A chemical survey of exoplanets with ARIEL
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Thousands of exoplanets have now been discovered with a huge range of masses, sizes and orbits: from rocky Earth-like planets to large gas giants grazing the surface of their host star. However, the essential nature of these exoplanets remains largely mysterious: there is no known, discernible pattern linking the presence, size, or orbital parameters of a planet to the nature of its parent star. We have little idea whether the chemistry of a planet is linked to its formation environment, or whether the type of host star drives the physics and chemistry of the planet’s birth, and evolution. ARIEL was conceived to observe a large number (~1000) of transiting planets for statistical understanding, including gas giants, Neptunes, super-Earths and Earth-size planets around a range of host star types using transit spectroscopy in the 1.25–7.8 μm spectral range and multiple narrow-band photometry in the optical. ARIEL will focus on warm and hot planets to take advantage of their well-mixed atmospheres which should show minimal condensation and sequestration of high-Z materials compared to their colder Solar System siblings. Said warm and hot atmospheres are expected to be more representative of the planetary bulk composition. Observations of these warm/hot exoplanets, and in particular of their elemental composition (especially C, O, N, S, Si), will allow the understanding of the early stages of planetary and atmospheric formation during the nebular phase and the following few million years. ARIEL will thus provide a representative picture of the chemical nature of the exoplanets and relate this directly to the type and chemical environment of the host star. ARIEL is designed as a dedicated survey mission for combined-light spectroscopy, capable of observing a large and well-defined planet sample within its 4-year mission lifetime. Transit, eclipse and phase-curve spectroscopy methods, whereby the signal from the star and planet are differentiated using knowledge of the planetary ephemerides, allow us to measure atmospheric signals from the planet at levels of 10–100 part per million (ppm) relative to the star and, given the bright nature of targets, also allows more sophisticated techniques, such as eclipse mapping, to give a deeper insight into the nature of the atmosphere. These types of observations require a stable payload and satellite platform with broad, instantaneous wavelength coverage to detect many molecular species, probe the thermal structure, identify clouds and monitor the stellar activity. The wavelength range proposed covers all the expected major atmospheric gases from e.g. H2O, CO2, CH4 NH3, HCN, H2S through to the more exotic metallic compounds, such as TiO, VO, and condensed species. Simulations of ARIEL performance in conducting exoplanet surveys have been performed – using conservative estimates of mission performance and a full model of all significant noise sources in the measurement – using a list of potential ARIEL targets that incorporates the latest available exoplanet statistics. The conclusion at the end of the Phase A study, is that ARIEL – in line with the stated mission objectives – will be able to observe about 1000 exoplanets depending on the details of the adopted survey strategy, thus confirming the feasibility of the main science objectives.
KeywordsExoplanets Space missions IR spectroscopy Molecular signatures
Thousands of exoplanets have now been discovered with a huge range of masses, sizes and orbits: from rocky Earth-size planets to large gas giants grazing the surface of their host star. However, the essential nature of these exoplanets remains largely mysterious: there is no known, discernible pattern linking the presence, size, or orbital parameters of a planet to the nature of its parent star. We have little idea whether the chemistry of a planet is linked to its formation environment, or whether the type of host star drives the physics and chemistry of the planet’s birth, and evolution.
On the same plot we show the conversion of the orbital period into planetary equilibrium temperature, i.e. the temperature that a black body would have at the given distance of a Sun-like star. Notice that in general a planet is not a black body: the albedo and atmospheric greenhouse effect, which are currently unknown for most exoplanets, have a great impact on its real temperature.
1.1 The ARIEL space mission
The information provided by the present and planned missions mainly deals with the orbital data and the basic physical parameters (e.g. mass, size) of the discovered planets. In the next decade, emphasis in the field of exo-planetary science must shift from “discovery” to “understanding”, by which we mean understanding the nature of the exo-planetary bodies and their formation and evolutionary history. It is in this context that the Atmospheric Remote-sensing Infrared Exoplanet Large-survey (ARIEL) has been selected as the next medium-class science mission, M4, by the European Space Agency.
1.1.1 Highlights & limits of current knowledge of planets
Since their discovery in the early 1990’s, planets have been found around every type of star, including pulsars and binaries. As they form in the late stage of the stellar formation process, planets appear to be rather ubiquitous. Current statistical estimates indicate that, on average, every star in our Galaxy hosts at least one planetary companion [21, 44] and therefore ~1012 planets should exist just in our Milky Way.
While the number of planets discovered is still far from the thousands of billions mentioned above, the ESA Gaia mission is expected to discover tens of thousands new planets . In addition to the ongoing release of results from Kepler , ground-based surveys and the continuing K2 mission  will add to the current ground and space based efforts (see Table 6). In the future, we can look forward to many more discoveries from the TESS (NASA), Cheops (ESA) and PLATO (ESA) missions [36, 187, 192].
In all scientific disciplines, taxonomy is often the first step toward understanding, yet to date we do not have even a simple taxonomy of planets and planetary systems in our galaxy. In comparison, astrophysics faced a similar situation with the classification of stars in the late 19th and early twentieth century. Here it was the systematic observations of stellar luminosity and colours of large numbers of stars that led to the breakthrough in our understanding and the definition of the classification schemes that we are so familiar with today. The striking observational phenomenon that the brightness of a star correlates with its perceived colours, as first noted by Hertzsprung  and Russell , led to a link between observation and theoretical understanding of interior structure of a star its and their nuclear power sources [27, 72]. Thus, observation of a few basic observables in a large sample allowed scientists to predict both the physical and chemical parameters and subsequent evolution of virtually all stars. This has proved to be an immensely powerful tool, not only in studying “local” stellar evolution, but also in tracing the chemical history of the universe and even large scale cosmology.
We seek now a similar approach (i.e. the study of a large sample of objects to seek the underlying physical properties) to understand the formation and evolution of planets. Interestingly, planets do not appear to be as well behaved as stars in terms of parameter-space occupancy: what is certain, though, is that without observing a large number of planets, we will never be able to identify any trend allowing us to pinpoint the general principles underlying their formation and evolution.
The way forward: the chemical composition of a large sample of planets
A statistically significant number of planets need to be observed in order to fully test models and understand which physical parameters are most relevant. This aim requires observations of a large sample of objects (hundreds), generally repeatedly or on long timescales, which can only be done with a dedicated instrument from space, rather than with multi-purpose telescopes, such as JWST and E-ELT (see Section 1.5 for details).
The way forward: ARIEL
In order to fulfil the ambitious scientific program outlined in the previous section, ARIEL has been conceived as a dedicated survey mission for transit, eclipse & phase-curve spectroscopy capable of observing a large, diverse and well-defined planet sample. The transit and eclipse spectroscopy method, whereby the signal from the star and planet are differentiated using knowledge of the planetary ephemerides, allows us to measure atmospheric signals from the planet at levels of 10–50 ppm relative to the star. It is necessary to provide broad instantaneous wavelength coverage to detect as many molecular species as possible, to probe the thermal structure and cloud distribution and to correct for potential contaminating effects of the stellar photosphere (see Section 2 for details). This can only be achieved with a carefully designed stable payload and satellite platform [71, 181].
1.1.2 Planetary classes & ARIEL
As shown in Fig. 3, the planets falling below the critical mass range are labelled as rocky/icy planets, since they are expected to be gas-poor and mainly composed of rocks and ices. Planets above the critical mass range are labelled as gas-rich planets, as they are expected to have formed in the circumstellar discs and to have accreted a non-negligible fraction of their mass from the gaseous component of the discs. Planets falling into the critical mass range are instead labelled transitional planets, as depending on when they formed (i.e. before or after the dispersal of the circumstellar discs) they can either be massive super-Earths or sub-Neptunian gaseous planets. Each of these three classes is associated with a number of outstanding questions concerning the way they formed, how they evolved and their physical nature (see Section 1.2).
The large observational sample of ARIEL will ensure that, for each of these three classes, ARIEL will observe a statistically significant population and will be able to address the very core of these questions.
The broad classes of planets identified in Fig. 3 are all expected to have very different formation, migration and evolution histories that will be imprinted on their atmospheric and bulk chemical signatures. Many theoretical studies have tried to understand and model the various processes controlling the formation and evolution of planetary atmospheres, with some success for the Solar System. However, such atmospheric evolution models need confirmation and tight calibrations from observations. ARIEL will focus especially – but not exclusively – on warm and hot planets, for which the atmospheric composition is more representative of the bulk one.
Planetary migration: an ARIEL ally
The current sample of known extrasolar planets highlights how planetary migration is a widespread and important process in shaping the structure of planetary systems. About half the exoplanets discovered so far orbit their host star at semimajor axes less than 0.1 AU and, especially in the case of gas-rich planets (i.e. the hot-Jupiters and hot-Neptunes), which is a strong observational indication that they probably formed elsewhere – plausibly beyond the water ice condensation line – and migrated to their present position.
1.1.3 Planet density: an inaccurate indicator of exoplanets’ nature
Objects lighter than ten Earth masses (so called super-Earths, Fig. 7 top right) are even more enigmatic – we cannot derive their properties based on mass and radius alone, as pointed out in many papers in the literature (e.g. [1, 94, 239]) and noticeable e.g. in Fig. 7 bottom left. Currently, we can only guess that the extraordinarily hot and rocky planets CoRoT-7b, Kepler-10b and Kepler-78b sport silicate compounds in the gaseous and liquid phases [134, 157]. The “mega-Earth”, Kepler-10c , is twice the Earth’s size but is ~ 17 times heavier, making it among the densest planets currently known. The five inner planets orbiting Kepler-11  show an extraordinary diversity, while being dynamically packed in orbits less than 0.45 AU in radius. Their masses range from ~2 to ~13 Earth masses and they cover a factor of six in density. Kepler 11b and c are possibly super-Earths with H2O and/or H/He envelopes . Kepler 11d, e, f resemble mini-Neptunes. As explained in detail in Section 1.2, the characterisation of the atmospheres of these and other planets is essential to disentangle the degeneracies in the mass-radius relationship.
