Advertisement

Hyperfine Interactions

, 239:24 | Cite as

Mössbauerite; polytypes in Tatkul Lake (Russia) marls and evidence in a Murray River reservoir (Australia)

  • J.-M. R. GéninEmail author
  • A. Christi
  • Y. Garcia
  • V. Ksenofontov
  • S. Mills
  • C. Ruby
  • E. Shcherbakova
Article
  • 33 Downloads
Part of the following topical collections:
  1. Proceedings of the International Conference on the Applications of the Mössbauer Effect (ICAME 2017), Saint-Petersburg, Russia, 3-8 September 2017

Abstract

Mössbauer spectroscopy characterizes “Green rust related minerals” of the fougèrite group within the hydrotalcite supergroup (Mills et al. Mineral. Mag. 76(5), 1289–1336, 2012) in locations on Earth quite different from the original studies done in a temperate climate such as Brittany- France, Western Europe. Two examples are described, the gley at the bottom of Tatkul Lake in South Urals (Russia), which is representative of permafrost conditions, and a gley at the bottom of Yanga Lake, a reservoir in the Murray River catchment (NSW-Australia), which is representative of warm and desert conditions. Complementary information is obtained from XRD patterns.

Keywords

Green rust related minerals Mössbauerite Fougèrite Trébeurdenite Gleys DLH 

Notes

Acknowledgments

Most fruitful discussions with dr. J.-M Grenèche (Universitè du Mans, France) about the magnetic properties of “ferric green rust”, that became mössbauerite, are fully acknowledged.

