Advertisement

International Journal of Thermophysics

, Volume 31, Issue 1, pp 131–142 | Cite as

Comparative Studies of the Mixing Effect on the Thermal Effusivity, Compressibility, and Molar Volume for Aqueous Solutions of Alcohols

  • Anna SikorskaEmail author
  • Nikodem Ponikwicki
  • Agnieszka Koniecko
  • Bogumił B. Linde
Article

Abstract

Concentration dependences of the thermal effusivity, isentropic compressibility coefficient, and molar volume were investigated experimentally for aqueous solutions of ethanol, 1-propanol, and 2-propanol. The thermal effusivity was determined using a photoacoustic method. The excess molar volume was found from measured densities, while the isentropic compressibility coefficient was calculated based on density and ultrasound velocity measurements. It has been shown that the dependence of the effusivity on concentration, expressed in mass fraction units, is nonlinear in the case of all the alcohols used. Moreover, the location of extreme deviations from linearity for the thermal effusivity, Δe, agrees well with that of characteristic points for the isentropic compressibility coefficient, κ S , and the excess molar volume, \({V_{\rm m}^{\rm E}}\), as a function of the concentration.

Keywords

Alcohols Aqueous solutions Isentropic compressibility coefficient Molar volume Photoacoustic Thermal effusivity 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    Neamtu C., Dadarlat D., Chirtoc M., Hadj Sahraoui A., Longuemart S., Bicanic D.: Instrum. Sci. Technol. 34, 225 (2006)CrossRefGoogle Scholar
  2. 2.
    Franks F.: Water: A Matrix of Life, 2nd edn, pp. 53–68. The Royal Society of Chemistry, Cambridge (2000)Google Scholar
  3. 3.
    Jerie K., Baranowski A., Ernst S., Glinski J.: Acta Phys. Polon. A69, 81 (1986)Google Scholar
  4. 4.
    Marczak W., Spurek M.: J. Solution Chem. 33, 99 (2004)CrossRefGoogle Scholar
  5. 5.
    Jeffrey G.A., McMullan R.K.: Progr. Inorg. Chem. 8, 43 (1967)CrossRefGoogle Scholar
  6. 6.
    Wakisaka A., Matsuura K.: J. Mol. Liq. 129, 25 (2006)CrossRefGoogle Scholar
  7. 7.
    Almond D.P., Patel P.M.: Photothermal Science and Techniques. Chapman & Hall, London (1996)Google Scholar
  8. 8.
    Dadarlat D., Neamtu C., Tosa V., Streza M.: Acta Chim. Slov. 54, 149 (2007)Google Scholar
  9. 9.
    Sikorska A., Dadarlat D., Linde B.B.J., Streza M., Neamtu C.: J. Phys. IV 137, 341 (2006)CrossRefGoogle Scholar
  10. 10.
    Sikorska A., Linde B.B.J., Żwirbla W.: Chem. Phys. 320, 31 (2005)CrossRefADSGoogle Scholar
  11. 11.
    Sikorska A., Linde B.: Chem. Phys. 354, 148 (2008)CrossRefADSGoogle Scholar
  12. 12.
    Gonzalez C., Iglesias M., Lanz J., Marino G., Orge B., Resa J.M.: J. Food Eng. 50, 29 (2001)CrossRefGoogle Scholar
  13. 13.
    J.A. Riddick, W.B. Bunger, T.K. Sokano (eds.), Organic Solvents. Physical Properties and Methods of Purification (Techniques of Chemistry) , 4th edn. (Wiley InterScience, New York, 1986)Google Scholar
  14. 14.
    D.R. Lide (ed.), CRC Handbook of Chemistry and Physics on CD-ROM, 86th edn. (CRC Press, Boca Raton, FL, 2006)Google Scholar
  15. 15.
    Savaroglu G., Aral E.: Int. J. Thermophys. 26, 1525 (2005)CrossRefGoogle Scholar
  16. 16.
    Savaroglu G., Aral E.: Fluid Phase Equilib. 215, 253 (2004)CrossRefGoogle Scholar
  17. 17.
    Papaloannou D., Zakklus D., Panayiotou C.: J. Chem. Eng. Data 36, 35 (1991)CrossRefGoogle Scholar
  18. 18.
    Kiyohara O., Benson G.C.: J. Solution Chem. 10, 281 (1981)CrossRefGoogle Scholar
  19. 19.
    Del Grosso V.A., Mader C.W.: J. Acoust. Soc. 52, 1442 (1972)CrossRefADSGoogle Scholar
  20. 20.
    Perondi L.F., Miranda L.C.M.: J. Appl. Phys. 62, 2955 (1987)CrossRefADSGoogle Scholar
  21. 21.
    Dupre A., Page F.T.M.: Nature 2, 210 (1870)CrossRefADSGoogle Scholar
  22. 22.
    Assael M.J., Charitidou E., Wakeham W.: Int. J. Thermophys. 10, 793 (1989)CrossRefGoogle Scholar
  23. 23.
    Wang J., Fielbig M.: Int. J. Thermophys. 16, 1353 (1994)CrossRefGoogle Scholar
  24. 24.
    Sato T., Chiba A., Nozaki R.: J. Chem. Phys. 110, 2508 (1999)CrossRefADSGoogle Scholar
  25. 25.
    Nishi N., Takahashi S., Morimoto M., Tanaka A., Muraya K.: J. Phys. Chem. 99, 462 (1995)CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC 2009

Authors and Affiliations

  • Anna Sikorska
    • 1
    Email author
  • Nikodem Ponikwicki
    • 1
  • Agnieszka Koniecko
    • 1
  • Bogumił B. Linde
    • 1
  1. 1.Institute of Experimental PhysicsUniversity of GdańskGdańskPoland

Personalised recommendations