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Hyperfine Interactions

, Volume 224, Issue 1–3, pp 7–13 | Cite as

Mössbauer investigation of the reaction of ferrate(VI) with sulfamethoxazole and aniline in alkaline medium

  • Virender K. SharmaEmail author
  • Zoltan Homonnay
  • Karolina Siskova
  • Libor Machala
  • Radek Zboril
Article

Abstract

Mechanisms on the oxidation of sulfamethoxazole (SMX) and aniline by ferrate(VI) (FeVIO\(_{4}{^{2-}}\), Fe(VI)) in alkaline medium suggested the formation of Fe(VI)-SMX or Fe(VI)-aniline intermediates, respectively. Fe(V) and Fe(IV) as other intermediate iron species have also been proposed in the mechanism. In this paper, rapid freeze Mössbauer spectroscopy was applied in rapidly frozen samples to explore intermediate iron species in the reactions of SMX and aniline with Fe(VI). In both reactions, Fe(VI)-SMX and Fe(VI)-aniline intermediates were not seen in second-minute time scale. Fe(V) and Fe(IV) were also not observed. Fe(III) was the only final species of the reactions.

Keywords

Ferrate High-valent iron species Fe(II) Fe(III) Antibiotics Electron-transfer Rapid-freeze technique Mössbauer spectroscopy 

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Copyright information

© Springer Science+Business Media Dordrecht 2013

Authors and Affiliations

  • Virender K. Sharma
    • 1
    Email author
  • Zoltan Homonnay
    • 2
  • Karolina Siskova
    • 3
  • Libor Machala
    • 3
  • Radek Zboril
    • 3
  1. 1.Center of Ferrate Excellence and Chemistry DepartmentFlorida Institute of TechnologyMelbourneUSA
  2. 2.Laboratory of Nuclear ChemistryInstitute of Chemistry, Eotvos Lorand UniversityBudapestHungary
  3. 3.Regional Center of Advanced Materials and TechnologiesPalacky University in OlomoucOlomoucCzech Republic

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