history method to determine thermophysical properties of phase change materials (PCM). Renew. Sustain. Energy Rev. 26, 425–436 (2013)CrossRefGoogle Scholar
  13. 13.
    ASTM Standard C518-Standard Test Method for Steady-State Thermal Transmission Properties by Means of the Heat Flow Meter Apparatus (ASTM International, West Conshohocken)Google Scholar
  14. 14.
    A. Tleoubaev, A. Brzezinski, L.C. Braga, Accurate simultaneous measurements of thermal conductivity and specific heat of rubber, elastomers, and other materials, in 12th Brazilian Rubber Technology Congress (Sao Paulo, 2008)Google Scholar
  15. 15.
    DIN, Guide to the Expression of Uncertainty in Measurement (Beuth Verlag GmbH, Berlin, 1995)Google Scholar

Copyright information

© Springer Science+Business Media New York 2017

Authors and Affiliations

  • A. Göbel
    • 1
    Email author
  • S. Vidi
    • 1
  • F. Klinker
    • 1
  • F. Hemberger
    • 1
  • M. Brütting
    • 1
  • H.-P. Ebert
    • 1
  • H. Mehling
    • 2
  1. 1.Bavarian Center for Applied Energy ResearchWürzburgGermany
  2. 2.WürzburgGermany

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