Spatial variability of soil heavy metals in the three gorges area: multivariate and geostatistical analyses
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Abstract
There is a growing concern about environmental contamination in the three gorges area. The objectives of this study were to investigate the spatial variability and the possible influence factors of seven heavy metals (As, Cd, Cr, Cu, Hg, Pb, and Zn) in the center of this area based on multivariate and geostatistical approaches. All analyzed heavy metals were below their background levels, except Cd. The average concentrations of the analyzed elements in topsoil (0–20 cm) were 5.83 mg As kg − 1, 0.21 mg Cd kg − 1, 78.79 mg Cr kg − 1, 21.53 mg Cu kg − 1, 0.049 mg Hg kg − 1, 24.12 mg Pb kg − 1, and 68.5 mg Zn kg − 1. The concentration of As was mostly due to parent materials, whereas the source of Pb was mainly due to vehicle exhaust. The high concentration of Cd was resulted from agricultural practices and parent materials. The concentrations of Cr, Cu, Hg, and Zn were associated with parent materials and human activities.
Keywords
Heavy metals Spatial variability Multivariate GeostatisticsPreview
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References
- Bloemen, M. L., Markert, B., & Lieth, H. (1995). The distribution of Cd, Cu, Pb and Zn in topsoils of Osnabrück in relation to land use. Science of the Total Environment, 166, 137–148. doi:10.1016/0048-9697(95)04520-B.CrossRefGoogle Scholar
- Cambardella, C. A., Moorman, T. B., Novak, J. M., Parkin, T. B., Turco, R. F., & Konopka, A. E. (1994). Field-scale variability of soil properties in central Iowa soils. Soil Science Society of America Journal, 58, 1501–1511.Google Scholar
- Engle, M. A., Gustin, M. S., Lindberg, A. W., & Ariya, P. A. (2005). The influence of ozone on atmospheric emissions of gaseous elemental mercury and relative gaseous mercury from substrates. Atmospheric Environment, 39, 7506–7517.CrossRefGoogle Scholar
- Gamma Design Software (2004). GS + user’s guide version 7. Gamma design software. MI: Plainwell.Google Scholar
- Goovaerts, P. (1997). Geostatistics for natural resources evaluation. Applied geostatistics series. New York: Oxford University Press.Google Scholar
- Gustafson, G. M., Salomon, E., & Jonsson, S. (2007). Barn balance calculations of Ca, Cu, K, Mg, Mn, N, P, S and Zn in a conventional and organic dairy farm in Sweden. Agriculture, Ecosystems & Environment, 119, 160–170. doi:10.1016/j.agee.2006.07.003.CrossRefGoogle Scholar
- Huang, B., Shi, X. Z., Yu, D. S., Őborn, I., Blombäck, K., Pagella, T. F., et al. (2006). Environmental assessment of small-scale vegetable farming systems in peri-urban areas of the Yangtze River Delta Region, China. Agriculture, Ecosystems & Environment, 112, 391–402. doi:10.1016/j.agee.2005.08.037.CrossRefGoogle Scholar
- Isaaks, E. H., & Srivastava, R. M. (1989). An introduction to applied geostatistics. New York: Oxford University Press.Google Scholar
- Li, Q. L., Huang, Y., Liu, G. D., Zeng, X. Y. (2004). The contents and character of heavy metals of main soil types in three gorge reservoir. Acta Pedologica Sinica, 2, 301–304 (in Chinese).Google Scholar
- Liu, G. D., Li, Q. L., Huang, Y. (2003). Status of non-point source pollution in the three gorges area with discussion on the countermeasures. Resources and Environment in the Yangtze Basin, 5, 462–466 (in Chinese).Google Scholar
- Liu, X. M., Wu, J. J., & Xu, J. M. (2006). Characterizing the risk assessment of heavy metals and sampling uncertainty analysis in paddy field by geostatistics and GIS. Environmental Pollution, 141, 257–264. doi:10.1016/j.envpol.2005.08.048.CrossRefGoogle Scholar
- Lucho-Constantino, C. A., Prieto-García, F., Razo, L. M. D., Rodríguez-Vázquez, R., Poggi-Varaldo, H. M. (2005). Chemical fractionation of boron and heavy metals in soils irrigated with wastewater in central Mexico. Agriculture, Ecosystems & Environment, 108, 57–71. doi:10.1016/j.agee.2004.12.013.CrossRefGoogle Scholar
- Mantovi, P., Bonazzi, G., Maestri, E., & Marmiroli, N. (2003). Accumulation of copper and Zinc from liquid manure in agricultural soils and crop plants. Plant Soil, 250, 249–257. doi:10.1023/A:1022848131043.CrossRefGoogle Scholar
- Mapanda, F., Mangwayana, E. N., Nyamangara, J., & Giller, K. E. (2005). The effect of long-term irrigation using wastewater on heavy metal contents of soils under vegetables in Harare, Zimbabwe. Agriculture, Ecosystems & Environment, 107, 151–165. doi:10.1016/j.agee.2004.11.005.CrossRefGoogle Scholar
- Martin, C. W. (2004). Heavy metal storage in near channel sediments of the Lahn River, Germany. Geomorphology, 61, 275–285. doi:10.1016/j.geomorph.2004.01.003.CrossRefGoogle Scholar
- McGraph, D., Zhang, C. S., & Carton, O. (2004). Geostatistical analyses and hazard assessment on soil lead in Silvermines, area Ireland. Environmental Pollution, 127, 239–248. doi:10.1016/j.envpol.2003.07.002.CrossRefGoogle Scholar
- Miller, J. R., Lechler, P. J., & Bridge, G. (2003). Mercury contamination of alluvial sediments within the Essequibo and Mazaruni river basins, Guyana. Water, Air and Soil Pollution, 148, 139–166.CrossRefGoogle Scholar
- Nan, Z. R., Li, J. J., Zhang, J. M., & Cheng, G. D. (2002). Cadmium and zinc interactions and their transfer in soil-crop system under actual field conditions. Science of the Total Environment, 285, 187–195. doi:10.1016/S0048-9697(01)00919-6.CrossRefGoogle Scholar
- National Environmental Protection Agency (NEPA). (1990). Background values of elements in soils of China. Beijing: China Environmental Science Press (in Chinese).Google Scholar
- National Environmental Protection Agency (NEPA) (1995). Environmental quality standard for soils (GB15618-1995) (in Chinese).Google Scholar
- Rodríguez, J. A., Nanos, N., Grau, J. M., Gil, L., & López-Arias, M. (2008). Multiscale analysis of heavy metal contents in Spanish agricultural topsoils. Chemosphere, 70, 1085–1096. doi:10.1016/j.chemosphere.2007.07.056.CrossRefGoogle Scholar
- Ryan, J. A., Pahren, H. R., & Lucas, J. B. (1982). Controlling cadmium in the human food chain—a review and rational based on health effects. Environmental Research, 28, 251–302. doi:10.1016/0013-9351(82)90128-1.CrossRefGoogle Scholar
- Saby, N., Arrouays, D., Boulonne, L., Jolivet, C., & Pochot, A. (2006). Geostatistical assessment of Pb in soil around Paris, France. Science of the Total Environment, 367, 212–221. doi:10.1016/j.scitotenv.2005.11.028.CrossRefGoogle Scholar