Environmental Monitoring and Assessment

, Volume 170, Issue 1–4, pp 365–382 | Cite as

Identification of the hydrogeochemical processes in groundwater using major ion chemistry: a case study of Penna–Chitravathi river basins in Southern India



Hydrogeochemical studies were carried out in the Penna–Chitravathi river basins to identify and delineate the important geochemical processes which were responsible for the evolution of chemical composition of groundwater. The area is underlain by peninsular gneissic complex of Archaean age, Proterozoic meta-sediments, and strip of river alluvium. Groundwater samples were collected covering all the major hydrogeological environs in pre- and post-monsoon seasons. The samples were analyzed for major constituents such as Ca2 + , Mg2 + , Na + , K + , CO3 − , HCO3 − , Cl − , SO2 − 4, NO3 − , and F − . The groundwater in general is of Na + –Cl − , Na + –HCO3 − , Ca2 + –Mg2 + –HCO3 − , and Ca2 + –Mg2 + –Cl −  types. Na +  among cations and Cl −  and/or HCO3 −  among anions dominate the water; Na +  and Ca2 +  are in the transitional state with Na +  replacing Ca2 +  and HCO3 −  Cl −  due to physiochemical changes in the aquifer and water–rock interactions. The Ca2 + –Mg2 + –Cl −  HCO3 −  type water in one third samples suggest that ion exchange and dissolution processes are responsible for its origin. Change in storage of aquifer in a season does not influence the major geochemical makeup of groundwater. Gibbs plots indicate that the evolution of water chemistry is influenced by water–rock interaction followed by evapotranspiration process. The aquifer material mineralogy together with semiarid climate, poor drainage system, and low precipitation factors played major role in controlling groundwater quality of the area.


Penna–Chitravathi rivers Anantapur Hydrogeochemstry Pre- and post-monsoon Evapotranspiration Water–rock interaction 


