Equation of State for the Thermodynamic Properties of 1,1,2,2,3-Pentafluoropropane (R-245ca)

Article

Abstract

An equation of state for the calculation of the thermodynamic properties of 1,1,2,2,3-pentafluoropropane (R-245ca), which is a hydrofluorocarbon refrigerant, is presented. The equation of state (EOS) is expressed in terms of the Helmholtz energy as a function of temperature and density, and can calculate all thermodynamic properties through the use of derivatives of the Helmholtz energy. The equation is valid for all liquid, vapor, and supercritical states of the fluid, and is valid from the triple point to 450 K, with pressures up to 10 MPa. Comparisons to experimental data are given to verify the stated uncertainties in the EOS. The estimated uncertainty for density is 0.1 % in the liquid phase between 243 K and 373 K with pressures up to 6.5 MPa; the uncertainties increase outside this range, and are unknown. The uncertainty in vapor-phase speed of sound is 0.1 %. The uncertainty in vapor pressure is 0.2 % between 270 K and 393 K. The uncertainties in other regions and properties are unknown due to a lack of experimental data.

Keywords

Equation of state Helmholtz energy R-245ca Thermodynamic properties 1\({, }\)1\({, }\)2\({, }\)2\({, }\)3-Pentafluoropropane 

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Copyright information

© Springer Science+Business Media New York (Outside the USA) 2016

Authors and Affiliations

  1. 1.Honeywell Integrated Technology (China) Co. Ltd.ShanghaiChina
  2. 2.Applied Chemicals and Materials DivisionNational Institute of Standards and TechnologyBoulderUSA

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