1.1.4 Current observations of exo-atmospheres: strengths & pitfalls
In the past decade, pioneering results have been obtained using transit spectroscopy with Hubble, Spitzer and ground-based facilities, enabling the detection of a few of the most abundant ionic, atomic (e.g. [45, 190]) molecular species and condensates [86, 208, 233] and constraints to be placed on the planet’s thermal structure. Information on the stability of the atmospheres of transiting planets has been collected through UV observations with Hubble (e.g. [140, 248, 83]) hydrodynamic escape processes are likely to occur for most of the planets orbiting too close to their parent star. The infrared (IR) range, on the contrary, offers the possibility of probing the neutral atmospheres of exoplanets and exploring their thermal structure (e.g. [122, 147, 213]). In the IR the molecular bands are more intense and broader than in the visible  and less perturbed by small particle clouds, and are hence easier to detect. On a large scale, the IR transit and eclipse spectra of hot-Jupiters seem to be dominated by the signature of water vapour (e.g. [13, 23, 28, 39, 47, 54, 55, 59, 63, 96, 126, 139, 154, 217, 218, 225, 226, 233]). Other carbon-bearing molecules, such as CO  and perhaps methane, are present . Similarly, the atmosphere of hot-Neptune HAT-P-11b appears to be water-rich . The data available for other warm Neptunes, such as GJ 436b, GJ 3470b are suggestive of cloudy atmospheres and do not always allow a conclusive identification of their composition (e.g. [87, 123, 164]). Multiple-band photometry and spectroscopy in the near-IR (1–5 μm) have been obtained for a number of young gaseous planets using ground-based dedicated instruments, such as VLT (SPHERE), Gemini (GPI), Subaru (SCExAO). The comparison of the chemical composition of these young gaseous objects (e.g. [144, 265]) with the composition of their migrated siblings probed through transit will help to clarify the role played by migration and by extreme irradiation on gaseous planets.
Concerning smaller planets, the analysis of the transit spectra for the 6.5 MEarth super-Earth GJ 1214b has oscillated between a metal-rich or a cloudy atmosphere (e.g. ; Kreidberg et al. [125, 126]). An interesting case is 55 Cnc e, a very hot super-Earth orbiting around its star in less than one day. Most recent observations with Spitzer/Hubble suggest a very strong day-night thermal gradient with a volatile atmosphere around it [65, 232]. Further observations in a broader spectral range are needed to understand the history and composition of the planet [106, 107, 118].
1.2 Key science questions addressed by ARIEL
What are exoplanets made of?
How do planets and planetary systems form?
How do planets and their atmospheres evolve over time?
1.2.1 How ARIEL will place the Solar System into a broader context
The Solar System has been so far our only example of a planetary system and its planets our only template of the different kinds of planetary bodies existing in our galaxy. The Solar System’s planets, however, do not sample all possible outcomes of the planetary formation process. Moreover, when studying them, we face the issue that the four giant planets are cold planets. Because of their low temperatures, their atmospheric composition is extremely affected by condensation and removal processes. The atmospheres of hot Jupiters and Neptunes present a critical advantage compared to the planets of the Solar System: their high temperature. Unlike Jupiter, Saturn, Uranus and Neptune, there is no cold trap in their atmosphere for species such as H2O, CH4, NH3, CO2 etc., which condense at much colder temperatures. Observations of hot gaseous exoplanets can therefore provide a unique access to their elemental composition (especially C, O, N, S) and enable the understanding of the early stage of planetary and atmospheric formation during the nebular phase and the following few million years (see Section 1.2.2).
Solar System difficulty 1 – Condensation:
Solar System difficulty 2 – Chemical (dis)equilibrium:
Because the main molecular carriers of the elements we want to constrain do not condense, as mentioned above, chemical disequilibrium is not necessarily a hindrance to the determination of the deep bulk elemental abundance of a planet. Indeed, when the most abundant molecules carrying a given element (for example, H2O, CO, CO2 for oxygen) can be constrained, the abundance of the element deep in the interior can be determined. This remains true as long as the transport of chemical species is dominated by turbulence and advection (as opposed to molecular diffusion), which is the case within and below the probed atmospheric regions, and that no species is removed (e.g. by condensation and settling) during the transport. The wide spectral coverage of ARIEL will prove an important asset as it covers the most visible molecular features of the main species (H2O, CO, CO2, NH3, CH4, HCN, H2S, C2H2, PH3).
This approach could of course be more difficult for some elements forming relatively transparent molecular species, e.g. nitrogen in the form of N2. For these species some chemical modeling will be needed. However, rather counter intuitively, thermochemistry at these warm to high temperatures is much better known and data-constrained than at the low temperatures encountered in Solar System giant planets. This is due to the huge databases used in industry to model combustion in engines which deal with the same type of pressure, temperature, and compositions [32, 243, 244]; these data are available to the scientific community through the KIDA database (Wakelam et al. [250, 249]). In addition, measurements of the radiatively active species and of the thermal structure of the atmosphere by ARIEL will ensure that the results of such chemical models will be better constrained, and thus more reliable than at present.
There are only 8 planets in the Solar System…
While the knowledge of the planets in our Solar System is getting more and more accurate due to ambitious exploration programs by ESA, NASA, JAXA and other agencies, the statistics are too small to draw conclusions about the general properties of the planets and planetary systems in our Galaxy. A larger population of planets covering a broader parameter space in terms of size, mass, orbital characteristics, and stellar host is needed to progress in our understanding.
1.2.2 Formation-evolution of gas-rich planets & ARIEL
Gas-rich planets possess massive envelopes of hydrogen and helium captured from the nebular gas. The metallicity of these envelopes is determined by the heavy elements accreted by the planets through the gas and the solids and, as such, it records the formation history of the planets themselves. Different elements allow one to trace different sources: metals and refractories are linked to the accreted rocks, volatiles to the ices and the most abundant elements C, O and N are linked to both the accreted solids and gas. The different formation and migration scenarios of gas-rich planets predict different relative contributions of these sources to the atmospheric composition and metallicity of the planets. In the following sections, we detail the ARIEL’s contribution to the understanding of formation and evolution processes for gas-rich planets.
How ARIEL observations will help overcome degeneracies in the study of the exoplanet interior
While mass and radius determination (and in the case of Solar System planets, gravitational moments) give constraints on the interior composition, they leave important degeneracies that can only be resolved by adding some independent constraints.
Degeneracies in the study of the exoplanet interior with only density constraints and mitigation of the problem by ARIEL atmospheric observations
Degeneracies in the study of the exoplanet interior with only density constraints
Mitigation of the problem by ARIEL atmospheric observations
Even without any uncertainty on the equation of state of the various materials potentially present, many different combinations of materials can yield the same mean density (; Baraffe et al. ).
By constraining the atmospheric composition, we will be able to constrain the elemental abundance in the deep gaseous envelope. Although this composition could still be different from that of the core, if it exists, this already reduces the uncertainty linked to the choice of the type of heavy elements to consider in modeling the interior (by fixing the C/O ratio for example).
Even at fixed composition, the distribution of the various materials inside the planet does impact the mean density. In other words, the amount of heavy elements needed to explain a given density will vary if these heavy elements are assumed to be segregated in a core or mixed into the gaseous envelope (Baraffe et al. [12, 130]).
All the heavy elements are often assumed to be gathered into a well defined core with a given composition (e.g. pure water, silicate, or iron).
Although atmospheric measurements will not give us the radial distribution of heavy elements directly, it could greatly illuminate this topic when compared to bulk internal enrichments inferred from the mass/radius data alone. Indeed, the presence or absence of a systematic bias between the enrichment values given by both methods would allow us to quantify the degree of compositional segregation and inform us on the strength of the mixing processes at play .
The temperature is currently inferred by relying on a model of the thermal evolution of the planet that itself assumes a given composition for the atmosphere (for the opacities) and that all the processes heating the interior are known (an assumption that we already know to be false because of the large unexplained radii measured for many transiting Hot Jupiters, the so-called radius anomaly; see e.g. Guillot ).
In the Solar System, the problem posed by the computation of the internal temperature is alleviated by the fact that the atmospheric temperature is measured and serves as an upper boundary condition that can be integrated downward to yield the whole thermal profile. Because spectroscopic measurements will be able to constrain the temperature profile (especially in eclipse) down to the bar level, we could ideally plan to apply the same approach to exoplanets. By providing the albedo, the thermal emission and the atmospheric composition (and thus opacity), ARIEL observations will strongly improve our modeling of the atmosphere and of the rate at which it allows the interior to cool down and contract (see Fig. 11). It will thus provide the key information necessary to infer the thermal profile in the planet.
Therefore, at present, any composition inference based on the sole knowledge of the mass and radius relies on strong additional assumptions needed to break these degeneracies.
As they will constrain both the composition and the thermal structure of the atmosphere, ARIEL observations will help mitigate or remove some of the key assumptions that are necessary today to determine the bulk composition of a planet.