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  1. Apadaca, L. E., Jeffrey, B. B., & Michelle, C. S. (2007). Water quality in shallow alluvium aquifers, Upper Calordo river basin, Calorado. Journal of the American Water Resources Association, 38(1), 133–148.CrossRefGoogle Scholar
  2. APHA (1995). Standard methods for the examination of water and wastewater (17th ed.). Washington, D.C.: American Public Health Association.Google Scholar
  3. Beck, B. F., Asmussen, L., & Leonard, R. S. (1985). Relationship of geology, physiography, agricultural land use and groundwater quality in southwest Georgia. Groundwater GRWAAP, 23(5), 627–634.Google Scholar
  4. Brijraj, K., & Kaur, P. (2007). Geochemistry of surface and sub-surface waters of Rawalyar lakes, Mandi district, Himachal Pradesh: Constraints on weathering and erosion. Journal of the Geological Society of India, 69, 1020–1030.Google Scholar
  5. Cerling, T. E., Pederson, B. L., & Damn, K. L. V. (1989). Sodium-calcium ion exchange in the weathering of shales implication for global weathering budgets. Gelogy, 17, 552–554.CrossRefGoogle Scholar
  6. Chadha, D. K. (1999). A proposed new diagram for geochemical classification of natural waters and interpretation of chemical data. Hydrogeology Journal, 7, 431–439.CrossRefGoogle Scholar
  7. Datta, P. S., & Tyagi, S. K. (1996). Major ion chemistry of groundwater in Delhi area: Chemical weathering processes and groundwater flow regime. Journal of the Geological Society of India, 47, 179–188.Google Scholar
  8. Doe, N.A., & Windecker, N. (2005). Groundwater notes. SHALE, 11, 37–44.Google Scholar
  9. Domenico, P. A. (1972). Concepts and models in groundwater hydrology. New York: Mc Graw Hill.Google Scholar
  10. Elango, L., & Kannan, R. (2007). Rock–water interaction and its control on chemical composition of groundwater. Chap. 11. Developments in Environmental Science, 5, 229–243, Publ. Elsevier.CrossRefGoogle Scholar
  11. Elango, L., Kannan, R., & Senthil Kumar, M. (2003). Major ion chemistry and identification of hydrogeochemical processes of groundwater in a part of Kancheepuram district, Tamil Nadu. Environmental Geosciences, 1(4), 157–166.Google Scholar
  12. Fisher, R. S., & Mulican, III, W. F. (1997). Hydrogeochemical evolution of sodium-sulfate and sodium-chloride groundwater beneath the Northern Cnihvahvan desert. Trans-Pecos, Texas USA. Hydrogeology Journal, 10(4), 455–474.Google Scholar
  13. Gibbs, R. J. (1970). Mechanisms controlling World’s water chemistry. Science, 170, 1088–1090.CrossRefGoogle Scholar
  14. Gopinath, G., & Seralathan, P. (2006). Chemistry of groundwater in the laterite formation of Muvatterpuzha river basin, Kerala. Journal of the Geological Society India, 68, 705–714.Google Scholar
  15. Gowd, S. S. (2005). Assessment of groundwater quality for drinking and irrigation purposes: A case study of Peddavanka watershed, Anantapur District, Andhra Pradesh, India. Environmental Geology, 48, 702–712.CrossRefGoogle Scholar
  16. Gosselin, C. D., Edwin, H. F., & Flowerday, C. (2003). The complex Dakota aquifer: Managing groundwater in Nebraska. Geotimes April 2003.: http://www.copyright.com/ccc/do/showConfigurator?WT.mc_id=PubLink.
  17. Govt. of Andhra Pradesh (2004). Handbook of statistics: Anantapur District. Andhra Pradesh: Govt. of Andhra Pradesh.Google Scholar
  18. Hem, J. D. (1991). Study and interpretation of the chemical characteristics of natural water. US Geol Surv Water Supply Paper (3rd ed.). Jodhpur: Scientific.Google Scholar
  19. Huh, Y., Tsoi, M. Y., Zaitiser, A., & Edward, J. N. (1998). The fluvial geochemistry of the river of Eastern Siberia, 1. Tributaries of Lena river drainage the sedimentation platform of the Siberia Craton. Geochimica et Cosmochimicha Acta, 62, 1657–1676.CrossRefGoogle Scholar
  20. Jankowski, J., & Acworth, R. I. (1997). Impact of depris-flow deposit on hydrogeochemical processes and the development of dry land salinity in the Yass River catchment, New South Wales, Australia. Hydrogeology Journal, 5(44), 71–88.CrossRefGoogle Scholar
  21. Johnson, C. C. (1979). Land application of water-an accident waiting to happen. Groundwater, 17(1), 69–72.Google Scholar
  22. King, L. J., & Olsen, H. W. (1999). Hydraulic conductivity reductions resulting from clay dispersion within alluvial sediments impacted by sodium-rich water. US Geological Survey Toxic Substances Hydrology Program–Proceedings of the Technical Meeting Charleston South Carolina March 8–12, 1999–Volume 3 of 3–Subsurface Contamination From Point Sources, Water-Resources Investigations Report 99–4018C, http://toxics.usgs.gov/pubs/wri99–4018/Volume3/SectionE/3608_King/index.html.
  23. Kumar, M., Ramanathan, A. L., Rao, M. S., & Kumar, B. (2006). Identification and evaluation of hydrogeochemical processes in the groundwater environment of Delhi. Environmental Geology, 50, 1025–1039.CrossRefGoogle Scholar
  24. Lavitt, N., Acworth, R. I., & Jankowski, J. (1997). Vertical hydrogeochemical zonation in a coastal section of the Botany Sands aquifer, Sydney, Australia. Hyrogeology Journal, 5, 64–74.CrossRefGoogle Scholar
  25. Matthess, G. (1982). The properties of groundwater (p. 498). New York: Wiley.Google Scholar
  26. May, A. L., & Loucks, M. D. (1995). Solute and isotope geochemistry and groundwater flow in the Central Wasatch Range, Utah. Journal of Hydrology, 170, 795–840.Google Scholar
