Advertisement

Hyperfine Interactions

, 240:124 | Cite as

Influence of ligand substitution on magnetic hyperfine interaction in Dy6-based single-molecule magnets/toroics

  • Lena ScherthanEmail author
  • Thomas Ruppert
  • Yan Peng
  • Amer Baniodeh
  • Hendrik Auerbach
  • Tim Hochdörffer
  • Juliusz A. Wolny
  • Wenli Bi
  • Jiyong Zhao
  • Michael Y. Hu
  • Thomas S. Toellner
  • E. Ercan Alp
  • Dennis E. Brown
  • Christopher E. Anson
  • Annie K. Powell
  • Volker SchünemannEmail author
Article
  • 35 Downloads
Part of the following topical collections:
  1. Proceedings of the International Conference on the Applications of the Mössbauer Effect (ICAME2019), 1-6 September 2019, Dalian, China

Abstract

161Dy time-domain synchrotron Mössbauer spectroscopy (SMS), just recently presented as a novel tool to investigate Dy(III)-based single-molecule magnets (SMMs), has now been applied on two polynuclear Dy6-based wheel compounds possessing special features of single-molecule toroics (SMTs). The magnitude of the magnetic hyperfine field revealed for the Dy6 ring system [Dy6(teaH)6(NO3)6]·8MeOH is with B0 = 574.3(5) T characteristic for Dy(III) with a 6H15/2 ground state. The ligand substituted compound [Dy6(Me-teaH)6(NO3)6]·6MeCN possesses within the experimental errors the same magnetic hyperfine characteristics (B0 = 574.9(5) T). Consequently, the herein studied organic ligand variation has no perceptible influence on the magnetic hyperfine field sensed by the 161Dy(III) nuclei in these particular homometallic Dy(III)6-wheels.

Keywords

Time-domain Mössbauer spectroscopy/nuclear forward scattering Dysprosium Magnetic hyperfine field Single-molecule magnets 

Notes

Acknowledgements

This work was supported by the Deutsche Forschungsgemeinschaft (DFG) through SFB/TRR 88 3MET. The presented research used resources of the Advanced Photon Source, U.S. Department of Energy (DOE) Office of Science User Facility operated for the DOE Office of Science by Argonne National Laboratory under Contract No. DE-AC02-06CH11357. W. B. would like to acknowledge the partial support by COMPRES, the Consortium for Materials Properties Research in Earth Sciences under NSF Cooperative Agreement EAR 1606856.