When considering the large number and the diversity of the planets that will be probed by ARIEL, such enhanced mass-radius-composition constraints will thus allow us to really start addressing important questions: What are the main factors determining the total and relative elemental enrichments of a planet? Is enrichment determined by the stellar abundances or the formation location? Do planets have dense central cores?
Condensation of major species as it happens for all four solar system giant planets: ARIEL specifically targets hot and warm planets to avoid this issue.
Presence of a dense core remaining at the centre of the planet that is not mixed within the gaseous layer: Then, the bulk composition (including the core) is retrieved by combining the usual information on the mean density (from the mass/radius measurements) with our knowledge of the composition of the gaseous envelope. This removes one free parameter (and thus a degeneracy) compared to the analysis of the density alone. ARIEL measurements also help improve the planetary models used to invert the density data (see below).
Presence of layers with significant compositional gradients due to mixing inefficiency: This cannot be ruled out, even for the solar system where gravity data are available . Nevertheless, because metal enrichment must increase downward, our analysis will provide a lower limit on the total enrichment (Baraffe et al. [12, 242]).
Concerning the uncertainties on our determination of the bulk density for Giant planets, one can look at Fig. 4 in Guillot : said figure illustrates how the uncertainties in the assumptions adopted in planetary models propagate on to the uncertainty in the inferred bulk composition. Once mass and radius measured uncertainties are reduced below the 3–5% level, as should be for most ARIEL targets, important contributions to the uncertainty budget are the albedo of the planet and the opacities in the atmosphere. ARIEL observations will measure both of these quantities, therefore reducing the uncertainty on the enrichment possibly below the 10% level which is sufficient to discriminate among formation models (see Fig. 16). We expect stellar ages to be refined as well thanks to Gaia data and asteroseismology.
Gas-rich exoplanets: ARIEL ability to measure atmospheric chemistry
Observables by ARIEL
> 1500 K
Bulk composition is observable through atmosphere
Bulk composition is observable through atmosphere
2D/3D models needed to represent chemistry & dynamics
Trace gases relative abundances (especially H2O, TO, VO, CO..)
Vertical & horizontal thermal structure through transits, eclipses & phase curves
Cloud detection through albedo and blue/red filters transit observations.
Cloud composition: detection TiO, VO, TiH.. gases
Inhomogeneities in the cloud decks through time-series
Bulk composition is observable through atmosphere
Bulk composition is partially observable through atmosphere
2D/3D models needed to represent chemistry & dynamics
Equilibrium transition CO/CH4
Trace gases relative abundances (especially CH4, HCN, NH3)
Vertical & horizontal thermal structure through transits, eclipses & phase curves
Cloud detection through albedo and blue/red filters transit observations.
Cloud composition: detection FeH, SiO gases. Detection of alkali metals (Na, Li, K) mainly from ground.
Inhomogeneities in the cloud decks through time-series
Negligible difference between day/night?
Information on bulk composition at ~ T > 600 K
1-D models represents well chemistry & dynamics?
Equilibrium transition N2/NH3
Trace gases relative abundances (especially CH4, HCN, NH3)
Vertical thermal structure eclipses
Cloud detection through albedo and blue/red filters transit obs.
Inhomogeneities in the cloud decks through time-series
TEMPERATE & COLD <350 K
No information on bulk composition
Negligible difference between day/night if not tidally locked, otherwise difference is extreme
More species are condensed out in clouds & interior
1-D models expected to represent well chemistry & dynamics.
Planets around cool-stars, might be tidally locked. 3D models are necessary.
Solar System planets (not from ARIEL observations).
ARIEL observations only for most favourable gas-rich planets or rocky planets around very cool stars (e.g. TRAPPIST1 planets)
The atmospheric temperatures found in short-period exoplanet atmospheres are very high and therefore one could think that the chemical composition of these atmospheres can be described by thermochemical equilibrium, as the high temperatures lead to very fast chemical kinetics. It is exactly what was assumed in the first models used to study these kind of planets (e.g. Burrows et al. [13, 38, 39, 40, 205, 206]), but it was quickly realised that interpreting observational data of hot-Jupiters was not so straightforward. There are out-of-equilibrium processes (mixing and photodissociations) that can influence the chemical composition [168, 243]. Indeed, a strong vertical mixing induces the phenomenon of quenching. In the deep atmosphere, the temperature is high, the kinetics are fast, and the atmosphere is at thermochemical equilibrium. At lower pressures, temperature decreases, the kinetics slow down, and there is a level where the dynamical timescale becomes shorter than the chemical timescale. Here, kinetics are not sufficiently fast to maintain the atmosphere with a composition corresponding to the thermochemical equilibrium. Then, vertical transport brings the composition of this level (called quenching level) towards lower pressure levels. The chemical composition of the atmosphere above this quenching level no longer corresponds to the prediction of the thermochemical equilibrium.
the elemental abundances (how much oxygen, how much carbon...) the planet formed with
the temperature of the atmosphere, which is of course dependent on the host star and internal heating
physical processes in the atmosphere (mixing, photolysis, etc.).
The relative elemental abundances can also have a crucial effect on the atmospheric chemical composition of exoplanets. Venot et al.  studied this effect as well as the consequences on the synthetic spectra. They found that for warm atmospheres, i.e. with a temperature around 500 K, changing the C/O ratio from solar (C/O = 0.54) to twice solar (C/O = 1.1) has almost no effect of the chemical composition, nor on the synthetic spectra.
Non-Local Thermodynamic Equilibrium emissions
Non-LTE emissions from CH4 and other molecules have long been known in the upper atmospheres of the solar system gas giants (e.g. ). It provides for example insight into the emission level temperature, and is sensitive to both auroral and non-auroral conditions. The modelling of NLTE phenomena is relatively mature for the solar system gas giants. However, much work remains to be done to achieve a comparable degree of confidence in Non-LTE models for the high-temperature conditions of close-in gas exoplanets. CH4 non-LTE detections have been reported on HD189733b [216, 252], but such measurements from the ground are very challenging (Mandell et al. ). ARIEL’s spectral coverage and resolving power are well suited to detect the Non-LTE emission from CH4, which is expected to peak at 1–5 μm. Its detection will make it possible to test composition and temperature models of warm and hot Jupiter atmospheres.
Gas-rich exoplanets: ARIEL ability to measure atmospheric dynamics & cloud distribution
Chemistry and dynamics are often entangled. For instance, Agúndez et al. [2, 3] showed that for hot-Jupiters the molecules CO, H2O, and N2 and H2 show a uniform abundance with height and longitude, even including the contributions of horizontal or vertical mixing. For these molecules, it is therefore of no relevance whether horizontal or vertical quenching dominates. The vertical abundance profile of the other major molecules CH4, NH3, CO2, and HCN shows, conversely, important differences when calculated with the horizontal and vertical mixing.
Longitudinal variations in the thermal properties of the planet cause a variation in the brightness of the planet with orbital phase. This orbital modulation has been observed in the IR in transiting (e.g. ) and non-transiting  systems. In Stevenson et al.  obtained full orbit spectra with Hubble/WFC3. These observations are key constraints to 2D and 3D global circulation models (e.g. ; Showman et al. [207, 116]). ARIEL phase-curve spectroscopic measurements of the dayside and terminator regions will provide a key observational test to constrain the range of models of the thermochemical, photochemical and transport processes shaping the composition and vertical structure of these atmospheres.
One of the great difficulties in studying extrasolar planets is that we cannot directly resolve the spatial variation of these bodies, as we do for planets in our solar system. However, the evolution of the overall brightness during ingress and egress provides information on the spatial distribution of the planet’s emission. Majeau et al.  and De Wit et al.  derived a two-dimensional map of the hot-Jupiter HD189733b at 8 μm with Spitzer-IRAC (see Fig. 19).
ARIEL will provide phase curves, 2D-IR maps recorded simultaneously at multiple wavelengths, for several gaseous planets, an unprecedented achievement outside the solar system. These curves and maps will allow one to determine horizontal and vertical, thermal/chemical gradients, cloud patchiness, exo-cartography.
Gas-rich exoplanets: ARIEL ability to constrain exoplanet provenance & formation mechanisms
As the study of the formation and evolution of the Solar System and its different planetary bodies taught us, orbital parameters plus mass and size are not enough to solve the puzzle of the origin of a planetary system and to constrain its past evolution. The orbital evolution of planets is randomly affected by planetary encounters and can be drastically altered by migration. Migration, in turn, can act either very early, due to the interaction between a planet and the circumstellar disk in which it is embedded in (e.g [57, 121]), or at a later time, as a result of planet-planet scattering in unstable multiplanet configurations [49, 258]. Finally, the onset of the dynamical instability that will result in the planet-planet scattering event is affected by unknown or poorly constrained parameters, like the mass present in the form of solid bodies in the early life of the planetary system, and is therefore difficult to pinpoint in time [136, 231].
1.2.3 Formation-evolution of transitional planets & ARIEL
Transitional planets encompass both large super-Earths and sub-Neptunes. One of the critical open questions, from a planetary formation point of view, is where exactly the transition between these two populations occurs. On one hand, according to our current theoretical framework, the formation of transitional planets should occur during the lifetime of circumstellar discs to allow for these bodies to capture the nebular gas and become the planetary cores of gas-rich planets. On the other hand, the formation of super-Earths could be an extreme end product of the same process governing the formation of rocky/icy planets (see next section) and, based on the chronological data from the case of the Solar System, should take place mostly after the dispersal of the gaseous component of the circumstellar disc.