  27. McIntosh, J. C., & Walter, L. M. (2006). Paleowater in Silurian-Devonian carbonate aquifers: Geochemical evolution of groundwater in the Great Lakes region since Late Pleistocene. Geochimica Cosmochimica Acta, 70, 2454–2479.CrossRefGoogle Scholar
  28. Meybeck, M. (1987). Global chemical weathering of surficial rocks estimated from river dissolved leads. American Journal of Science, 287, 401–428.CrossRefGoogle Scholar
  29. Pandian, K., & Sankar, K. (2007). Hydro-geochemistry and groundwater quality in the Vaippar River Basin, Tamil Nadu. Journal of the Geological Society of India, 69, 970–982.Google Scholar
  30. Pophare, M. A., & Dewalkar, S. M. (2007). Groundwater quality in eastern and south eastern parts of Rajura Tehsil, Chendrapur district, Maharashtra. Gondwana Geol Mazn Sp, 11, 119–129.Google Scholar
  31. Raghunath, H. M. (1982). Groundwater (p. 456). New Delhi: Wiley.Google Scholar
  32. Raju, J. (2007). Hydrogeochemical parameters for assessment of groundwater quality in the upper Gunjanaeru River basin, Cuddapah District, Andhra Pradesh, South India. Environmental Geology, 52, 1067–1074.CrossRefGoogle Scholar
  33. Raju, K. C. C., Kareemuddin, M. D., & Prabhakara, R. P. (1979). Operation Anantapur. Miscellaneous publication 47: Geological Survey of India.Google Scholar
  34. Randall, M. G., Trivedi, D. P., Graham, J., Small, J. S., & Hughes, C. (1996). Mineralogical characterization of sediments at the Drigg low level radioactive waste disposal site and the influence on groundwater chemistry. © 1995–2009. Warrendale: Materials Research Society.Google Scholar
  35. Rashid, U., & Izrar, A. (2007). Hydrchemical characteristics of groundwater in parts of Kushva-Yamuna basin, Muzaffarnagar district, UP. Journal of the Geological Society of India, 69, 970–982.Google Scholar
  36. Reddy, A. G. S., Niranjan, K. K., & Venkat, R. D. (2008). Seasonal and temporal variations in groundwater quality of north eastern parts of aantapur district, AP. Journal of Applied Geochemistry, 10(1), 103–112.Google Scholar
  37. Reddy, A. G. S., Niranjan, K. K., Subba, R. D., & Sambashiva, R. S. (2009). Assessment of nitrate contamination due to groundwater pollution in north eastern part of Anantapur District, AP India. Environmental Monitoring and Assessment, 148, 463–476. doi:10.1007/s10661-008-0176-y.CrossRefGoogle Scholar
  38. Reddy, N. B. Y., & Prasad, K. S. S. (2005). Hydro-geochemistry of groundwater in and around Tadpatri area, Anantapuir district, AP. Journal of Indian Association of Environmental Management, 32, 66–73.Google Scholar
  39. Sami, K. (1992). Recharge mechanism and geochemical processes in a semi arid sedimentary basin, Eastern Cape, South Africa. Journal of Hydrology, 139, 27–48.CrossRefGoogle Scholar
  40. Sarin, M. M., Krishnaswmay, S., Dilli, K., Somayajulu, B. L. K., & Moore, W. S. (1989). Major ion chemistry of the Ganga-Brahmaputra river system: Weathering processes and fluxes to the bay of Bengal. Geochimica et Cosmochimica Acta, 53, 997–1009.CrossRefGoogle Scholar
  41. Sastry, J. C. V. (1994). Groundwater chemical quality in river basins, hydrogeochemical facies and hydrogeochemical modeling. In Lecture notes-refresher course conducted by School of Earth Sciences. Tamil Nadu, India: Bharathidasan University, Thiruchirapalli.Google Scholar
  42. Schoeller, H. (1965). Hydrodynamique lans lekarst (ecoulemented emmagusinement). Actes Colloques Doubronik, I: AIHS et UNESCO, 3–20.Google Scholar
  43. Schoeller, H. (1967). Qualitative evaluation of groundwater resources. In Methods and techniques of groundwater investigation and development. Water Research, Series-33: UNESCO (pp. 44–52).Google Scholar
  44. Singh, P. K., Amrita, M., Dinesh, M., Vinod, K. S., & Singh, S. (2006). Evaluation of groundwater quality in northern Indo-Gangetic alluvium region. Environmental Monitoring and Assessment, 112, 211–230. doi:10.1007/s10661-006-0357-5.CrossRefGoogle Scholar
  45. Soltan, M. E. (1998). Characterization, classification and evaluation of some groundwater samples in Upper Epygt. Chemos, 37, 735–747.CrossRefGoogle Scholar
  46. Soltan, M. E. (1999). Evaluation of groundwater quality in Dakhla Oasis (Egyptian Western Desert). Evironmental Monitoring and Assessment, 57, 157–168.CrossRefGoogle Scholar
  47. SoCo (2009). Sustainable agriculture and soil conservation, soil degradation processes. Fact sheet no. 4, http://eusoils.jrc.ec.europa.eu/projects/soil_atlas/.
  48. Stallard, R. F., & Edmond, J. M. (1983). Geochemistry of the Amazon, the influence of geology and weathering environment on the dissolved load. Journal of Geophysical Research, 88, 9671–9688.CrossRefGoogle Scholar
  49. Stocking, M. A. (2006). Catena of sodium-rich soil in Rhodesia. European Journal of Soil Science, 30(1), 139–146. Published Online: 28 Jul 2006.Google Scholar
  50. Subbarao, N. (2006). Seasonal variation of ground\(\backslash \) water quality in a part of Guntur district, AP, India. Environmental Geology, 49, 413–429.CrossRefGoogle Scholar
  51. Wallick, E. I., & Toth, J. (1976). Methods of regional groundwater flow analysis with suggestions for the use of environmental isotope and hydrochemical data in groundwater hydrology (pp. 37–64). Vienna: IAEA.Google Scholar

Copyright information

© Springer Science+Business Media B.V. 2009

Authors and Affiliations

  1. 1.Central Ground Water Board, SRHyderabadIndia
  2. 2.Kakatiya UniversityWarangal, APIndia

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