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Glass and Ceramics

, Volume 76, Issue 9–10, pp 387–390 | Cite as

Effect of Antimony Oxide on the Crystallization Particulars of Lithium-Aluminum-Silicate Glasses

  • V. I. Savinkov
  • G. Yu. Shakhgil’dyan
  • A. S. Naumov
  • N. N. Klimenko
  • V. N. SigaevEmail author
Article
  • 7 Downloads

It is shown that the introduction of antimony oxide Sb2O3 into the makeup of lithium-aluminum-silicate glass with sitall-forming composition makes it possible to suppress the often observed cracking of the glass during its crystallization at temperatures above 700°C. It was found that the introduction of Sb2O3 does not change the phase composition of the formed sitall. A scenario describing the observed effect is proposed for the implantation of antimony atoms into the residual glass phase.

Key words

crystallization sitall lithium-aluminum-silicate system eucryptite 

Notes

This work was supported by the Russian Science Foundation (contract No. 19-19-00613).

References

  1. 1.
    W. Pannhorst, “Overview,” in: Low Thermal Expansion GLACs Ceramics, Springer, New York (2005), pp. 1 – 12.Google Scholar
  2. 2.
    D. Krause and H. Bach, Low Thermal Expansion GLACs Ceramics, Springer, New York (2005).Google Scholar
  3. 3.
    M. P. Vetchinnikov, A. S. Lipatiev, G. Yu. Shakhgildyan, et al., “Direct femtosecond laser-induced formation of CdS quantum dots inside silicate glass,” Opt. Lett., 43(11), 2519 – 2522 (2018).CrossRefGoogle Scholar
  4. 4.
    G. Y. Shakhgil’dyan, A. S. Lipat’ev, M. P. Vetchinnikov, et al., “Femtosecond laser modification of zinc-phosphate glasses with high silver oxide content,” Steklo Keram., No. 11, 32 – 34 (2017); G. Yu. Shakhgil’dyan, A. S. Lipat’ev, M. P. Vetchinnikov, et al., “Femtosecond laser modification of zinc-phosphate glasses with high silver oxide content,” Glass Ceram., 73(11 – 12), 420 – 422 (2017).Google Scholar
  5. 5.
    N. A. Toropov, Structural Transformations in Glasses at Heightened Temperatures [in Russian], Nauka, Leningrad (1965).Google Scholar
  6. 6.
    V. N. Sigaev, V. I. Savinkov, E. E. Stroganova, et al., “Glass formation and crystallization of lithium-aluminum-silicate glass: effect of the form of raw materials on the melting and crystallization properties,” Steklo Keram., No. 7, 3 – 7 (2014); V. N. Sigaev, V. I. Savinkov, E. E. Stroganova, et al., “Glass formation and crystallization of lithium-aluminum-silicate glass: effect of the form of raw materials on the melting and crystallization properties,” Glass Ceram., 71(7 – 8), 225 – 228 (2014).Google Scholar
  7. 7.
    V. N. Sigaev, V. I. Savinkov, E. E. Stroganova, et al., “Glass formation and crystallization of lithium-aluminum-silicate glass: effect of phosphorus, lithium, and barium oxides on the crystallization properties,” Steklo Keram., No. 10, 21 – 24 (2015); V. N. Sigaev, V. I. Savinkov, E. E. Stroganova, et al., “Glass formation and crystallization of lithium-aluminum-silicate glass: effect of phosphorus, lithium, and barium oxides on the crystallization properties,” Glass Ceram., 71(9 – 10), 356 – 359 (2015).Google Scholar
  8. 8.
    V. N. Sigaev, V. I. Savinkov, E. E. Stroganova, and A. N. Ignatov, A Method of Obtaining Optical Sitall, RF Patent No. 2569703 C03C 10/12 [in Russian], publ. November 27, 2015.Google Scholar
  9. 9.
    A. L. Patterson, “The Scherrer formula for x-ray particle size determination,” Phys. Rev., 56, 978 – 982 (1939).CrossRefGoogle Scholar
  10. 10.
    R. A. Eppler, “Effect of antimony oxide on the anatase-rutile transformation in titanium dioxide,” J. Am. Ceram. Soc., 70, 64 – 66 (1987).CrossRefGoogle Scholar
  11. 11.
    L. Vladislavova, C. Thieme, T. Zscheckel, et al., “Crystallization of Ba1–xSrxZn2Si2O7 from the BaO/SrO/ZnO/SiO2 glass system: Effect of platinum and Sb2O3 on nucleation,” J. Alloys Compd., 793, 705 – 714 (2019).CrossRefGoogle Scholar
  12. 12.
    C. Thieme, M. Kracker, K. Thieme, et al., “Core-shell structures with metallic silver as nucleation agent of low expansion phases in BaO/SrO/ZnO/SiO2 glasses,” CrystEngComm., 21, 4373 – 4386 (2019).CrossRefGoogle Scholar
  13. 13.
    M. Mee, B. C. Davies, R. G. Orman, et al., “Antimony and silicon environments in antimony silicate glasses,” J. Solid State Chem., 183(9), 1925 – 1934 (2010).CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2020

Authors and Affiliations

  • V. I. Savinkov
    • 1
  • G. Yu. Shakhgil’dyan
    • 1
  • A. S. Naumov
    • 1
  • N. N. Klimenko
    • 1
  • V. N. Sigaev
    • 1
    Email author
  1. 1.D. I. Mendeleev Russian University of Chemical Technology (RKhTU)MoscowRussia

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