Planetary bodies reaching the critical mass range before the dispersal of the nebular gas might give rise to the exoplanetary population of sub-Neptunes (H/He rich formation scenario), while those that complete their accretion process after the dispersal of the disc might join the exoplanetary population of super-Earths (H/He poor formation scenario). In such a scenario, the planetary radius can be an unreliable indication of the nature of the planetary body in question, as we have no reason to expect that the largest super-Earths cannot possess a greater radius than the least massive sub-Neptunes (see Section 188.8.131.52).
Classification of transitional planets. Given their expected spectral amplitude (from bulk mass/radius) we can identify whether the planet is H/He rich (large spectral amplitude) has lower/mid-altitude cloud covers or heavier mean molecular weight atmosphere (dampened spectrum) or is devoid of features (heavy atmosphere or high altitude clouds). When H/He rich or dampened, we can infer the atmospheric trace gasses, temperature profiles and (if applicable) cloud distribution and particle sizes. ARIEL transit spectra will allow us to constrain the formation scenarios and structure of the interior of individual transitional planets
Why mass-radius determination is not enough to constrain the transitional planets’ composition
Today, the only constraint we have on the bulk composition of an exoplanet is from its average density. As pointed out by Adams and Seager , however, the average density is not unique within the range of compositions. Variations of a number of important planetary parameters produce planets with the same average densities but widely varying bulk compositions. A planet with a given mass and radius might have substantial water ice content (a so-called ocean planet), or alternatively a large rocky iron core and some H and/or He. Adams and Seager  conclude that H-rich thick atmospheres will confuse the interpretation of planets based on a measured mass and radius. They find that the identification of water worlds based on the mass-radius relationship alone is impossible unless a significant gas layer can be ruled out by other means. Transmission and emission spectroscopy through transit, as performed by ARIEL, is the only way to remove this degeneracy.
How the atmospheric composition can solve the issue
1.2.4 Formation-evolution of rocky/icy planets & ARIEL
Several scenarios may occur for the formation and evolution of small planets – i.e. predominantly solid planets (Fig. 2). To start with, these objects could have formed in situ, or have moved from their original location because of dynamical interaction with other bodies, or they could be remnant cores of more gaseous objects which have migrated in . Having a lower mass, their atmospheres could have evolved quite dramatically from the initial composition, with lighter molecules, such as hydrogen, escaping more easily. Impacts with other bodies, such as asteroids or comets, or volcanic activity might also have altered significantly the composition of the primordial atmosphere. None of the terrestrial planets in our Solar System have primitive atmospheres of H and He: the atmospheres of the Earth and Venus are the result of partial degassing of their mantles. Isotope analyses demonstrate that these gases have been acquired with the solid material that built-up our planet. In fact, Earth’s gases (e.g. N, H, etc.) have a chondritic isotopic composition and not a solar composition; nevertheless, there is evidence for some solar gases (e.g. Ne, with solar isotopic composition) in the deep Earth’s mantle . All this is well explained in the generally accepted view that, within the lifetime of the gaseous proto-planetary disk, the planetary embryos that formed in the inner solar system had only (approximately) the mass of Mars (see Morbidelli et al. , for a review). These embryos may have had thin primitive atmospheres and may even have absorbed some of these gases in their interiors. However, the terrestrial planets formed much later, after the removal of the gas from the protoplanetary disc, via mutual collisions among the embryos. During these high-energy impacts, the primitive atmospheres of the embryos got lost into space, while there was no more solar gas available to accrete. If super-Earths are analogous to solar system terrestrial planets in terms of formation process, but just more massive, they should have no H/He atmospheres either. ARIEL will be able to determine whether that is the case (see Table 3).
Expected impact of ARIEL observations to the understanding of the atmospheric composition of rocky and icy planets
Rocky/icy planets – science objectives
Contribution of ARIEL observations
In current formation models, if the planet is formed close to the snow line, the water content of the planetesimals could be significantly large and tens to thousands of Earth oceans of water could be accreted .
This suggests the existence of a vast population of planets with deep oceans (aqua-planets) or whose bulk composition is dominated by water (Ocean planets, Léger et al. ).
ARIEL will test this scenario through transit and eclipse spectroscopy of candidate Ocean planets such as GJ1214b.
If an object exhibits a radius that is bigger than that of a pure water world (water being the least dense, most abundant material except for H/He) of the same mass, this suggests that at least a few % of the total mass of the planet is made of low density species, most likely H/He. The fact that many objects less massive than Neptune are in this regime suggests that it is possible to accrete a large fraction of gas down to 2–3 MEarth, the mass of Kepler-11 f.
ARIEL can test this hypothesis by probing the presence of H/He and H2O through primary transit spectroscopy (Fig. 19).
An interesting case is 55 Cnc e (; ; ; ). A hot world (~2000 K), of mass 8.6 M⊕ and orbiting its host star every 18 h. Current observations suggest the presence of a hydrogen-rich atmosphere  despite its proximity to the star. The hydrogen could be primordial (perhaps remnant of a giant planet, ) or produced through photolysis of outgassed chemical species from the interior. The large day-night temperature gradient probed through phase-curves  is compatible with the presence of an atmosphere . 55 Cnc e, bears evidence to the picture that indeed super-Earths are far more complex than simple mass/radius measurements allow us to constrain.
ARIEL will test these hypotheses by observing the atmospheres of planets like 55 Cnc e over a broad wavelength range. A robust determination of the composition of the upper atmosphere of super-Earths like 55 Cnc e by ARIEL will determine the extent of compositional segregation between the atmosphere and the interior.
A very thick atmosphere (several Earth masses) of heavy gas, such as carbon dioxide, ammonia, water vapour or nitrogen, is not realistic because it requires amounts of nitrogen, carbon, and oxygen with respect to silicon much higher than all the stellar ratios detected so far .
If ARIEL detects an atmosphere which is not made of hydrogen and helium, the planet is almost certainly from the terrestrial family, which means that the thickness of the atmosphere is small compared to the planetary radius. In that case, theoretical works provided by many authors in the last decade (; [237, 238]; ; ) can be fully exploited to characterise the inner structure of the planet.
Among the most extreme examples portrayed in 2–4, “lava planets”, such as Corot-7b are so close to their host star that the temperatures reached on the dayside are sufficient to melt the surface itself. As a result, some elements, usually referred to as “refractory”, become more volatile and can form a thin silicate atmosphere . Depending on the composition of the crust and interior, the most abundant species could be, Na, K, O2, O and SiO. In addition, silicate clouds could form.
ARIEL will test these hypotheses by observing the atmospheres of candidate “lava planets” similar to Corot-7b.
An important motivation for exoplanet characterisation is to understand the probability of the occurrence of habitable worlds, i.e. suitable for surface liquid water.
While ARIEL is not conceived to study habitable planets, transiting super-Earths in the temperate zone of late M and ultra-cool dwarfs might be within reach ARIEL capabilities, depending on the stellar brightness. For instance, simulations show that ARIEL can observe the most favourable TRAPPIST1 planets in Tier 2 mode starting from 30 transits. Nevertheless, ARIEL will make a major contribution to the topic of habitability resulting from its ability to detect the composition and structure of atmospheres of many small planets outside the habitable zone, providing a statically sound ground-truth of what a habitable planet does look like.
1.2.5 Planets in rare and/or extreme conditions & ARIEL
Planets in high eccentric orbits – In contrast to Solar System planets, a large fraction of exoplanets discovered today revolve around their parent stars in eccentric orbits. In some cases the eccentricity is extreme, e.g. 0.98 for HD80606b. From a climate/chemistry perspective these planets represent a very interesting challenge (e.g. Williams and Pollard ): for instance Laughlin et al.  measured with Spitzer the thermal properties of HD80608b at periastron, finding that the planet temperature increased from 800 K to ~ 1500 K over a six-hour period. Maggio et al.  observed with XMM the highly eccentric HD 17156b: its parent star showed enhanced chromospheric and coronal emission a few hours after the passage of the planet at the periastron suggesting a complex planet-star interaction. The origin of the said “eccentric” planet is still being debated in the literature (e.g. ).
ARIEL will observe these and other similar planets to study the climate, and chemistry of high eccentricity planets. By providing the elemental composition of high-eccentricity planets, ARIEL will be able to cast light on the provenance and history of those objects.
Circumbinary planets – About twenty circumbinary planets, i.e. planets orbiting binary stars, including both S-orbit (planet orbiting just one of the 2 stars) or P-orbit (planet orbiting both stars at large distance) have been discovered. As in the case of eccentric planets, from a climate/chemistry perspective these circumbinary planets represent a very interesting challenge. ARIEL will observe transiting circumbinary planets to study the climate, and chemistry of these exotic bodies.
Transiting multi-planet systems – Among the 3500 planets discovered so far, about 600 planets are part of a planetary system. Special examples are Kepler 11 (6 transiting planets with sizes between super-Earths and Neptunes, ), Kepler 9 , 55 Cnc  and the most recent TRAPPIST1 (7 Earth-size planets transiting in the temperate zone of an ultra-cool dwarf, ). Transiting multiplanet systems give us a unique opportunity to study not just a single object, but to enable comparative exoplanetology for planets within the same extrasolar system. ARIEL observations of those and other transiting planetary systems will reveal the intra-planetary-system diversity outside our solar system. Since the planets have likely experienced a very similar formation process, this body of work will present a unique probe into the physical processes that govern the composition and structure and their evolution.
