Hyperfine Interactions

, 239:15 | Cite as

Structural and Mössbauer study of nanoparticles CoFe2O4 prepared by sol-gel auto-combustion and subsequent sintering

  • M. Al-Maashani
  • A. M. Gismelseed
  • K. A. M. Khalaf
  • Ali A. Yousif
  • A. D. Al-Rawas
  • H. M. Widatallah
  • M. E. Elzain
Part of the following topical collections:
  1. Proceedings of the International Conference on the Applications of the Mössbauer Effect (ICAME 2017), Saint-Petersburg, Russia, 3-8 September 2017


Single-phased nanocrystalline Cobalt ferrite (CoFe2O4) have been synthesized by sol-gel auto-combustion method. The prepared sample was divided into four different samples (auto-combustion (S1), 400 C (S2), 600 C (S3), and 1000 C (S4)). The effect of sintering temperature on the structure, and morphology, were subsequently evaluated by X-ray diffraction (XRD), Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM). The hyperfine Interactions of all samples were studied using Mössbauer Spectroscopy (MS). No significant changes noticed in lattice constant (a), and the crystallite size was found to increase with sintering temperature which can be attributed to the grain growth of the particles. SEM shows an increase in the grain size and crystallinity as the sintering temperature increases, and the particles are cubic-like for S4. The particle size of each sample was determined using TEM and were in the range of 10–70 nm for the first three samples S1, S2, and S3, and increased beyond the nano-sized limit for S4 sample. The 57Fe Mössbauer spectra at 295 K and 78 K showed two sets of magnetic hyperfine patterns for all the four samples, indicating the presence of Fe3+ in both A and B-sites, with superimposed doublet in each of S1 and S2 samples. This doublet shows a significant reduction in intensity with increasing the sintering temperature. The existence of the doublet at 78 K suggests that the blocking temperature is below 78 K temperature. From the intensity of the Fe3+ sites and assumed site occupancies of the Co2+ ions, it may be deduced that the paramagnetic doublet is associated with octahedral site.


