Fibre Chemistry

, Volume 49, Issue 2, pp 101–107 | Cite as

Composite Fibers Based on Cellulose and Tetraetoxysilane: Preparation, Structure and Properties

  • I. S. Makarov
  • L. K. Golova
  • L. K. Kuznetsova
  • G. N. Bondarenko
  • I. Yu. Skvortsov
  • M. V. Mironova
  • M. V. Bermeshev
Article
First Online:

A method for producing cellulose-based composite fibers with the addition of tetraethoxysilane (TEOS) with a high degree of dispersion of the additive in the cellulose matrix through a “solid phase” dissolution step of the cellulose in N-methylmorpholine-N-oxide (NMMO) is proposed. Investigation of the phase state and morphological features of mixtures of cellulose solutions with TEOS additives in NMMO has shown that in the entire range of concentrations studied, the solutions are biphasic emulsions, and their dispersity and the shape of dispersed phase droplets depend on the prehistory of solution preparation. It is established that the rheological behavior of cellulose solutions with TEOS additives varies depending on the amount of the additive. A theory about a mechanism for changing the rheological behavior of cellulose solutions with TEOS is formulated. X-ray diffraction analysis, scanning and transmission microscopy and IR spectroscopy were used to characterize the structure and morphology of composite fibers. The mechanical properties of composite cellulose fibers with TEOS are investigated.

This is a preview of subscription content, log in to check access.

Notes

The authors express their gratitude to B. F. Shklyaruk for conducting X-ray diffraction analysis of composite fibers. The work was supported by the Russian Foundation for Fundamental Research. Grant 16-33-60218 mol_a_dk.

References

  1. 1.
    A. I. Kadantseva and V. A. Tverskoi, Carbon Fibers [in Russian], textbook, Moscow State University of Fine Chemical Technologies named after M.V. Lomonosov, Moscow (2008) 55 p.Google Scholar
  2. 2.
    A. V. Skolunov and M. E. Kazakov, Fibre Chemistry, 32, No. 5, 365-371 (2000).Google Scholar
  3. 3.
    L. K. Golova, V. G. Kulichikhin, S. P. Papkov, Vysokomol. Soed. Ser. A., 28, No. 9, 1795-1809 (1986).Google Scholar
  4. 4.
    Proceedings of 92nd Meeting of the BISFA Subcommittee Terminology, Paris, France, 1989.Google Scholar
  5. 5.
    S. Peng, H. Shao, and X. Hu, J. Appl. Polymer Sci., 90, No. 7, 1941-1947 (2003).CrossRefGoogle Scholar
  6. 6.
    V. G. Kulichikhin, L. K. Golova, et al., Polymer Sci. Ser. C., 58, No. 1, 74-84 (2016).CrossRefGoogle Scholar
  7. 7.
    Yu. V. Karasev et al., Russian Federation Patent 2429316 C1 (2010).Google Scholar
  8. 8.
    V. V. Korshak, Chemical Structure and Temperature Characteristics of Polymers [in Russian], Nauka, Moscow (1970) 420 p.Google Scholar
  9. 9.
    D. N. Chernenko, dissertation, May 16, 2006, NIIgrafit, Moscow (2015) 240 p.Google Scholar
  10. 10.
    A. A. Konkin, Carbon and Other Heat-Resistant Fibrous Materials [in Russian], Khimiya, Moscow (1974) 376 p.Google Scholar
  11. 11.
    P. Olri, Russian Federation Patent, 2256013 (2005).Google Scholar
  12. 12.
    Zunli Mo, Zhongli Zhao, et al., Acta Mater. Compos. Sinica., 25, No. 4, 24-28 (2008).Google Scholar
  13. 13.
    Arnaud Demilecamps. Synthesis and characterization of polysaccharide-silica composite aerogels for thermal superinsulation. Materials. Ecole Nationale Superieure des Mines de Paris, 2015. English. <NNT : 2015ENMP0029>.Google Scholar
  14. 14.
    S. Sequeira, D. V. Evtuguin, and I. Portugal, Polymer Compos., 30, No. 9, 1275-1282 (2009).CrossRefGoogle Scholar
  15. 15.
    M. E. Kazakov, A. M. Trushnikov, and M. L. Yunitskaya, Russian Federation Patent, 2045472, (1992).Google Scholar
  16. 16.
    A. M. Trushnikov, M. E. Kazakov, et al., Russian Federation Patent, 2047674, (1993).Google Scholar
  17. 17.
    I. Yu. Skvortsov, L. B. Kandyrin, et al., Vestnik MITKhT, 5, No. 4, 98-100 (2010).Google Scholar
  18. 18.
    P. Kulpinski, J. Appl. Polymer Sci., 98, 1793-1798 (2005).CrossRefGoogle Scholar
  19. 19.
    L. K. Golova, Russian Federation Patent, 1645308 (1992).Google Scholar
  20. 20.
    L. Golova, I. Makarov, et al., Cellulose – Fundamental Aspects, InTech, Rijeka (2013) 303 p.Google Scholar
  21. 21.
    I. A. Karpov, E. N. Samarov, et al., Fiz. Tverd. Tela, 47, No. 2, 334-338 (2005).Google Scholar
  22. 22.
    R. Sato-Berru, J. M. Saniger, et al., J. Mater. Sci. Eng. A-Struct., 3, No. 4, 237-242 (2013).Google Scholar
  23. 23.
    J. Zhu, J. Wu, et al., J. Mater. Sci., 45, No. 24, 6769-6774 (2010).CrossRefGoogle Scholar
  24. 24.
    E. N. Johnson Ford, Sh. K. Mendon, et al., J. Eng. Fiber Fabr., 5, No. 1, 10-20 (2010).Google Scholar
  25. 25.
    L. Bellamy, Infrared Spectra of Complex Molecules [in Russian], Izdatinlit, Moscow (1963) 590 p.Google Scholar

Copyright information

© Springer Science+Business Media, LLC 2017

Authors and Affiliations

  • I. S. Makarov
    • 1
  • L. K. Golova
    • 1
  • L. K. Kuznetsova
    • 1
  • G. N. Bondarenko
    • 1
  • I. Yu. Skvortsov
    • 1
  • M. V. Mironova
    • 1
  • M. V. Bermeshev
    • 1
  1. 1.A. V. Topchiev Institute of Petrochemical Synthesis of the Russian Academy of SciencesMoscowRussia

Personalised recommendations