Disintegrating planets and planetesimals – The Kepler mission has reported the occurrence of a few transiting disintegrating planets (e.g. KIC 12557548b) and a postulated disintegrating planetesimal in orbit around the white dwarf WD 1145 + 017 (Vanderburg et al. ). These objects orbit their host stars in less than one day, and are suspected to carry dust tails with them. Characterizing the distribution of particle sizes will shed valuable light on the formation and evolution of the dust and, in turn, on the objects. Multi-wavelength photometry during transit (and slightly before/after) can put key constraints on the extinction cross sections of the dust particles and therefore on their sizes. So far, the observations from the UV to the IR (K′ band) have typically implied particle radii large enough (r ~0.5 μm or more) that they produce no chromatic extinction (Bochinski et al. ). For a given dust cloud, the cloud optical thickness depends strongly on the r/λ ratio. The fact that ARIEL will observe from 0.5 to 7.8 μm means that the optical thickness of the dust cloud can change significantly over ARIEL’s range of wavelengths. In other words, the same dust cloud that may appear optically thick at the shorter wavelengths would appear optically thin at the longer wavelengths. This information is pivotal to understanding the morphology of the dust cloud, the physical mechanisms that drive its variability, and in turn, to forming a more complete view of disintegrating planets and planetesimals.
Planets around flaring stars – Venot et al.  investigated how the activity of a star can influence the chemical composition and resulting spectra of typical exoplanets. They focused on the effect of stellar flares (see 184.108.40.206 for a discussion about flaring stars), and found significant changes in the chemistry of the atmospheres of two typical planets around an active M star. These changes are visible in the transit spectra of these planets, and the resulting differences are observable with ARIEL observations (see also ). ARIEL’s unique ability to measure a broad wavelength spectrum in one shot will enable the study of the atmospheres of planets around flaring stars with great accuracy and the testing/validation of theoretical predictions about planetary atmospheres in these extreme environments.
1.3 Extended use of ARIEL observations
ARIEL will generally produce time-series of a few hours duration since it will observe any particular star only around the time of each transit. This will provide spectra for stellar oscillations with periods less than around an hour (i.e. frequencies greater than about 300 μHz). At these relatively high frequencies, stellar variability is dominated by p-mode oscillations and by granulation noise. P-mode oscillations provide constraints on a star’s mass, radius and internal structure [113, 151]; information which is interesting in its own right but also necessary for accurate interpretation of the transits (e.g. as applied to Kepler data (Gilliland et al. ). Models of granulation noise (Samadi et al. [197, 198]; Cranmer et al. ) will benefit from testing against the suite of noise time-series which ARIEL will provide across a range of masses, rotation rates and metallicities. This will lead to a better understanding of photosphere convection and turbulence.
Moving to the “signal”, this can provide information about the planetary systems orbiting host stars since variations in the timing of transits are produced by perturbations from other bodies. The influence of other planets in a system has been clearly detected in Kepler data (e.g. see Fabrycky et al. ) but these transit time variations (TTVs) may also allow detection of moons (Sartoretti and Scheider [202, 119]) and large Trojans (Ford and Holman ).
No exomoons or exo-trojans have yet been discovered but, because of its high cadence, high precision photometry in the IR – where no limb darkening or stellar variability affect the signal – ARIEL could be the first observatory to do so. Monte-Carlo simulation of ARIEL’s TTV sensitivity assuming that the transiter is a ten Earth-mass ice-giant orbiting at the right distance from its star to have an effective surface temperature of ~ 500 K, show that the TTV signal produced by a five lunar-mass satellite orbiting at the maximum stable distance from the planet (i.e. 0.5 Hill radii, Domingos et al. ) is larger than the 3σ timing uncertainty. Confirmation of the exomoon candidates will require additional transit duration variation (TDV) signal, also observable by ARIEL – along with analysis of dynamic stability (Sasaki et al. ) – to distinguish between signals produced by planets, moons and Trojans.
1.4 Strategy to achieve the science objectives
1.4.1 How do we observe exo-atmospheres?
For transiting planets, we have five complementary methods to probe their atmospheric composition and thermal structure, which are described briefly in the following paragraphs. ARIEL will use them all.
When a planet passes in front of its host star (transit), the star flux is reduced by a few percent, corresponding to the planet/star projected area ratio (transit depth, Fig. 20). The planetary radius can be inferred from this measurement. If atomic or molecular species are present in the exoplanet’s atmosphere, the inferred radius is larger at some specific (absorption) wavelengths corresponding to the spectral signatures of these species [37, 205, 226].
A direct measurement of the planet’s emission/reflection can be obtained through the observation of the planetary eclipse, by recording the difference between the combined star+planet signal, measured just before and after the eclipse, and the stellar flux alone, measured during the eclipse, Fig. 20. Observations provide measurements of the flux emitted/reflected by the planet in units of the stellar flux [46, 62]. The planet/star flux ratio is defined as:
In addition to transit and eclipse observations, monitoring the flux of the star+planet system over the orbital period (phase curve) allows the retrieval of information on the planet emission at different phase angles (Fig. 20). Such observations can only be performed from space, as they typically span a time interval of more than a day (e.g. [33, 65, 213]).
In addition, eclipses can be used to spatially resolve the day-side hemisphere (eclipse mapping). During ingress and egress, the partial occultation effectively maps the photospheric emission region of the planet . Figure 20 illustrates eclipse mapping observations [66, 147].
Finally, an important aspect of ARIEL is the repeated observations of a number of key planets in both transit and eclipse mode (time series of narrow spectral bands). This will allow the monitoring of global meteorological variations in the planetary atmospheres, and to probe cloud distribution and patchiness (see e.g.  for similar work on brown dwarfs, Fig. 20).
1.4.2 ARIEL observational strategy: a 3-tier approach
Summary of the survey tiers and the detailed science objectives they will address
Reconnaissance survey (~30%)
Low Spectral Resolution observations of ~1000 planets in the VIS & IR, with SNR ~ 7
• What fraction of planets are covered by clouds?
• What fraction of small planets have still retained H/He?
• Classification through colour-colour diagrams?
• Constraining/removing degeneracies in the interpretation of mass-radius diagrams
• Albedo, bulk temperature & energy balance for a subsample.
Deep survey (~60%)
Higher Spectral Resolution observations of a sub-sample in the VIS-IR
• Main atmospheric component for small planets
• Chemical abundances of trace gases
• Atmospheric thermal structure (vertical/horizontal)
• Cloud characterization
• Elemental composition
Benchmark planets (~10%)
Very best planets, re-observed multiple time with all techniques
• Very detailed knowledge of the planetary chemistry and dynamics
• Weather, spatial & temporal variability
1.4.3 ARIEL Tier 1: exoplanet population analysis
What fraction of planets are covered by clouds?
Tier 1 mode is particularly useful for discriminating between planets that are likely to have clear atmospheres, versus those that are so cloudy that no molecular absorption features are visible in transmission. Extremely cloudy planets may be identified simply from low-resolution observations over a broad wavelength range. This preliminary information will therefore allow us to take an informed decision about whether to continue the spectral characterization of the planet at higher spectral resolution, and therefore include or not the planet in the Tier 2 sample.
In addition, it may be possible to discriminate between broad cloud types simply using photometric indices. This will also be useful for planning follow-up observations, and additionally, if borne out by full retrieval analyses of ARIEL spectroscopic data, will increase the pool of cloudy planets to compare and contrast.
What fraction of small planets have still retained molecular hydrogen?
Constraining/removing degeneracies in the interpretation of mass-radius diagrams
Potential classification through colour-colour diagrams or colour-magnitude diagrams
It is worth noting that many planetary scientists are sceptical about the usefulness of such diagrams to understand and classify planets, as they consider them too simple to capture the complexity and diversity of planets. However, as pointed out in Section 1.1.1, a large number of objects needs to be analysed to fully appreciate the underlying properties of the planetary population, a requirement which cannot be fulfilled today. Increasing by two orders of magnitude the number of planets characterised and multiplying the number of colour-filters available in the 0.5–8 μm wavelength range compared to current observations, ARIEL Tier 1 observations will provide, among other results, the ultimate test of whether an equivalent H-R diagram for planets does exist or not.
Albedo, bulk temperature & energy balance
Eclipse measurements of VIS and IR broadbands provide the bulk temperature and albedo of the planet, thereby allowing to estimate the planetary energy balance and whether the planet has an additional energy input, such as an internal heat source.
1.4.4 ARIEL Tier 2: single planets & population analysis
We used the TauREx and NEMESIS spectral retrieval models to investigate the impact of wavelength coverage, SNR and spectral resolution on the retrievability of individual model parameters from transit and eclipse spectra as observed by ARIEL. Model parameters include the planetary temperature, molecular abundances and cloud parameters.
The Non-linear optimal Estimator for MultivariateE spectral analysis (NEMESIS)  uses a combination of the correlated-k forward model with an optimal estimation retrieval scheme (Rodgers ). It has been used to successfully investigate planetary atmospheres in our own Solar System and beyond [15, 16, 133]. Here simulated spectra are generated using an input atmospheric model, and random noise of the appropriate magnitude added. These are then used as inputs for the NEMESIS optimal estimation retrieval scheme and the retrieved atmospheric state compared with the input.
