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Hyperfine Interactions

, 239:33 | Cite as

Manganese-doped feroxyhyte nano-urchins produced by chemical methods

  • Naoki NishidaEmail author
  • Shota Amagasa
  • Honami Ito
  • Yoshio Kobayashi
  • Yasuhiro Yamada
Article
  • 34 Downloads
Part of the following topical collections:
  1. Proceedings of the 4th Mediterranean Conference on the Applications of the Mössbauer Effect (MECAME 2018), Zadar, Croatia, 27-31 May 2018

Abstract

Mn-doped feroxyhyte (δ-FeOOH) nanoparticles were synthesized using a wet chemical method, starting from a mixture of iron and manganese salts. The particles obtained were needle-like, around 100 nm in length, and formed had a nano-urchin structure. The compositions of the four samples obtained were calculated to be δ-Fe0.92Mn0.08OOH, δ-Fe0.75Mn0.25OOH, δ-Fe0.56Mn0.44OOH, and δ-Fe0.32Mn0.68OOH. The superparamagnetic behavior of the nanoparticles was determined from their room-temperature Mössbauer spectra. The hyperfine magnetic field of the Mn-doped δ-FeOOH nanoparticles decreased when iron atoms were substituted by Mn atoms. Furthermore, Mn atoms were locally doped into δ-FeOOH.

Keywords

Mn-doped δ-FeOOH nano-urchins Wet chemical method One-pot production 

References

  1. 1.
    Schwertmann, U., Cornell, R.M.: Iron oxides in the laboratory: preparation and characterization. Wiley-VCH Weinheim, Germany (2000)CrossRefGoogle Scholar
  2. 2.
    Bender Koch, C., Oxborrow, C.A., Mørup, S., Madsen, M.B., Quinn, A.J., Coey, J.M.D.: Magnetic properties of feroxyhyte (δ-FeOOH). Phys. Chem. Miner. 22, 333–341 (1995)ADSGoogle Scholar
  3. 3.
    Polyakov, A.Y., Goldt, A.E., Sorkina, T.A., Perminova, I.V., Pankratov, D.A., Goodilin, E.A., Tretyakov, Y.D.: Constrained growth of anisotropic magnetic δ-feOOH nanoparticles in the presence of humic substances. CrystEngComm. 14, 8097–8102 (2012)CrossRefGoogle Scholar
  4. 4.
    Pereira, M.C., Garcia, E.M., Silva, A.C., Lorencon, E., Ardisson, J.D., Murad, E., Fabris, J.D., Matencio, T., Ramalho, T.C., Rocha, M.V.J.: Nanostructured δ-feOOH: a novel photocatalyst for water splitting. J. Mater. Chem. 21, 10280–10282 (2011)CrossRefGoogle Scholar
  5. 5.
    Faria, M.C.S., Rosemberg, R.S., Bomfeti, C.A., Monteiro, D.S., Barbosa, F., Oliveira, L.C.A., Rodriguez, M., Pereira, M.C., Rodrigues, J.L.: Arsenic removal from contaminated water by ultrafine δ-feOOH adsorbents. Chem. Eng. J. 237, 47–54 (2014)CrossRefGoogle Scholar
  6. 6.
    Nishida, N., Amagasa, S., Kobayashi, Y., Yamada, Y.: Synthesis of superparamagnetic δ-feOOH nanoparticles by a chemical method. Appl. Surf. Sci. 387, 996–1001 (2016)ADSCrossRefGoogle Scholar
  7. 7.
    Rocha, T.S., Nascimento, E.S., Silva, A.C., Oliveira, H.S., Garcia, E.M., Oliveira, L.C.A., Monteiro, D.S., Rodriguez, M., Pereira, M.C.: Enhanced photocatalytic hydrogen generation from water by Ni(OH)2 loaded on Ni-doped δ-FeOOH nanoparticles obtained by one-step synthesis. RSC Adv. 3, 20308–20314 (2013)CrossRefGoogle Scholar
  8. 8.
    Pinakidou, F., Katsikini, M., Paloura, E.C., Simeonidis, K., Mitraka, E., Mitrakas, M.: Monitoring the role of Mn and Fe in the As-removal efficiency of tetravalent manganese feroxyhyte nanoparticles from drinking water: An X-ray absorption spectroscopy study. J. Colloid Interface Sci. 477, 148–155 (2016)ADSCrossRefGoogle Scholar
  9. 9.
    Burda, C., Chen, X., Narayanan, R., El-Sayed, M.A.: Chemistry and properties of nanocrystals of different shapes. Chem. Rev. 105, 1025–1102 (2005)CrossRefGoogle Scholar
  10. 10.
    Zhao, B., Li, D., Long, Y., Yang, G., Tung, C.-H., Song, K.: Modification of colloidal particles by unidirectional silica deposition for urchin-like morphologies. RSC Adv. 6, 32956–32959 (2016)CrossRefGoogle Scholar
  11. 11.
    Zhou, Y.X., Zhang, Q., Gong, J.Y., Yu, S.H.: Surfactant-assisted hydrothermal synthesis and magnetic properties of urchin-like MnWO4 microspheres. J. Phys. Chem. C 112, 13383–13389 (2008)CrossRefGoogle Scholar
  12. 12.
    Nishida, N., Amagasa, S., Kobayashi, Y., Yamada, Y.: One-pot production of copper ferrite nanoparticles using a chemical method. Hyperfine Interact. 237, 111 (2016)ADSCrossRefGoogle Scholar
  13. 13.
    Nishida, N., Amagasa, S., Kobayashi, Y., Yamada, Y.: Mixture of silver and iron oxide nanoparticles produced by chemical methods. Hyperfine Interact. 238, 71 (2017)CrossRefGoogle Scholar
  14. 14.
    Ito, H., Amagasa, S., Nishida, N., Kobayashi, Y., Yamada, Y.: Wet chemical synthesis of zinc-iron oxide nanocomposite. Hyperfine Interact. 238, 79 (2016)ADSCrossRefGoogle Scholar

Copyright information

© Springer Nature Switzerland AG 2018

Authors and Affiliations

  1. 1.Department of ChemistryTokyo University of ScienceShinjuku-kuJapan
  2. 2.Department of Engineering ScienceThe University of Electro-CommunicationsChofuJapan
  3. 3.Nishina Center for Accelerator-Based ScienceRIKENWakoJapan

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