Hyperfine Interactions

, Volume 185, Issue 1–3, pp 133–137 | Cite as

Synthesis and spectroscopic investigation of iron(III) complexes of N′-(thioaroyl)pyridine-2-carbohydrazides

  • N. K. Singh
  • M. Singh
  • P. Tripathi
  • A. K. Srivastava
  • M. J. K. Thomas
Article

Abstract

A new series of iron(III) complexes [Fe(L1)(HL1)], [Fe(L1)Cl]; [H2L1 = N′-(2-methoxythiobenzoyl)pyridine-2-carbohydrazide], [Fe(L2)(acac)], [Fe(HL2)2Cl]; [H2L2 = N′-(4-methoxythiobenzoyl)pyridine-2-carbohydrazide] and [Fe(L3) (acac)]; [H2L3 = N′-(2-hydroxythiobenzoyl)pyridine-2-carbohydrazide] were prepared by stirring/refluxing/mixing the respective ligand with FeCl3/Fe(acac)3 in chloroform/methanol. All the compounds were characterized by elemental analyses, magnetic susceptibility, IR, UV and Mössbauer spectral data. The complexes posses high/ low spin state and have tetrahedral/octahedral geometry.

Keywords

Thiocarbohydrazides Fe(III) complexes Mössbauer spectra 

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Copyright information

© Springer Science+Business Media B.V. 2008

Authors and Affiliations

  • N. K. Singh
    • 1
  • M. Singh
    • 1
  • P. Tripathi
    • 1
  • A. K. Srivastava
    • 1
  • M. J. K. Thomas
    • 2
  1. 1.Department of ChemistryBanaras Hindu UniversityVaranasiIndia
  2. 2.Department of ChemistryUniversity of GreenwichWoolwichLondon

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