References

  1. 1.
    Bogani, L., Wernsdorfer, W.: Nat. Mater. 7, 179 (2008)ADSCrossRefGoogle Scholar
  2. 2.
    Rinehart, J.D., Long, J.R.: Chem. Sci. 2, 2078 (2011)CrossRefGoogle Scholar
  3. 3.
    Liu, J.-L., Chen, Y.-C., Tong, M.-L.: Chem. Soc. Rev. 47, 2431 (2018)CrossRefGoogle Scholar
  4. 4.
    Ungur, L., Lin, S.-Y., Tang, J., Chibotaru, L.F.: Chem. Soc. Rev. 43, 6894 (2014)CrossRefGoogle Scholar
  5. 5.
    Scherthan, L., Schmidt, S.F.M., Auerbach, H., Hochdörffer, T., Wolny, J.A., Bi, W., Zhao, J., Hu, M.Y., Toellner, T., Alp, E.E., Brown, D.E., Anson, C.E., Powell, A.K., Schünemann, V.: Angew. Chem. Int. Ed. Eng. 58, 3444 (2019)CrossRefGoogle Scholar
  6. 6.
    Sieklucka, B., Pinkowicz, D.: Molecular magnetic materials. Concepts and applications. Wiley-VCH, Weinheim (2017)CrossRefGoogle Scholar
  7. 7.
    Ungur, L., Langley, S.K., Hooper, T.N., Moubaraki, B., Brechin, E.K., Murray, K.S., Chibotaru, L.F.: J. Am. Chem. Soc. 134, 18554 (2012)CrossRefGoogle Scholar
  8. 8.
    Langley, S.K., Moubaraki, B., Forsyth, C.M., Gass, I.A., Murray, K.S.: Dalton Trans. 39, 1705 (2010)CrossRefGoogle Scholar
  9. 9.
    Baniodeh, A., Magnani, N., Bräse, S., Anson, C.E., Powell, A.K.: Dalton Trans. 44, 6343 (2015)CrossRefGoogle Scholar
  10. 10.
    Mereacre, V., Baniodeh, A., Anson, C.E., Powell, A.K.: J. Am. Chem. Soc. 133, 15335 (2011)CrossRefGoogle Scholar
  11. 11.
    Vieru, V., Ungur, L., Cemortan, V., Sukhanov, A., Baniodeh, A., Anson, C.E., Powell, A.K., Voronkova, V., Chibotaru, L.F.: Chem. Eur. J. 24, 16652 (2018)CrossRefGoogle Scholar
  12. 12.
    Toellner, T.S., Hu, M.Y., Bortel, G., Sturhahn, W., Shu, D.: Nucl. Inst. Methods Phys. Res. A. 557, 670–675 (2006)ADSCrossRefGoogle Scholar
  13. 13.
    W. Sturhahn, CONUSS is free software available via http://www.nrixs.com/conuss.html
  14. 14.
    Sturhahn, W.: Hyperfine Interact. 125, 149 (2000)CrossRefGoogle Scholar
  15. 15.
    R. Röhlsberger: Nuclear Condensed Matter Physics with Synchrotron Radiation Springer-Verlag STMP 208, Berlin Heidelberg, (2004)Google Scholar
  16. 16.
    Chumakov, A.I., Rüffer, R., Leupold, O., Barla, A., Thiess, H., Gil, J.M., Alberto, H.V., Vilao, R.C., Ayres de Campos, N., Kohn, V.G., Gerken, M., Lucht, M.: Phys. Rev. B. 63, (2001)Google Scholar
  17. 17.
    Rechenberg, H.R., Bogé, M., Jeandey, C., Oddou, J.L.: Solid State Commun. 64, 277 (1987)ADSCrossRefGoogle Scholar
  18. 18.
    Ofer, S., Rakavy, M., Segal, E., Khurgin, B.: Phys. Rev. 138, (1965)ADSCrossRefGoogle Scholar
  19. 19.
    Nowik, I., Ofer, S., Wernick, J.H.: Phys. Lett. 20, (1966)Google Scholar
  20. 20.
    Greenwood, N.N., Gibb, T.C.: Mössbauer Spectroscopy. Chapman and Hall Ltd., London (1971)CrossRefGoogle Scholar
  21. 21.
    Shvyd’ko, Y.V., Gerken, M., Franz, H., Lucht, M., Gerdau, E.: Europhys. Lett. 56, 309 (2001)ADSCrossRefGoogle Scholar

Copyright information

© Springer Nature Switzerland AG 2019

Authors and Affiliations

  • Lena Scherthan
    • 1
    Email author
  • Thomas Ruppert
    • 2
  • Yan Peng
    • 2
  • Amer Baniodeh
    • 2
  • Hendrik Auerbach
    • 1
  • Tim Hochdörffer
    • 1
  • Juliusz A. Wolny
    • 1
  • Wenli Bi
    • 3
    • 4
  • Jiyong Zhao
    • 3
  • Michael Y. Hu
    • 3
  • Thomas S. Toellner
    • 3
  • E. Ercan Alp
    • 3
  • Dennis E. Brown
    • 5
  • Christopher E. Anson
    • 2
  • Annie K. Powell
    • 2
    • 6
  • Volker Schünemann
    • 1
    Email author
  1. 1.Department of PhysicsTechnische Universität KaiserslauternKaiserslauternGermany
  2. 2.Institute of Inorganic ChemistryKarlsruhe Institute of TechnologyKarlsruheGermany
  3. 3.Advanced Photon SourceArgonne National LaboratoryArgonneUSA
  4. 4.Department of GeologyUniversity of Illinois at Urbana-ChampaignUrbanaUSA
  5. 5.Department of PhysicsNorthern Illinois UniversityDeKalbUSA
  6. 6.Institute of NanotechnologyKarlsruhe Institute of TechnologyKarlsruheGermany

Personalised recommendations