Tau-REx (Tau Retrieval for Exoplanets), as developed by Waldmann et al. [256, 257], is a line-by-line radiative transfer and fully Bayesian retrieval framework. It contains 1) the optimised use of molecular line-lists from the ExoMol project [220, 221, 262]; 2) an unbiased atmospheric composition prior selection, through custom built pattern recognition software; 3) the use of two independent algorithms to fully sample the Bayesian likelihood space: nested sampling as well as a more classical Markov Chain Monte Carlo approach; 4) iterative Bayesian parameter and model selection using the full Bayesian Evidence as well as the Savage-Dickey Ratio for nested models.
1.4.5 ARIEL Tier 3: very detailed study of select planets
Missions flying earlier than ARIEL or ground-based surveys, as well as ARIEL in its Tier 1, will likely identify “oddballs” that can have an impact on our general perspective of exoplanets. As a dedicated mission, ARIEL has the capability and the time for a detailed study of these identified interesting objects (Benchmark planets).
1.4.6 Targets available for ARIEL today
ARIEL will study a large population of planets, already discovered by other facilities. In particular, it will focus on hundreds of warm/hot gaseous objects (Jupiters, Saturns, Neptunes) and of super-Earths/sub-Neptunes around bright stars of all types. There are >200 currently known planets complying with these requirements.
1.4.7 The ARIEL mission reference sample in 2028
Summary of the main surveys/projects that will provide targets for ARIEL in the next ten years . The columns on stars and expected planets refer specifically to the observations relevant for ARIEL. J = Jupiters, N=Neptunes, SN = sub-Neptunes, SE = Super-Earths
Transit from ground
Past / Ongoing
WASP/SuperWASP (; Maxted priv. Comm.)
XO (McCullough et al. )
TrES (Alonso et al. )
Space Transit & astrometry
Past / Ongoing
Gaia (; Sozzetti priv. Comm.)
PLATO (; Pagano priv. Comm.)
CHEOPS (Fortier et al. , Pagano priv. Comm.)
Past / Ongoing (mainly follow-up)
HARPS/HARPS-N (Pepe et al. )
CARMENES (Quirrenbach et al. )
AAPS (Tinney et al. )
Future (mainly follow-up)
ESPRESSO (Pepe et al. )
GIANO (Oliva et al. )
SPIROU (Artigau et al. )
1.5 Uniqueness of ARIEL and synergies with other facilities
Synoptic view of ARIEL unique capabilities compared to other future facilities with some exoplanet capabilities
Complementary spectral range
Focus on much brighter sources
Broader, simultaneous spectral range, lower resolution
• IR rather than VIS• Transmission/emission rather than reflection• Planets close to the stars rather than large separation
1.5.1 Complementarity ARIEL-JWST
Obtaining JWST spectra over 1–11 μm, will typically require observations of four separate transit (or eclipse) events using four instrument modes for planets with bright host stars (; Cowan et al. [56, 25]). Faint targets can be observed in 2 passes, provided they do not saturate NIRSpec near 1–2 μm (see Fig. 35).
A first cut, notional observing program for the JWST is encompassed in the Science Observations Design Reference Mission (SODRM – http://www.stsci.edu/jwst/science/sodrm/jwst/science/sodrm/): this consists of a number of observing programs built around seven science themes designed to allow the mission team test the observation planning tools. The allocation to exoplanet science is 16.1%. This includes also direct imaging observations.
Cowan et al.  anticipating that actually 25% of JWST time will be devoted to transiting planets (based on the community interest) and multiplying this by the 70% duty cycle of the observatory and a 5 year mission, estimate 320 days devoted to the observation of transiting exoplanets. They provide in Table 8 possible science portfolios for transiting exoplanets and the time required to complete the observations. If the focus is on hot-Jupiters, up to 150 planets could be observed by JWST. They conclude that a dedicated mission is needed to performance an atmospheric survey in order to compliant the detailed characterisation of the most challenging targets that will be conducted with JWST.
JWST will have insufficient time to study the hundreds – thousands of planets discovered by current and future missions and ground-based surveys. Additionally, these observations will be heterogeneous both in terms of spectral coverage and observing mode. The best way to capitalise on these discoveries is ARIEL, designed to perform a large survey of the brightest transiting planets in its 4-year mission.
Having a large collecting area, i.e. more photons, is certainly positive, but the lesson learnt from Spitzer and Hubble is that other aspects are also critical, especially the instrument stability and the knowledge of the instrument systematics. Kepler has been an incontestable success because it was built from start to achieve the 100 to 10 ppm photometric precision needed to discover Earth-size planets. We do not know at this time exactly how JWST data will be impacted by systematic noise, but one can assume that the noise is consistent with the best performance of HST or Spitzer as appropriate for each wavelength range. We show in Fig. 36 the comparison between JWST and ARIEL performances in the case of a hot-Jupiter. As shown from the posteriors of the molecular abundances and other atmospheric parameters, in this case the retrieved information is very similar for ARIEL and JWST.
Instruments are most of the time not calibrated at the level needed to combine multiple observations. The ability to observe simultaneously a broad wavelength range, and the use of frequent observations to external calibrators will solve these issues in the case of ARIEL.
Another critical point is the stellar activity (see Section 2.2.2), which often interferes with the possibility of combining measurements at different wavelengths, if recorded at different times. Barstow et al.  find that stellar activity could be the limiting factor for accurate retrievals of JWST observations of active stars. While simultaneous photometric observations by other observatories at relatively short wavelengths would be needed to correct this effect in the case of JWST, the ARIEL mission has been designed to be self-sufficient in its ability to correct for the effects of stellar activity. This is possible thanks to the instantaneous, broad-wavelength coverage and the strong chromatic dependence of light modulations caused by stellar variations. This is a unique capability of ARIEL, unmatched by present and future space and ground observatories.
In the first months of observations, ARIEL will re-observe some of the targets studied by JWST for calibration purposes. In general, the knowledge acquired through JWST observations will be fed into the ARIEL observational planning: e.g. whether duplicating some of the observations by JWST is desirable to study e.g. weather variability or to record a missing data set.
from Cowan et al. 
JWST Transiting Planet Observing Portfolios
Number of targets
Duration per Target
Endmember portfolios for transiting planet science with JWST. Linear combinations of these are possible, and probably more scientifically productive: e.g., 70 × 2 = 140 days of structure, 5 × 12 = 60 days of mapping, and 1 terrestrial (100 days) also adds up to 300 days.
1.5.2 Complementarity ARIEL-E-ELT
ARIEL and E-ELT are expected to be operational in the same time-frame, i.e. 2025+. ARIEL and E-ELT observations will be highly complementary and mutually beneficial. Ground-based observations of exoplanet atmospheres have many challenges and limitations: large parts of the electromagnetic spectrum are blocked from view due to absorption and scattering in the Earth’s atmosphere. In addition, the thermal background from the sky and telescope are strongly variable, making high- precision ground-based transit or eclipse spectroscopy practically impossible from the ground at wavelengths longer than 5 μm. However, the E-ELT will be very valuable in specific ways. One particularly successful observing strategy makes use of spectroscopy at a very high dispersion of R~100,000 using the METIS instrument . At this resolution, molecular bands in exoplanet spectra are resolved into hundreds to thousands of individual lines, whose signals can be combined to secure a molecular detection. Only astrophysical information over small wavelength scales is preserved, hence the line-contrast is being measured with respect to a local pseudo-continuum. This technique has been used very successfully using the VLT, for both exoplanet transmission spectroscopy  and emission spectroscopy (Brogi et al. ), and will be more effective on the next-generation of extra-large telescopes.
E-ELT observations will be highly complementary to ARIEL. The ARIEL spectra, which will be obtained over a large instantaneous wavelength range, are crucial for measuring the most important planetary atmosphere parameters − the temperature-pressure profile, the cloud coverage and the key molecular abundances. With these parameters determined by ARIEL, i.e. the local pseudo-continuum, high-resolution E-ELT observations, providing planet differential transmission and day-side spectra at specific wavelengths, can then be calibrated and used to target other, specific aspects of the planetary atmospheres. For the best observable targets, the E-ELT can provide information on the rotation of the planet and high-altitude wind speeds using the absorption line profiles [209, 210].
2 Scientific requirements
In section 2 we presented the science objectives of the ARIEL mission. Here we detail the science requirements which need to be met by the ARIEL mission to enable those objectives. These include the spectral coverage and resolution, the signal to noise ratios, the photometric stability and the data needed to be able to deal with astrophysical noise sources such as stellar variability, activity and flaring.
2.1 Required wavelength coverage, spectral resolution and S/N
Measure both albedo and thermal emission to determine the planetary energy budget (Fig. 37).
Classify the variety of planets at different temperatures.
- Detect the variety of chemical components present in warm & hot exoplanet atmospheres (Fig. 38)
Guarantee redundancy (i.e. molecules detected in multiple bands of the spectrum) to secure the reliability of the detection – especially when multiple species overlap in a spectral range (Fig. 39).
Enable an optimal retrieval of the chemical abundances and thermal profile (Section 220.127.116.11).
Detect clouds and constrain their spatial distribution and temporal variability (see Section 1.4.3).
