Hyperfine Interactions

, 239:16 | Cite as

The effect of Zn substitution on the structure and magnetic properties of magnesium nickel ferrite

  • Abbasher M. GismelseedEmail author
  • K. A. Mohammed
  • F. N. Al-Mabsali
  • M. S. Al-Maashani
  • A. D. Al-Rawas
  • A. A. Yousif
  • H. M. Widatallah
  • M. E. Elzain
Part of the following topical collections:
  1. Proceedings of the International Conference on the Applications of the Mössbauer Effect (ICAME 2017), Saint-Petersburg, Russia, 3-8 September 2017


The series ZnxMg1−xNiFeO4(0.0 ≤ x ≤ 1.0) were prepared by the conventional solid state double sintering ceramic techniques and studied using X-ray diffraction (XRD), and Mössbauer spectroscopy techniques. The diffraction patterns of all samples show single phase cubic spinel structure. Mössbauer spectroscopy measurements at liquid nitrogen temperature show an ordered magnetic structure with well resolved tetrahedral and octahedral sites. Data analysis were performed in order to investigate the magnetic properties of the materials and their cation distribution behavior between the tetrahedral and octahedral sites. These will be discussed based on the substitution of both diamagnetic divalent.


Mössbauer Spin canting Effective magnetic moment Cation distribution 



One of the authors (Abbasher M Gismelseed) is very grateful to the Dean’s office of the college of science, Sultan Qaboos University for providing partial financial support to attend the IBAME meetings and participating the conference activities.


  1. 1.
    Aravind, G., Raghasudha, M., Ravinder, D., Manivel Raja, M., Meena, S.S., Bhatt, P., Hashim, M.: Study of structural and magnetic properties of LiNi nanoferrites synthesized by citrate-gel auto combustion method. Ceramics Inter. 42, 2941–2950 (2016)CrossRefGoogle Scholar
  2. 2.
    Velinov, N., Manova, E., Tsoncheva, T., Estournes, C., Paneva, D., Tenchev, K., Petkova, V., Koleva, K., Kunev, B., Mitov, I.: Spark plasma sintering synthesis of Ni1−xZnxFe2O4 ferrites: Mössbauer and catalytic study. Soild State Sci. 14, 1092–1099 (2012)ADSCrossRefGoogle Scholar
  3. 3.
    Gismelseed, A.M., Mohammed, K.A., Elzain, M.E., Widatallah, H.M., Al-Rawas, A.D., Yousif, A.A.: The structural and magnetic behaviour of the MgFe2−xCrxO4 spinel ferrite. Hyper. Interact. 208, 33 (2012)ADSCrossRefGoogle Scholar
  4. 4.
    Lutterotti, L., Matthies, S., Wenk, H.R.: MAUD: a User friendly Java program for material analysis using diffraction. Int. Union Crystallogr. Newslett. 21, 14 (1999)Google Scholar
  5. 5.
    Lagarec, K., Rancourt, D.G.: Rancourt, Extended Voigt-based analytic line shape method for determining N-dimensional correlated hyperfine parameter distributions in Mössbauer spectroscopy. Nucl. Instrum. Methods 129, 266 (1998)CrossRefGoogle Scholar
  6. 6.
    Mazen, S.A., Abu-Elsaad, N.I.: Structural and some magnetic properties of manganese-substituted lithium ferrites. J of Magnet. Magnet. Mater. 324, 3366–3373 (2012)ADSCrossRefGoogle Scholar
  7. 7.
    Neel, L.: Magnetic Properties of Ferrites: Ferrimagnetism and Antiferromagnetism. Ann. Phys. 3, 137 (1948)CrossRefGoogle Scholar
  8. 8.
    Yafet, Y., Kittel, C.: Antiferromagnetic arrangements in ferrites. Phys. Rev. 87, 290 (1952)ADSCrossRefGoogle Scholar
  9. 9.
    Krishna, K.R., Vijay Kumar, K., Ravindernathguta, C., Ravinder, D.: Magnetic Properties of Ni-Zn Ferrites by Citrate Gel Method. Advances in Materials Physics and Chemistry. 2, 149 (2012)ADSCrossRefGoogle Scholar
  10. 10.
    Gismelseed, A.M., Yousif, A.A.: Mössbauer study of chromium-substituted nickel ferrites. Phys. B 370, 215–222 (2005)ADSCrossRefGoogle Scholar
  11. 11.
    Sattar, A.A., Wafik, A.H., El-Shokrofy, K.M., El-Tabby, M.M.: Magnetic Properties of Cu-Zn Ferrites Doped with rare Earth Oxides. Phys. Stat. Sol. 171, 563 (1999)ADSCrossRefGoogle Scholar
  12. 12.
    Gismelseed, A.M., Widatallah, H.M., Al-Rawas, A.D., Al-Omari, I., Elzain, M.E., Yousif, A.A.: Structural characterization and magnetic properties of NiMg3x/2Cr0.9Fe1.1−xO4. Hyper. Interact. 184, 105–110 (2008)ADSCrossRefGoogle Scholar

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© Springer International Publishing AG, part of Springer Nature 2018

Authors and Affiliations

  1. 1.Department of Physics, College of ScienceSultan Qaboos UniversityAl-khoudOman
  2. 2.Department of Mathematical and Physical Sciences, College of Arts & SciencesUniversity of NizwaNizwaOman

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