Characteristics of the Structural State of Bismuth Ions in Bismuth-Borate Glasses
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The properties and graphical plots of the properties of bismuth-borate glasses in a wide range of compositions—20 to 80 mol.% Bi2O3 —are presented. In multi-bismuth glasses both the boron and bismuth ions are found in two coordination states: B3+, B4+ and Bi3+, Bi6+. The [BiO3] groups play the role of a conventional glass former but manifest weakly in the IR spectra.
Key words
lead-free low-melting glasses properties of bismuth-borate glasses structural role of Bi ions structure of bismuth-borate glassesReferences
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