Correct for stellar variability (see Section 2.2.2)
Summary of the ARIEL spectral coverage (left column) and resolving power as designed (central column), see Puig et al. . The key scientific motivations are listed in the right column
Required R & SNR
SNR ≥ 200 on the Stellar SNR
SNR ≥ 7 on the exoplanet (goal)
• Correction for stellar activity (optimised early stars)
• Measurement of planetary albedo
• Detection of Rayleigh scattering/clouds
SNR ≥ 200 on the Stellar SNR
SNR ≥ 7 on the exoplanet (goal)
• Correction for stellar activity (optimised late stars)
• Measurement of planetary albedo
• Detection of clouds
SNR ≥ 200 on the Stellar SNR
SNR ≥ 7 on the exoplanet (goal)
• Correction stellar activity (optimised late stars)
Detection of clouds
R: 10 averaged bands for 1.25–7.8 μm
SNR ≥ 7
R ≥ 10
SNR ≥ 7
R ≥ 10
SNR ≥ 7
• Correction for stellar activity (optimised late stars)
• Detection of clouds
• Detection of molecules (esp. TiO, VO, metal hydrides)
• Measurement of planet temperature (optimised hot)
• Retrieval of molecular abundances
• Retrieval of vertical and horizontal thermal structure
• Detection time variability (weather/cloud distribution)
(Channels 0 & 1)
R ≥ 50 for λ<3.9μm; R ≥ 15 for (λ>3.9μm)
SNR ≥ 7
R ≥ 100 for (λ<3.9μm); R ≥ 30 for (λ>3.9μm)
SNR ≥ 7
• Detection of atmospheric chemical components
• Measurement of planet temps. (optimised warm-hot)
• Retrieval of molecular abundances
• Retrieval of vertical and horizontal thermal structure
• Detection time variability (weather/cloud distribution)
For hot and warm planets, the wavelength coverage 1.25–7.8 μm is critical for ARIEL, as it guarantees that ALL the key chemical species (shown in Fig. 39) can be detected.
Redundancy (i.e. molecules detected in multiple bands of the spectrum) significantly improves the reliability of the detection, especially when multiple chemical species overlap in a particular spectral range.
Redundancy in molecular detection is also necessary to allow the retrieval of the vertical thermal structure and molecular abundances .
The moderate resolving power of ARIEL will permit the detection of most molecules at warm and hot temperature given the spectral broadening .
The spectrograph in the NIR and VIS/NIR photometers enable to detect and differentiate between of Rayleigh scattering as opposed to clouds/hazes (see Fig. 37 right).
2.2 Dealing with Systematic and Astrophysical Noise
2.2.1 ARIEL performance requirements
the design of the spacecraft, payload and instruments
the calibration strategy to characterise all possible systematic variations in performance
the data processing pipeline(s).
In deriving the noise performance requirements, a sensitivity study has been completed that shows that the mission science goals are very robust against the noise parameters assumed. The minimum required noise performance (which is exceed by the design) allows the mission science to be achieved with up to 1000 planets being observed within the baseline mission lifetime to the required SNR. Increases in the noise levels lead only to a gradual degradation of the number of targets that can be successfully observed in each of the 3 tiers during the mission life.
The ARIEL end-to-end instrument simulator: ARIEL-Sim
The ExoSim tool  has been used to simulate the performance of the ARIEL system (Fig. 40). ExoSim is a generic, numerical end-to-end simulator of transit spectroscopy intended as open-access software. It permits the simulation of a time-resolved spectroscopic observation in either primary transit or secondary eclipse. The observational parameters can be adjusted, and the telescope and instrument parameters changed in a simple manner to simulate a variety of existing or proposed instruments. ExoSim is a tool to explore a variety of signal and noise issues that occur in transit spectroscopy observations, including the effects of the instrument systematics, correlated noise sources, and stellar variability. The simulations are fast, which allows ExoSim to be used for Monte Carlo simulations of such observations. A specific instance “ARIEL-Sim” has been created with the baseline instrument parameters of the payload and spacecraft performance detailed in .
The simulator has been validated against both existing published transit data (, Kreidberg et al. [125, 126]), and the combination of simulator and ARIEL specific instrument parameters has been validated against the independent (static) Radiometric Model prepared by ESA . The simulations include a representative pointing jitter timeline (supplied by the ESA industrial study teams) and all other noise sources identified in . A basic data reduction pipeline (not using optimal data extraction and noise decorrelation techniques at this stage) is used to post-process the output data in the same way as the real science data will be handled.
Postprocessing analysis techniques
Within the ARIEL consortium, we have developed field-leading time series decorrelation techniques based on non-parametric machine learning ([251, 254] [164, 165, 166, 167, 253]; Damiano et al. ) which recently won the Spitzer time-series data challenge  and enabled the first detection of a super-Earth’s atmosphere with Hubble-WFC3 . These techniques are highly complementary to traditional de-trending and post-processing as they de-trend the data from systematic (e.g. instrument) noise on a purely statistical basis. Hence, we can well address any residual systematic noise that has not be captured by more traditional, parametric data de-trending routines.
2.2.2 Correcting for stellar activity
The differential spectroscopy measurement strategy of ARIEL (before/during/after the transit) may be affected by changes in the host star spectrum on the timescale of the transit. Changes in the host star spectrum are caused by magnetic activity (flares, co-rotating active regions and spots) and convective turbulence (granulation, pulsations). Results from the Kepler mission  indicate that most G dwarfs have photometric dispersions less than 50 ppm over a period of 6 h, while most late-K and M dwarfs vary at a level of some 500 ppm. Note that Kepler operates in the visible where stellar photometric variability is few times higher than in the “sweet spot” of ARIEL – the NIR and MIR – because of the contrast between surface inhomogeneities and the stellar photosphere.
The ARIEL mission has been designed to be self-sufficient in its ability to correct for the effects of stellar activity. This is possible thanks to the instantaneous, broad-wavelength coverage and the strong chromatic dependence of light modulations caused by stellar variations. This is a unique capability of ARIEL, unmatched by present and future space and ground observatories.
The impact of stellar variations on the ARIEL data has been carefully evaluated in parallel by many teams part of the ARIEL consortium working on stars [109, 156, 204, 263] and more specifically through ARIEL-Sim . We have explored several possible approaches to evaluate the effect of oscillations and stellar activity and developed methodologies to prove the performance of ARIEL data in reaching the required precision. We describe here these methodologies.
ARIEL-Sim simulations of impact of stellar variability on ARIEL observations
convection-driven variability arising from pulsations and granulations
star spot activity.
Pulsations and granulations
Convection in the outer layer of stars induces stochastic pulsations and the emergence of granulation on the stellar surface. Both of these phenomena cause local temperature fluctuations and yield a stellar effective temperature that varies over time. Figure 42 shows time series from the convection model simulating pulsations and granulations. For oscillations, the timescales and amplitudes of optical and infrared variability were calculated based on University of Leuven’s simulations using the BiSON solar data from Broomhall et al.  where amplitudes and frequencies were rescaled using the scaling relations from Kjeldsen and Bedding . The peak-to-peak variation due to oscillations was computed on a 10 h basis. The Marcs model atmosphere parameters for the different spectral types were chosen following Habets and Heintze  and Pickles . For granulation, the variability for solar type stars was simulated using different red noise components due to active regions and background granulation . The scaling from the optical to the infrared was done using SEDs from Marcs models .
Timelines from these models were incorporated into the ARIEL ExoSim model and the noise resulting on the out-of-transit timelines obtained for each spectral bin and channel. An example is shown in Fig. 43, which shows the noise budget for M-dwarf GJ1214 (faintest required target) in AIRS channel 0, where the stellar convection noise can be compared to the contribution of other noise sources. We find that noise from granulations and pulsations is insignificant when compared to the photon noise and most other noise sources.
A stellar spots/faculae model has been developed which is now fully integrated with ARIEL-Sim . The model can simulate different star classes, with spots and faculae of different sizes, temperatures and spatial distributions.
We note that the spot temperature contrast has a known relationship to spectral class (E.g. Andersen and Korhonen ), but the faculae contrast is not so well constrained in stars other than the Sun. The facula brightness temperature for the Sun also varies with limb position. The faculae temperature contrast in ARIEL-Sim is based on the ratio of average faculae: spot temperature contrast in the Sun and scale for other stars based on their spot contrast. Secondly the exact faculae: spot area (Q) ratio is not well established for stars other than the Sun. There is some evidence that the Q ratio is lower in more active (higher spot fraction) stars. A relationship based on extrapolation of data in Chapman et al. (1997) is used to predict the Q ratio at spot fractions much higher than exist on the Sun. The Q ratio falls with spot coverage based on this relation. Pixelation and overlap effects reduce the final Q ratio somewhat from the input Q ratio.
Due to this uncertainty, spots-only simulations in addition to spots and faculae can be run to assess the worst-case scenario of unopposed spot effects, though the faculae simulation is based on reasonable physical assumptions.
To address the concern that plage areas might not always be associated with spots, the plage areas can be uncoupled from the spots if required. Figure 44 right is an example of a 1% spot coverage case (with an equatorial spatial distribution) where a fraction of the faculae coverage is uncoupled to the spots, giving a final Q ratio of 10:1.
A default log-normal distribution is used for the size distribution of spots based on the size distribution pattern for the Sun (Bogdan [31, 211]) adapted for different spot coverages. However, ARIEL-Sim can also simulate spots with uniform size distributions as shown below for a 10% hemispheric spot coverage case, where the cold spots are 2 degrees in diameter (Fig. 45).
ARIEL-Sim can simulate active regions as well as uniform distributions. In Fig. 46 we show four distinct configurations.
Unocculted spots/faculae may increase/decrease the transit depth, with the bias being wavelength dependent.
Occulted spots/faculae may reduce/increase the transit depth obtained through curve fitting, with the amplitude on the light curve being wavelength dependent.
Occulted/unocculted spots with molecular absorption features can contaminate the planet spectrum.
