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Hyperfine Interactions

, 239:25 | Cite as

In-beam Mössbauer spectra of 57Mn implanted into ice

  • Y. Yamada
  • Y. Sato
  • Y. Kobayashi
  • M. Mihara
  • M. K. Kubo
  • W. Sato
  • J. Miyazaki
  • T. Nagatomo
  • S. Tanigawa
  • D. Natori
  • J. Kobayashi
  • S. Sato
  • A. Kitagawa
Article
  • 30 Downloads
Part of the following topical collections:
  1. Proceedings of the 4th Mediterranean Conference on the Applications of the Mössbauer Effect (MECAME 2018), Zadar, Croatia, 27-31 May 2018

Abstract

In-beam Mössbauer spectra of 57Mn implanted into ice were measured at 13, 77, and 150 K to investigate the interaction of Fe atoms with water molecules having a lattice structure of ice. Three types of 57Fe species, which were high-spin divalent Fe2+ species, were evident in the ice. Although a divalent Fe2+ ion in water is stabilized in the form of hexaquo ferrous ions, Fe(H2O)\(_{\mathrm {6}}^{\mathrm {2+}}\), the 57Fe atom implanted into low-temperature ice had a different chemical form. Density functional theory calculations were performed to make assignments of the species identified from the Mössbauer spectra. The major species was assigned to Fe2+ bonded to four H2O molecules of the ice, Fe(H2O)\(_{\mathrm {4}}^{\mathrm {2+}}\), which is located inside of cubic form ice (ice Ic). Other minor species that appeared at 13 K was assigned to Fe2+ bonded to OH and three H2O molecules, FeOH(H2O)\(_{\mathrm {3}}^{\mathrm {+}}\), trapped in the ice. Another species that appeared at higher temperatures of 77 and 130 K was assigned to Fe(OH)2(H2O)2 trapped in ice Ic.

Keywords

In-beam Mössbauer spectroscopy Manganese-57 Iron Ice Density functional theory calculation 

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Copyright information

© Springer International Publishing AG, part of Springer Nature 2018

Authors and Affiliations

  1. 1.Department of ChemistryTokyo University of ScienceTokyoJapan
  2. 2.Graduate School of Engineering ScienceUniversity of Electro-CommunicationsChofuJapan
  3. 3.Nishina Center for Accelerator-Based ScienceRIKENWakoJapan
  4. 4.Graduate School of ScienceOsaka UniversityToyonakaJapan
  5. 5.Division of Arts and SciencesInternational Christian UniversityMitakaJapan
  6. 6.Institute of Science and EngineeringKanazawa UniversityKanazawaJapan
  7. 7.Faculty of Pharmaceutical SciencesHokuriku UniversityKanazawaJapan
  8. 8.National Institute of Radiological SciencesInageJapan

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