References

  1. 1.
    Mills, S.J., Christi, A.G., Génin, J.-M.R., Kameda, T., Colombo, F.: Nomenclature of the hydrotalcite supergroup: natural layered double hydroxides. Mineral. Mag. 76(5), 1289–1336 (2012)CrossRefGoogle Scholar
  2. 2.
    Génin, J.-M.R., Bauer, Ph., Olowe, A.A., Rézel, D.: Mössbauer study of the kinetics of simulated corrosion process of iron in chlorinated aqueous solution around room temperature: the hyperfine structure of ferrous hydroxides and green rust I. Hyperfine Interact. 29, 1355–1360 (1986)ADSCrossRefGoogle Scholar
  3. 3.
    Drissi, S.H., Refait, Ph., Abdelmoula, M., Génin, J.-M.R.: The preparation and thermodynamic properties of Fe(II)-Fe(III) hydroxycarbonate (green rust 1); Pourbaix diagram of iron in carbonate-containing aqueous media. Corros. Sci. 37, 2025–2041 (1995)CrossRefGoogle Scholar
  4. 4.
    Refait, Ph., Abdelmoula, M., Génin, J.-M.R., Sabot, R.: Green rusts in electrochemical and microbially influenced corrosion of steels. Compt. Rendus Geosci. 338(6), 476–487 (2006)ADSCrossRefGoogle Scholar
  5. 5.
    Génin, J.-M.R., Olowe, A.A., Refait, Ph., Simon, L.: On the stoichiometry and Pourbaix diagram of Fe(II)-Fe(III) hydroxysulphate or sulphate-containing green rust 2: an electrochemical and Mössbauer spectroscopy study. Corros. Sci. 38, 1751–1762 (1996)CrossRefGoogle Scholar
  6. 6.
    Refait, Ph., Charton, A., Génin, J.-M.R.: Identification, composition, thermodynamic and structural properties of a pyroaurite-like Fe(II)-Fe(III) hydroxy-oxalate Green Rust. Eur. J. Solid State Inorg. Chem. 35, 655–666 (1998)CrossRefGoogle Scholar
  7. 7.
    Génin, J.-M.R., Ruby, C.: Composition and anion ordering in some FeII−III hydroxysalt green rusts (carbonate, oxalate, methanoate); the fougèrite mineral. Solid State Sci. 10, 244–259 (2008)ADSCrossRefGoogle Scholar
  8. 8.
    Benali, O., Abdelmoula, M., Refait, Ph., Génin, J.-M.R.: Effect of orthophosphate on the oxidation products of Fe(II)-Fe(III) hydroxycarbonate: the transformation of green rust to ferrihydrite. Geochim. Cosmochim. Acta 65, 1715–1726 (2001)ADSCrossRefGoogle Scholar
  9. 9.
    Génin, J.-M.R., Aïssa, R., Géhin, A., Abdelmoula, M., Benali, O., Ernstsen, V., Ona-Nguema, G., Upadhyay, C., Ruby, C: Fougèrite and FeII−III hydroxycarbonate green rust: ordering, deprotonation and/or cation substitution; structure of hydrotalcite-like compounds and mythosic ferrosic hydroxide Fe(OH)(2+x). Solid State Sci. 7, 545–572 (2005)ADSCrossRefGoogle Scholar
  10. 10.
    Génin, J.-M.R., Ruby, C., Upadhyay, C.: Structure and thermodynamics of ferrous, stoichiometric and ferric oxyhydroxycarbonate green rusts; redox flexibility and fougèrite mineral. Solid State Sci. 8, 1330–1343 (2006)ADSCrossRefGoogle Scholar
  11. 11.
    Ruby, C., Abdelmoula, M., Naille, S., Renard, A., Khare, V., Ona-Nguema, G., Morin, G., Génin, J.-M. R.: Oxidation modes and thermodynamics of FeII−III oxyhydroxycarbonate green rust: dissolution-precipitation versus in situ deprotonation. Geochim. Cosmochim. Acta 74(3), 953–966 (2010)ADSCrossRefGoogle Scholar
  12. 12.
    Génin, J.-M.R., Mills, S.J., Christy, A.G., Guérin, O., Herbillon, A.J., Kuzmann, Ona-Nguema G., Ruby, C., Upadhyay, C.: Mössbauerite, Fe\(^{\mathrm {3+}}_{\mathrm {6}}\textit {O}_{\mathrm {4~}}\)(OH)8 [CO3]. 3H2O, the fully oxidized ‘green rust’ mineral from Mont Saint-Michel Bay, France. Mineral. Mag. 78(2), 447–465 (2014)CrossRefGoogle Scholar
  13. 13.
    Rusch, B., Génin, J.-M.R., Ruby, C., Abdelmoula, M., Bonville, P.: Mössbauer study of magnetism in FeII-FeIII (oxy)hydroxycarbonate green rusts; ferrimagnetism of FeII-FeIII hydroxycarbonate. Hyperfine Interact. 187, 7–12 (2008)ADSCrossRefGoogle Scholar
  14. 14.
    Rusch, B., Génin, J.M.R., Ruby, C., Abdelmoula, M., Bonville, P.: Ferrimagnetic properties in FeII−III (oxy)hydroxycarbonaye green rusts. Solid State Sci. 10(1), 40–49 (2008)ADSCrossRefGoogle Scholar
  15. 15.
    Vysostskii, G. N.: Gley. Eurasian Soil Sci. (Pochvovedenie) 4, 291–327 (1905)Google Scholar
  16. 16.
    Génin, J.M.R., Bourrié, G., Trolard, F., Abdelmoula, M., Jaffrezic, A., Refait, Ph., Maître, V., Humbert, B., Herbillon, A.J.: Thermodynamic equilibrium in aqueous suspensions of synthetic and natural FeII-FeIII green rusts: occurrences of the mineral in hydromorphic soils. Environ. Sci. Techn. 32, 1058–1068 (1998)ADSCrossRefGoogle Scholar
  17. 17.
    Génin, J.-M.R., Guérin, O., Herbillon, A.J., Kuzman, E., Mills, S.J., Morin, G., Ona-Nguema, G., Ruby, C., Upadhyay, C.: Redox topotactic reactions in FeII−III (oxy)-hydroxycarbonate new minerals related to fougerite in gleysols; “trébeurdenite”and “mössbauerite”. Hyperfine Interact. 204, 71–81 (2012)ADSCrossRefGoogle Scholar
  18. 18.
    Ona-Nguema, G., Abdelmoula, M., Jorand, F., Benali, O., Géhin, A., Block, J.-C., Génin, J.-M.R.: IronII−III hydroxycarbonate green rust formation and stabilization from lepidocrocite bioreduction. Environ. Sci. Technol. 36, 16–20 (2002)ADSCrossRefGoogle Scholar
  19. 19.
    Rodionov, D., Klingelhöfer, G., Bernhardt, B., Blumers, C., Kane, S., Trolard, F., Bourrié, G., Génin, J.-M.R.: Automated Mössbauer spectroscopy in the field and monitoring of fougerite. Hyperfine Interact. 167, 869–873 (2006)ADSCrossRefGoogle Scholar
  20. 20.
    Féder, F., Trolard, F., Klingelhöfer, G., Bourrié, G.: In situ Mössbauer spectroscopy: evidence for green rust (fougerite) in a gleysol and its mineralogical transformations with time and depth. Geochim. Cosmochim. Acta 69, 4463–4483 (2005)ADSCrossRefGoogle Scholar

Copyright information

© Springer International Publishing AG, part of Springer Nature 2018

Authors and Affiliations

  • J.-M. R. Génin
    • 1
    Email author
  • A. Christi
    • 2
  • Y. Garcia
    • 3
  • V. Ksenofontov
    • 4
  • S. Mills
    • 5
  • C. Ruby
    • 1
  • E. Shcherbakova
    • 6
  1. 1.Institut Jean Barriol FR2843 Université de Lorraine-CNRS, Polytech-Nancy (ex ESSTIN)Vandœuvre-Lès-NancyFrance
  2. 2.Advanced Microscopy CenterAustralian National UniversityCanberraAustralia
  3. 3.IMCNUniversité Catholique de LouvainLouvain-la-NeuveBelgium
  4. 4.Institut für Anorganische & Analytische Chemie der Johannes Gütenberg–UniversitätMainzGermany
  5. 5.GeosciencesMuseum VictoriaMelbourneAustralia
  6. 6.Institute of Mineralogy, Ural DivisionRussian Academy of SciencesMiassRussia

Personalised recommendations