The situation is simpler for eclipses, where the planetary emission follows directly from the depth measurement. In this case, only activity-induced variations on the timescale of the duration of the occultation need to be corrected to ensure that the proper stellar flux baseline is used.
Impact of stellar activity to spectral shapes
The TauREx spectral retrieval code was upgraded to assess the impact of stellar activity due to spots and faculae to transit and eclipse spectra and retrieved results. The code can simulate several combinations of spots and faculae (spot/faculae size distribution, % star coverage, spatial distribution), for stars of different temperatures (Waldmann and Sarkar, submitted). SEDs of stars are simulated with Phoenix models.
As illustrated by Fig. 47, spots and faculae will impact primarily the short wavelengths. Spots’ and Faculae’ contributions at wavelengths longer than 2 μm are in the Rayleigh-Jeans tail of the stellar/spot/faculae SEDs and exhibit sufficiently smooth trends (when modelled with Phoenix models) for the relative retrievals of trace gas abundances to not be biased by unocculted spots/faculae. Most spot/faculae effects are observed <1.0 μm and exhibit smooth trends where complex molecules are predominantly detected. The main effect observed is a bias to the absolute Rp/Rs level (i.e. spectra shifted up or down) for large coverage of spots or faculae. Figure 47 further shows the effect of various combinations of unocculted spots and faculae coverages for a G0V (HD 209458 type) star. This near constant bias in Rp/Rs over 2 μm can affect the retrieval accuracy of the planet radius and temperature mainly but, due to the lack of sharp spectral features in the main ARIEL wavelengths, we find that unocculted stellar activity does not significantly bias trace gas abundance retrieval results.
Figure 48 shows the retrievals of a very spotty star with 10% spot coverage and 60% faculae and the retrieval of a spot/faculae free star. In both cases the spot and faculae coverage, spot and faculae temperatures as well as the trace gases (H2O, CH4), planet radius and temperatures were fitted as free parameters. As seen in Fig. 48, trace gas abundances were retrieved with good accuracy without systematic biases. We note that these cases all assume an extremely pessimistic level of uncorrected stellar activity. Here the stellar activity information contained in <1 μm data has not been used to correct for these effects (or as informed priors on stellar activity parameters) but instead has been taken as ‘unknown and uncorrectable’ parameters in this study. Hence, these retrievals/spectra very much present an unrealistic worst-case scenario.
Methods to correct the effect of star spots on transit spectra
Herrero et al.  developed a stellar simulator including surface inhomogeneities (spots, faculae), limb darkening/brightening and time-variable effects such as differential rotation and active region evolution. They used said simulator to assess the correlation between activity-induced transit depth variations in the visible (0.8 μm) and the IR (2.5 and 5.0 μm). The existing correlation was used to correct the transit data down to 10 ppm. A different approach based on Principal Component Analysis, has been developed by Micela  with similar conclusions. Zellem et al. , Bruno et al.  proposed the analysis of out of transit lightcurves to correct/identify the noise due to stellar activity.
A further approach has focused on statistical methods to de-correlate astrophysical noise from the desired science signal. Given single time series on an active star with various modes of pulsation obtained by the Kepler space telescope, Waldmann  showed that a randomly chosen pulsation mode of the star could be isolated and the remaining autocorrelative noise of the star suppressed, resulting in a strong reduction of the stellar noise component. Similar concepts apply to periodic exoplanetary lightcurves observed over multiple transits and/or wavelengths. The results were repeated for a sample of Kepler stellar light curves, spanning from M to G types. In all cases a correction of the order of 10–100 ppm in the visible wavelengths depending on the frequency of the sampling (i.e. 10 h continuous observations every day or 10 h once a week), was obtained.
Despite the high activity of GJ1214 in the optical due mainly to faculae, as described in Rackham et al. , in the NIR Kreidberg et al. [125, 126] do not detect signs of activity in the 12 WFC3 transit spectra analysed, an analysis confirmed by Zellem et al. .
The star CoRoT-2 is notoriously very active and has been observed extensively with Corot. Bruno et al.  presented a new method for the fit of transit photometry which takes into account the impact of activity features on the transit. This approach models both non-occulted and occulted features and their evolution. The method was applied to correct the light curve of CoRoT-2 in two ways. The first is based on the simultaneous modelling of activity features and transits in a non-normalized light curve. The second consists in normalizing the transits by using the modelling of the out-of-transit light curve, and then in a standard fit of the so-normalized transits.
Fraction of flaring stars in SC Kepler data (from Balona )
No stars in the sample
No flaring stars
The first step will be, therefore, the identification of planets around flaring stars and either eliminate them from the sample, or actually target them for specific science cases . However even if after the cleaning of the sample, some flares will occur, it will be possible to recognize a typical flare from the shape of light curve with the photometric channels from the FGS. The typical sudden rise and slow decay signature of a flare over one/several hours allows to disentangle it from a transit signature. The hot color of the flare emission will also allow to use the two optical channels to recognize the flare in the light curves and discard the data if necessary.
expected variation in K band for a given variation in V-band. The reported case is relative to a very intense flare. A flare on a M0 star with an amplitude in U of Δu = 2.05, has an amplitude of ΔV = 0.21 in V and of Δmk = 0.01 in K band. Such a strong flare will be easily detected
Globally the flare effect in the NIR is therefore very small, as illustrated from the case of AD Leo (a very active M-star) reported in Fig. 49 right (from ). In Table 11 we give example of intense flares for M0 and M3 stars. Earlier spectral type stars will have flares of significantly lower intensity.
To summarize, stars with intense flaring are uncommon and might not make it to the final ARIEL sample. Isolated flares would be immediately identified with the FGS and the flare effect in the IR is very small.
2.3 The ARIEL data policy
The ARIEL data policy has been designed to embrace the astronomy community in general and the exoplanet community in particular. It is recognised that ARIEL data and data products will be of huge interest to the entire exoplanet community, not only to those directly involved in the mission. The intention is to provide high quality data in a timely manner and to have a continuous dialogue with the wider community, maximising the science that can be achieved by the mission.
Inputs to the target list – to be observed will be solicited from the wider community (e.g. through whitepapers, meetings, and other mechanisms), the community will be kept informed about the status of the target list, as will the ESA Advisory Bodies whose feedback will be solicited.
A Science Demonstration Phase (SDP) will be conducted as the final step before routine science phase operations commence. The SDP is foreseen to provide approximately one month worth of data observed in the same manner that the core survey will be conducted. These data will be made public on a timescale of about a month, in conjunction with organisation of a major public workshop.
Regular timely public releases of high quality data products at various processing levels will be provided throughout the mission. The data will be pipeline processed to different levels of data products labelled ‘raw telemetry’ (level 0), ‘raw spectral frame cubes’ (level 1), ‘target (star + planet) spectra’ (level 2), and ‘individual planet spectra’ (level 3), respectively. The lower levels can generally be released quicker than higher levels, but the objective is to release all levels timely in order to maximise the science return and impact of ARIEL.
Beyond the science community, ARIEL’s mission to characterise distant worlds offers an immense opportunity to capture the public imagination and inspire the next generation of scientists and engineers. Through the provision of enquiry-based educational programmes and citizen science platforms, school students and members of the public will have the opportunity to participate directly in the analysis of ARIEL data.
We have presented in this paper an overview of the science objectives for the ARIEL mission and the worked completed during the Phase A study. In order for the ARIEL mission to address the fundamental questions of “what are exoplanets made of” and “how do planetary systems form and evolve”, the investigation of many hundreds of planetary atmospheres will be needed. By observing a large number (~1000) of transiting planets from a range of different classes of objects we will gain a statistical understanding of their nature.
The main ARIEL focus will be on warm and hot planets to take advantage of their well-mixed atmospheres which should show minimal condensation and sequestration of high-Z materials and thus reveal their bulk and elemental composition (especially C, O, N, S, Si). Observations of these warm/hot exoplanets will allow the understanding of the early stages of planetary and atmospheric formation during the nebular phase and the following few million years. ARIEL will thus provide a truly representative picture of the chemical nature of the exoplanets and relate this directly to the type and chemical environment of the host stars.
The combination of a stable platform, operating in a stable thermal environment and with a highly integrated payload and systems design, will ensure the very high level of photometric stability required to record exoplanet atmospheric signals, i.e. 10–50 ppm relative to the star (post-processing). The broad, instantaneous wavelength range covered by ARIEL will allow to detect many molecular species, probe the thermal structure, identify/characterize clouds and monitor/correct the stellar activity. Finally, requiring an agile, highly stable platform in orbit around L2, from which the complete sky is accessible within a year, will enable the observation of hundreds of planets during the mission lifetime.
The scale height H of an atmosphere is the altitude at which the atmospheric pressure decreases by 1/e. H = k T/μ g; where: k Boltzmann constant, T atmospheric temperature, g gravity acceleration, μ atmospheric mean molecular weight. ARIEL can measure directly T through eclipse measurements, g is known through the radius and mass, so a measure of the scale height determine μ, the molecular weight of the atmosphere.
The payload consortium would like to thank the national agencies for their support during the assessment study.
Many co-authors of this paper were supported by European Research Council grants (programs AEROSOL, E3ARTHS, ExoAI, ExoLights, ExoMol, MoltenEarths, SPECULOOS, WHIPLASH), H2020-COMPET-2017 (ExoplANETS A) and ANR (e-PYTHEAS) UKSA grant ST/S002634/1.
We would like to thank the ESA CDF team, as well as TEC and SRE directorate colleagues and industrial teams led by Airbus Defense and Space – France and TAS – France who provided support during the course of the study.
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