Sol gel auto-combustion Ferrites Sintering temperature Mössbauer spectroscopy 


  1. 1.
    Barbero, B.P., Andrade Gamboa, J., Cadús, L.E.: Synthesis and characterisation of La1−xCaxFeO3 perovskite-type oxide catalysts for total oxidation of volatile organic compounds. Appl. Catal. B 65, 21–30 (2006)Google Scholar
  2. 2.
    Chicinas, I.: Soft magnetic nanocrystalline powders produced by mechanical alloying routes. J. Optoelectron. Adv. Mater. 8(2), 439–448 (2006)Google Scholar
  3. 3.
    Jonker, G.H.: Analysis of the semiconducting properties of cobalt ferrite. J. Phys. Chem. Solids 9(2), 165–175 (1959)Google Scholar
  4. 4.
    Waje, S.B., Hashim, M., Yousoff, W.D.W., Abbas, Z.: Sintering temperature dependence of room tempera-ture magnetic and dielectric properties of Co0.5Zn0.5 Fe2 O 4 prepared using mechanically alloyed nanoparticles. J. Magn. Magn. Mater. 322(6), 686–691 (2010)ADSCrossRefGoogle Scholar
  5. 5.
    Meng, X., Li, H., Chen, J., Mein, L.: Mössbauer study of cobalt ferrite nanocrystals substituted with rare-earth Y3+ ions. J. Magn. Magn. Mater. 321(9), 1155–1158 (2009)ADSCrossRefGoogle Scholar
  6. 6.
    Sajjia, M., Oubaha, M., Hasanuzzaman, M., Olabi, A.G.: Developments of cobalt ferrite nanoparticles prepared by the sol–gel process. Ceram. Int. 40, 1147–1154 (2014)CrossRefGoogle Scholar
  7. 7.
    Maaz, K., Mumtaz, A., Hasanain, S.K., Ceylan, A.: J. Magn. Mater. 308, 289–295 (2007)ADSCrossRefGoogle Scholar
  8. 8.
    Lu, L.T., Dung, N.T., Tung, L.D., Thanh, C.T., Quy, O.K., Chuc, N.V., Maenosonoe, S., Thanh, N.T.K.: Synthesis of magnetic cobalt ferrite nanoparticles with controlled morphology, monodispersity and composition: the influence of solvent, surfactant, reductant and synthetic conditions. Nanoscale- R. Soc. Chem. 8, 3141–3850 (2016)Google Scholar
  9. 9.
    Greneche, J.-M.: Magnetic nanoparticles. In: Yoshida, Y., Langouche, G (eds.) Mössbauer Spectroscopy, pp 187–241. Springer, Berlin (2013)Google Scholar
  10. 10.
    Liu, M., Lu, M., Wang, L., Xu, S., Zhao, J., Li, H.: Mössbauer study on the magnetic properties and cationdistribution of CoFe2O4 nanoparticles synthesize by hydrothermal method. J. Mater. Sci. 51, 5487–5492 (2016)ADSCrossRefGoogle Scholar
  11. 11.
    Poddar, P., Gass, J., Rebar, D.J., Srinath, S., Srikanth, H.: Magnetocaloric effect in ferrite nanoparticles. J. Magn. Magn. Mater. 307, 227–231 (2006)ADSCrossRefGoogle Scholar
  12. 12.
    Iqbal, M.J., Yaqub, N., Sepiol, B., Ismail, B.: A study of the influence of crystallite size on the electrical and magnetic properties of CuFe2 O 4. Mater. Res. Bull. 46, 1837–1842 (2011)CrossRefGoogle Scholar
  13. 13.
    Singhal, S., Singh, J., Barthwal, S.K., Chandra, K.: Preparation and characterization of nanosize nickel-substituted cobalt ferrites (Co1−xNixFe2 O 4). J. Solid State Chem. 178, 3183–3189 (2005)ADSCrossRefGoogle Scholar
  14. 14.
    Roumaih, Kh., Manapov, R.A., Sadykov, E.K., Pyataev, A.V.: Mössbauer studies of Cu 1-xNi xFeMnO 4 spinel ferrites. J. Magn. Magn. Mater. 288, 267 (2005)ADSCrossRefGoogle Scholar
  15. 15.
    Subbarao, M.V., Yusuf, S.M., Kulkarni, R.G., Madhav Rao, L., Pramana, J: Local canted spin behaviour in Co1.4−x ZnxGe0.4 Fe1.2 O 4spinels: a macroscopic, mesoscopic and microscopic study. Pramana - J. Phys. 53, 342 (1999)ADSCrossRefGoogle Scholar
  16. 16.
    Fayek, M.K., Ata-Allah, S.S.: 57Fe Mössbauer and electrical studies of the (NiO)–(Cr2 O 3) x–(Fe2 O 3)2−x system. Phys. Status Solidi (a) 198, 457–464 (2003)ADSCrossRefGoogle Scholar
  17. 17.
    Thang, D.P., Rijnders, G., Blank, D.H.A.: Spinel cobalt ferrite by complexometric synthesis. J. Magn. Magn. Mater. 295, 251–256 (2005)ADSCrossRefGoogle Scholar

Copyright information

© Springer International Publishing AG, part of Springer Nature 2018

Authors and Affiliations

  • M. Al-Maashani
    • 1
  • A. M. Gismelseed
    • 1
  • K. A. M. Khalaf
    • 2
  • Ali A. Yousif
    • 1
  • A. D. Al-Rawas
    • 1
  • H. M. Widatallah
    • 1
  • M. E. Elzain
    • 1
  1. 1.Department of Physics, College of ScienceSultan Qaboos UniversityMuscatOman
  2. 2.Department of Mathematical and Physical Sciences, College of Arts and SciencesUniversity of NizwaMuscatOman

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